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Journal of Materials Research | 2004

Metal ion and N co-doped TiO 2 as a visible-light photocatalyst

Yoshiaki Sakatani; Hiroyuki Ando; Kensen Okusako; Hironobu Koike; Jun Nunoshige; Tsuyoshi Takata; Junko N. Kondo; Michikazu Hara; Kazunari Domen

Powders of TiO2 doped with a metal ion and N species were prepared by a polymerized complex method and the visible-light photocatalytic activities of the products are investigated. Of the metal ions studied (K+, Ca2+, Sr2+, Ba2+, Nb5+, Fe3+, Zn2+, and Al3+), the photocatalyst prepared with Sr2+ exhibits the highest activity for acetaldehyde decomposition under visible-light irradiation. Results obtained from x-ray photoelectron spectroscopy (XPS) and electron spin resonance (ESR) analyses suggest that the doped N species reside at interstitial lattice positions in the catalyst. It was also found by XPS and ESR measurements that the doped N species combine with lattice oxygen to give rise to a paramagnetic property. The visible-light response of the catalyst is driven by the formation of paramagnetic N species at interstitial positions in the TiO2 lattice.


Chemistry Letters | 2003

Photocatalytic Decomposition of Acetaldehyde under Visible Light Irradiation over La3+ and N Co-doped TiO2

Yoshiaki Sakatani; Jun Nunoshige; Hiroyuki Ando; Kensen Okusako; Hironobu Koike; Tsuyoshi Takata; Junko N. Kondo; Michikazu Hara; Kazunari Domen


Archive | 1997

Abrasive composition and use of the same

Yoshiaki Sakatani; Kazumasa Ueda; Yoshiaki Takeuchi


Archive | 2004

Method for producing titanium oxide

Yuko Yoshida; Yoshiaki Sakatani


Archive | 2009

Photocatalyst dispersion liquid and process for producing the same

Yoshiaki Sakatani; Kensen Okusako; Makoto Murata


Archive | 2001

Titanium oxide, and photocatalyst and photocatalyst coating composition using the same

Kazunari Domen; Yoshiaki Sakatani


Archive | 2001

Process for producing titanium oxide

Yoshinari Sawabe; Yoshiaki Sakatani; Hironobu Koike


Archive | 2000

Titanium oxide, photocatalyst comprising same and photocatalytic coating agent

Yoshiaki Sakatani; Hironobu Koike; Yoshiaki Takeuchi


Archive | 2001

Titanium oxide production process

Yoshiaki Sakatani; Hironobu Koike


Archive | 2002

Method of manufacturing titanium oxide

Hironobu Koike; Yoshiaki Sakatani; 宏信 小池; 能彰 酒谷

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