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Young Cheol Bae

University of Massachusetts Lowell

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Archive | 1999

Cationic Macromolecular Design Using Non(HOMO)Polymerizable Monomers

Young Cheol Bae; Savvas Hadjikyriacou; Helmut Schlaad; Rudolf Faust

The last half decade’s development in the cationic macromolecular using non(homo)polymerizable monomers is reviewed. This process involves the intermediate capping reaction of living polyisobutylene with non(homo)polymerizable monomers, such as 1,1-diphenylethylene derivatives or 2-alkylfurans. Kinetic and mechanistic aspects of this capping reaction is discussed, and an overview of capping and coupling reactions is presented as advanced tools for the cationic design of macromolecular structures and properties. Examples are given for the synthesis of functional polymers, block copolymers, star-block copolymers, and macromonomers.

Macromolecules | 1998

Living Coupling Reaction in Living Cationic Polymerization. 2. Synthesis and Characterization of Amphiphilic A2B2 Star−Block Copolymer: Poly[bis(isobutylene)-star-bis(methyl vinyl ether)]

Young Cheol Bae; Rudolf Faust

Macromolecules | 1998

Temperature Effects on the Living Cationic Polymerization of Isobutylene: Determination of Spontaneous Chain-Transfer Constants in the Presence of Terminative Chain Transfer

Zsolt Fodor; Young Cheol Bae; Rudolf Faust

Macromolecules | 1997

β-Proton Elimination by Free Bases in the Living Carbocationic Polymerization of Isobutylene

Young Cheol Bae; Rudolf Faust

Macromolecular Symposia | 1998

The role of pyridine derivatives in living carbocationic polymerization: Lewis base or nucleophile?

Young Cheol Bae; Rudolf Faust

Macromolecules | 1997

Living coupling reaction in living cationic polymerization. 1. Coupling reaction of living polyisobutylene

Young Cheol Bae; and Zsolt Fodor; Rudolf Faust

Macromolecules | 1998

Addition reaction of living polyisobutylene to double diphenylethylenes. Synthesis of 1,1-diphenylethylene-functionalized polyisobutylene macromonomers

Young Cheol Bae; Rudolf Faust

Archive | 1997

Capping of Polyisobutylene with 1,1-Diphenylethylene and Its Derivatives: Kinetic and Mechanistic Studies

Young Cheol Bae; Zsolt Fodor; Rudolf Faust

Archive | 1997

Coupling Reaction of Living Polyisobutylene Using Bis(diphenylethenyl) Compounds as Coupling Agents

Young Cheol Bae; Simion Coca; P. L. Canale; Rudolf Faust

Macromolecular Symposia | 1996

Synthetic applications of non-polymerizable monomers in living carbocationic polymerization; recent developments

Savvas Hadjikyriacou; D. Li; Young Cheol Bae; Rudolf Faust

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Rudolf Faust

University of Massachusetts Lowell

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Savvas Hadjikyriacou

University of Massachusetts Lowell

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Zsolt Fodor

University of Massachusetts Lowell

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D. Li

University of Massachusetts Lowell

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Il‐Jin Kim

University of Massachusetts Lowell

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Simion Coca

Carnegie Mellon University

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Helmut Schlaad

University of Potsdam

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