Yoshinobu Motomura

Petrology of the 1991-1995 eruption at Unzen: Effusion pulsation and groundmass crystallization

Abstract Effusive eruption of dacite magma (2.1×108 m3) during 1991–1995 formed a lava dome at the summit of Unzen Volcano, Japan. The effusion rate was highest at the beginning, 4.0×105 m3/day (4.6 m3/s), and decreased roughly with time, to almost zero before this pattern was repeated with a second pulse of magma supply. The whole-rock chemistry of lavas shows significant variation attributable to variations in phenocryst abundance; the more mafic, the more abundant the phenocrysts. The pattern of chemical variation with time shows some difference from that of the effusion rate. All phenocrysts in dacite (plagioclase, hornblende, biotite, quartz and magnetite) show evidence of disequilibrium with melt. Although a glomerophyric aggregation of phenocrysts suggests coexistence with each other, phenocrysts are isotopically heterogeneous from species to species. The calculated initial melt composition was rhyodacite, and was nearly constant throughout the activity. In contrast, the bulk phenocryst population is andesite. A model explaining the textures and the isotopic heterogeneity is the capture of diorite fragments (or xenocrysts) by parental rhyodacite magma. It is suggested that, when effusion rate was high, less viscous crystal-poor magma exited from the reservoir. Groundmass glass and plagioclase microlite rims show temporal chemical variations correlating with the effusion rate; the higher the effusion rate, the more evolved the compositions. Groundmass crystallinity increased with decreasing effusion rate; from 33% to 50%. Textures in dome lavas suggest that groundmass crystallization had been mostly completed when magma reached the conduit top. The Fe–Ti oxide temperature (880–780°C) was low when the crystallinity was high. Micropumice erupted before dome growth provided a sample recording magmatic foam in the conduit. Porosity of dome lavas was lower at lower effusion rates. Collapse of foam magma and simultaneous escape of volatiles through the conduit top were probably responsible for the accompanying low-frequency earthquakes. Phenocrysts were broken and the breakdown rims on hornblende phenocrysts were torn off during collapse and successive compaction. When effusion waned, degassing and the resultant crystallization proceeded more completely, so that the magma became too viscous to flow in the conduit top and behaved as a plug, resulting in a temporary halt of effusion. In turn, groundmass crystallization in magma below the plug increased excess pressure in the upper parts of conduit due to slow cooling. The plug was scavenged when rising excess pressure overcame its effective strength. Then, the second pulse of magma supply began. Strong endogenous growth and extrusion of a lava spine in the later stage probably occurred for the same reason.

Microbial silica deposition in geothermal hot waters

Abstract. A combined use of molecular ecological techniques and geochemical surveys revealed that thermophilic or hyperthermophilic microorganisms living in geothermal environments are likely to be implicated in the formation of biogenic siliceous deposits. Electron microscopic observations indicated that numerous microorganism-like fabrics were preserved in naturally occurring siliceous deposits such as siliceous sinter, geyserite, and silica scale, which suggests microbial contribution to silica precipitation. Molecular phylogenetic analyses suggested that extreme thermophilic bacteria within the genera Thermus and Hydrogenobacter are predominant components among the indigenous microbial community in siliceous deposits formed in pipes and equipment of Japanese geothermal power plants. These bacteria seem to actively contribute to the rapid formation of huge siliceous deposits. Additionally, in vitro examination suggested that Thermus cells induced the precipitation of supersaturated amorphous silica during the exponential growth phase, concomitant with the production of a specific cell envelope protein. Dissolved silica in geothermal hot water may be a significant component in the maintenance of position and survival of microorganisms in limited niches.

Manner of magma ascent at Unzen Volcano (Japan)

Juvenile materials were found among products of phreatomagmatic eruptions that preceded dacite dome growth at Unzen Volcano in 1991. They give evidence showing that the hydrous magma started degassing with the resultant crystallization around 100 MPa, and was quenched soon thereafter. Ascending at a rate as low as 13 m/d while degassing, however, the still-molten part inside reacted with water. Phreatomagmatic eruptions started when the magma reached about 1.2 km in depth, and strong ones started at about 0.6 km. Volcanic tremors had occurred at these depths, where the sources of vulcanian explosions and the ground deformation were also located, implying the existence of a possible gas pocket.

Petrogenetic characteristics of molten slag from the pyrolysis/melting treatment of MSW

MSW slag materials derived from four pyrolysis melting plants in Japan were studied from the viewpoint of petrology in order to discriminate the glass and mineral phases and to propose a petrogenetic model for the formation process of molten slag. Slag material is composed of two major components: melt and refractory products. The melt products that formed during the melting process comprise silicate glass, and a suite of minerals as major constituents. The silicate glass is essentially composed of low and high silica glass members (typically 30% and 50% of SiO(2), respectively), from which minerals such as spinels, melilite, pseudowollastonite, and metallic inclusions have been precipitated. The refractory products consist mainly of pieces of metals, minerals and lithic fragments that survived through the melting process. Investigations demonstrated that the low silica melts (higher Ca and Al contents) were produced at upper levels of high temperature combustion chamber HTCC, at narrower temperature ranges (1250-1350 degrees C), while the high silica melts formed at broader temperature ranges (1250-1450 degrees C), at the lower levels of HTCC. The recent temperature ranges were estimated by using CaOAl(2)O(3)SiO(2) (CAS) ternary liquidus diagram that are reasonably consistent with those reported for a typical combustor. It was also understood that the samples with a higher CaO/SiO(2) ratio (>0.74-0.75) have undergone improved melting, incipient crystallization of minerals, and extensive homogenization. The combined mineralogical and geochemical examinations provided evidence to accept the concept of stepwise generation of different melt phases within the HTCC. The petrogenesis of the melt products may therefore be described as a two-phase melt system with immiscible characteristics that have been successively generated during the melting process of MSW.