Yoshihiro Nakashima

Experimental Study of the Active Compensation to a Full-Size Separate-Shell Magnetic Shield

Shielding efficiency of a full-size separate-shell magnetic shield equipped with active compensation coils is presented. Its size is 135 cm in height, 100 cm in width, and 240 cm in depth. With respect to active compensation two control schemes, i.e., feedback and feedforward, are compared. The shielding efficiency is estimated from the measurements of the attenuation of environmental magnetic fields in two axial directions (horizontal and vertical). In the case of feedback, a reference sensor that measures the incoming magnetic fields is positioned inside the shield, whereas in the case of feedforward the reference sensor is positioned outside the shell. In both axial directions, the environmental magnetic noise can be reduced to less than 500 pT: the noise floor measured by a fluxgate magnetometer is approximately 10 pT/¿Hz in the frequency range from 10 to 100 Hz.

A new method of magnetic shielding: Combination of flux repulsion and backing up magnetic pathways

The guiding principle of the magnetic shield is to redirect magnetic fluxes so that they do not enter an area of interest. There are two ways to do this: the one way is to provide magnetic fluxes with good pathways and the other way is to use repulsive forces acting on the magnetic flux. In this paper, a new method of magnetic shielding combining the above two is proposed. A circulating current and a thin magnetic plate working as a back yoke are the key components. Repulsive forces that act on the magnetic fluxes originating from a noise source are present only on one side of a thin back yoke. By enclosing an area to be shielded with several of those, one can make a magnetic shield in which thin magnetic plates are not necessarily connected. Several numerical examples as well as experimental results are given to demonstrate this idea.

Determination of nitrous acid emission factors from a gasoline vehicle using a chassis dynamometer combined with incoherent broadband cavity-enhanced absorption spectroscopy

Nitrous acid (HONO) is a well-known source of hydroxyl radicals in the troposphere. Vehicle exhaust is considered to be one of the primary emission sources of HONO. In this study, measurements of HONO in gasoline vehicle exhaust were carried out using a chassis dynamometer combined with incoherent broadband cavity-enhanced absorption spectroscopy. When catalysts were warm, concentrations of HONO were higher than those prior to catalysts warming. Other species, such as CO, and total hydrocarbons (THCs), showed the opposite pattern. There were no correlations evident between HONO and other trace species concentrations immediately after emission. The HONO/NOx ratio, a good proxy for the formation of HONO in atmosphere, ranged from 1.1 to 6.8×10-3, which was consistent with previous studies. HONO emission factors (EFs) were calculated to be 0.01-3.6mgkg-1 fuel, which was different from the vehicles specifications and those reported under different driving cycles. Annual HONO emissions in Japan were estimated using the calculated EFs and other statistical data.

Contributions of vehicular emissions and secondary formation to nitrous acid concentrations in ambient urban air in Tokyo in the winter

Nitrous acid (HONO) plays an important role in the formation of OH radicals, which are involved in photochemical oxidation. HONO concentrations in ambient air at urban sites have previously been measured, but very few studies have been performed in central Tokyo. In this study, HONO concentrations in ambient air in southeast central Tokyo (near Tokyo Bay) in winter were determined by incoherent cavity enhanced absorption spectroscopy. The O3, NO, NO2, and SO2 concentrations were simultaneously determined. The NO concentrations were used to classify the parts of the study period into types I (high pollution), II (medium pollution), and III (low pollution). The maximum HONO concentrations in the type I, II, and III periods were 7.1, 4.5, and 3.0ppbv, respectively. These concentrations were comparable to concentrations previously found in other Asian megacities. The mean HONO concentration varied diurnally, and HONO was depleted between 00:00 and 03:00 each day. The sampling site is surrounded by roads with high traffic loads, but vehicular emissions were estimated to contribute <10% of the HONO concentrations. Two positive and negative relative humidity dependences of the HONO to NO2 ratio were confirmed, implying the existence of the two different secondary formation process of HONO. The NO2 to HONO conversion rates at night in the type I, II, and III periods were 6.3×10-3, 7.6×10-3, and 4.2×10-3h-1, respectively.

Validation of in situ Measurements of Atmospheric Nitrous Acid Using Incoherent Broadband Cavity-enhanced Absorption Spectroscopy

Incoherent broadband cavity-enhanced absorption spectroscopy (IBBCEAS) is a useful technique for measuring trace gaseous species in the atmosphere. Recently, IBBCEAS was used to measure concentrations of nitrous acid (HONO) in the troposphere to resolve controversies related to its formation and loss. Here, measurements of HONO and a mixture of HONO and NO2 using IBBCEAS were validated by comparing them with those obtained with a NOx analyzer. Good agreement was found between these methods, given their respective experimental uncertainties. The detection limit of our IBBCEAS instrument was 0.2 ppbv, with a signal-to-noise ratio of 1, and a 5-min integration time.

High-resolution Fourier transform emission spectroscopy of the A∼2Πi−X∼2Πi band of the OCS+ ion

High resolution Fourier transform emission spectroscopy of the A∼2Πi-X∼2Πi band of the OCS+ ion was performed in the UV region to observe the ν1 (CO stretch) progression bands (υ1 = 0 → 2-5) for both the Ω=3/2 and 1/2 spin components. Accurate molecular constants including the rotational constants, B0 = 0.194 765(13) and 0.187 106(13) cm-1, and the spin-orbit interaction constants, A0 = -381.0(56) and -126.5(56) cm-1, were determined for the X∼2Π and A∼2Π states, respectively, by the simultaneous analysis of the observed progression bands. The CO bond length (rCO = 1.2810 Å) for the A∼2Π state, derived from the rotational constant B0 and Franck-Condon factors, is longer by 0.1756 Å than that (1.1054 Å) for the X∼2Π state, while the CS bond length for the A∼2Π state is shorter by 0.0905 Å than that for the X∼2Π state. Pure rotational transition frequencies in the ground X∼2Π state are predicted, as well as transition frequencies of the ν1 fundamental band, with the present molecular constants.