Yoan Germain

Pore water geochemistry at two seismogenic areas in the Sea of Marmara

Within the Sea of Marmara, the highly active North Anatolian Fault (NAF) is responsible for major earthquakes (Mw ≥ 7), and acts as a pathway for fluid migration from deep sources to the seafloor. This work reports on pore water geochemistry from three sediment cores collected in the Gulfs of Izmit and Gemlik, along the Northern and the Middle strands of the NAF, respectively. The resulting data set shows that anaerobic oxidation of methane (AOM) is the major process responsible for sulfate depletion in the shallow sediment. In the Gulf of Gemlik, depth concentration profiles of both sulfate and alkalinity exhibit a kink-type profile. The Sulfate Methane Transition Zone (SMTZ) is located at moderate depth in the area. In the Gulf of Izmit, the low concentrations observed near the seawater-sediment interface for sulfate, calcium, strontium, and magnesium result from rapid geochemical processes, AOM, and carbonate precipitation, occurring in the uppermost part of the sedimentary column and sustained by free methane accumulation. Barite dissolution and carbonate recrystallization have also been identified at deeper depth at the easternmost basin of the Gulf of Izmit. This is supported by the profile of the strontium isotope ratios (87Sr/86Sr) as a function of depth which exhibits negative anomalies compared to the modern seawater value. The strontium isotopic signature also shows that these carbonates had precipitated during the reconnection of the Sea of Marmara with the Mediterranean Sea. Finally, a first attempt to interpret the sulfate profiles observed in the light of the seismic activity at both sites is presented. We propose the hypothesis that seismic activity in the areas is responsible for the transient sulfate profile, and that the very shallow SMTZ depths observed in the Gulf of Izmit is likely due to episodic release of significant amount of methane.

Geochemical Dynamics of the Natural-Gas Hydrate System in the Sea of Marmara, Offshore Turkey

Natural-gas hydrate systems are solid-state light-hydrocarbon accumulations which are encountered in the permafrost and the continental margins. They are stable under highpressure and low-temperature conditions and represent the major hydrocarbon volume on earth (Kvenvolden, 1988). Gas hydrates consist of a polycrystalline structure where a light hydrocarbon is trapped within a water lattice. The nature of the hydrocarbons is strongly related to their origin which is either microbial (also called biogenic) or thermogenic. Microbial gas-hydrate systems contain hydrocarbons produced by bacteria and archaea. There are primarily methane with a very small amount of ethane and eventually propane (Max, 2003). Others non-hydrocarbon compounds like hydrogen sulphur and carbon dioxide are also present. In the case of microbial gases, the hydrates are formed at or near the gas production area. Owing to the very high-methane content, these hydrates are commonly called methane-hydrate systems.

Dissolved iron in the North Atlantic Ocean and Labrador Sea along the GEOVIDE section (GEOTRACES section GA01)

Dissolved Fe (DFe) samples from the GEOVIDE voyage (GEOTRACES GA01, May–June 2014) in the North Atlantic Ocean were analyzed using a seaFAST-picoTM coupled to an Element XR sector field inductively coupled plasma mass spectrometer (SF-ICP-MS) and provided interesting insights into the Fe sources in this area. Overall, DFe concentrations ranged from 0.09± 0.01 to 7.8± 0.5 nmol L−1. Elevated DFe concentrations were observed above the Iberian, Greenland, and Newfoundland margins likely due to riverine inputs from the Tagus River, meteoric water inputs, and sedimentary inputs. Deep winter convection occurring the previous winter provided iron-to-nitrate ratios sufficient to sustain phytoplankton growth and lead to relatively elevated DFe concentrations within subsurface waters of the Irminger Sea. Increasing DFe concentrations along the flow path of the Labrador Sea Water were attributed to sedimentary inputs from the Newfoundland Margin. Bottom waters from the Irminger Sea displayed high DFe concentrations likely due to the dissolution of Fe-rich particles in the Denmark Strait Overflow Water and the Polar Intermediate Water. Finally, the nepheloid layers located in the different basins and at the Iberian Margin were found to act as either a source or a sink of DFe depending on the nature of particles, Published by Copernicus Publications on behalf of the European Geosciences Union. 918 M. Tonnard et al.: Dissolved iron in the North Atlantic Ocean with organic particles likely releasing DFe and Mn particle scavenging DFe.

Focused hydrocarbon‐migration in shallow sediments of a pockmark cluster in the Niger Delta (Off Nigeria)

The Niger Delta is one of the largest hydrocarbon basin offshore Africa and it is well known for the presence of active pockmarks on the seabed. During the Guineco-MeBo cruise in 2011, long cores were taken from a pockmark cluster in order to investigate the state of its current activity. Gas hydrates, oil and pore-water were sampled for geochemical studies. The resulting dataset combined with seismic data reveal that shallow hydrocarbon migration in the upper sedimentary section was focused exclusively within the pockmarks. There is a clear tendency for gas migration within the hydrate-bearing pockmarks, and oil migration within the carbonate-rich one. This trend is interpreted as a consequence of hydrate dissolution followed by carbonate precipitation in the course of the evolution of these pockmarks. We also demonstrate that Anaerobic Oxidation of Methane (AOM) is the main process responsible for the depletion of pore-water sulfate, with depths of the Sulfate-Methane Transition Zone (SMTZ) ranging between 1.8 and 33.4 m. In addition, a numerical transport-reaction model was used to estimate the age of hydrate-layer formation from the present-day sulfate profiles. The results show that the sampled hydrate-layers were formed between 21 and 3750 years before present. Overall, this work shows the importance of fluid flow on the dynamics of pockmarks, and the investigated cluster offers new opportunities for future cross-site comparison studies. Our results imply that sudden discharges of gas can create hydrate layers within the upper sedimentary column which can affect the seafloor morphology over few decades. This article is protected by copyright. All rights reserved.

Extensive wet episodes in Late Glacial Australia resulting from high-latitude forcings

Millennial-scale cooling events termed Heinrich Stadials punctuated Northern Hemisphere climate during the last glacial period. Latitudinal shifts of the intertropical convergence zone (ITCZ) are thought to have rapidly propagated these abrupt climatic signals southward, influencing the evolution of Southern Hemisphere climates and contributing to major reorganisation of the global ocean-atmosphere system. Here, we use neodymium isotopes from a marine sediment core to reconstruct the hydroclimatic evolution of subtropical Australia between 90 to 20 thousand years ago. We find a strong correlation between our sediment provenance proxy data and records for western Pacific tropical precipitations and Australian palaeolakes, which indicates that Northern Hemisphere cooling phases were accompanied by pronounced excursions of the ITCZ and associated rainfall as far south as about 32°S. Comparatively, however, each of these humid periods lasted substantially longer than the mean duration of Heinrich Stadials, overlapping with subsequent warming phases of the southern high-latitudes recorded in Antarctic ice cores. In addition to ITCZ-driven hydroclimate forcing, we infer that changes in Southern Ocean climate also played an important role in regulating late glacial atmospheric patterns of the Southern Hemisphere subtropical regions.