Yoon Deok Han

Remarkable Mobility Increase and Threshold Voltage Reduction in Organic Field‐Effect Transistors by Overlaying Discontinuous Nano‐Patches of Charge‐Transfer Doping Layer on Top of Semiconducting Film

An effective strategy for significantly increasing the organic transistor mobility with simultaneous reduction of the threshold voltage utilizing discontinuous nano-patches of charge-transfer doping layer is demonstrated. By overlaying the nano-patches on top of a given semiconducting film, mobility and threshold voltage of p-type pentacene are remarkably improved to 4.52 cm(2) V(-1) s(-1) and -0.4 V, and those of n-type Hex-4-TFPTA are also improved to 2.57 cm(2) V(-1) s(-1) and 4.1 V.

Photoresponsive characteristics and hysteresis of soluble 6,13-bis(triisopropyl-silylethynyl)-pentacene-based organic thin film transistors with and without annealing

We report on the photoresponsive characteristics and hysteresis of soluble 6,13-bis(triisopropyl-silylethynyl; TIPS)-pentacene-based organic thin film transistors (OTFTs) with and without an annealing process. Under incident light, the hysteresis and memory effect increased for the annealed devices through photoinduced electron trapping and recombination at the gate-dielectric-semiconductor interface. To investigate the cause of the photoenhanced memory effect and hysteresis, we estimated the trapped electron densities from the threshold shift, while applying a gate bias to the annealed OTFTs under both dark and light conditions. A comparison of the characteristics of OTFT devices that are prepared under various conditions suggests that deep electron traps might be caused by the appearance of a domain boundary (i.e., cracks) in the annealed TIPS-pentacene film during the annealing process, which showed stable photoresponsive characteristics but relatively lower mobility.