Youngsuk Nam

A nanophotonic solar thermophotovoltaic device

The most common approaches to generating power from sunlight are either photovoltaic, in which sunlight directly excites electron-hole pairs in a semiconductor, or solar-thermal, in which sunlight drives a mechanical heat engine. Photovoltaic power generation is intermittent and typically only exploits a portion of the solar spectrum efficiently, whereas the intrinsic irreversibilities of small heat engines make the solar-thermal approach best suited for utility-scale power plants. There is, therefore, an increasing need for hybrid technologies for solar power generation. By converting sunlight into thermal emission tuned to energies directly above the photovoltaic bandgap using a hot absorber-emitter, solar thermophotovoltaics promise to leverage the benefits of both approaches: high efficiency, by harnessing the entire solar spectrum; scalability and compactness, because of their solid-state nature; and dispatchablility, owing to the ability to store energy using thermal or chemical means. However, efficient collection of sunlight in the absorber and spectral control in the emitter are particularly challenging at high operating temperatures. This drawback has limited previous experimental demonstrations of this approach to conversion efficiencies around or below 1% (refs 9, 10, 11). Here, we report on a full solar thermophotovoltaic device, which, thanks to the nanophotonic properties of the absorber-emitter surface, reaches experimental efficiencies of 3.2%. The device integrates a multiwalled carbon nanotube absorber and a one-dimensional Si/SiO2 photonic-crystal emitter on the same substrate, with the absorber-emitter areas optimized to tune the energy balance of the device. Our device is planar and compact and could become a viable option for high-performance solar thermophotovoltaic energy conversion.

Fabrication and Characterization of the Capillary Performance of Superhydrophilic Cu Micropost Arrays

We report the fabrication of dense arrays of super-hydrophilic Cu microposts at solid fractions as high as 58% and aspect ratios as high as four using electrochemical deposition and chemical oxidation techniques. Oxygen surface plasma treatments of photoresist molds and a precise control of the initial electrodeposition current are found to be critical in creating arrays of nearly defect-free Cu posts. The capillary performance of the micropost arrays is characterized using capillary rate of rise experiments and numerical simulations that account for the finite curvatures of liquid menisci. For the given wick morphology, the capillary performance generally decreases with increasing solid fraction and is enhanced by almost an order of magnitude when thin nanostructured copper oxide layers are formed on the post surface. The present work provides a useful starting point to achieve optimal balance between the capillary performance and the effective thermal conductivity of advanced wicks for micro heat pipes.

Energy and hydrodynamic analyses of coalescence-induced jumping droplets

We report our dynamic analysis of coalescence-induced jumping on superhydrophobic surfaces with a full 3D numerical model supported with experiments. The analysis shows that approximately half (40%–60%) of the released surface energy during the coalescence is converted to kinetic energy before the detachment starts. The rapid increase in the kinetic energy at the beginning is initiated from low pressure associated with the high negative curvature of a liquid bridge. The asymmetric nature of the droplet evolution with a superhydrophobic wall generates high pressure at the bottom, which provides driving force to make the merged droplet spontaneously jump from the wall.

Bubble nucleation on hydrophobic islands provides evidence to anomalously high contact angles of nanobubbles

We observe stable steady-periodic vapor bubble nucleation on islands of nanoscopically smooth hydrophobic materials microfabricated on a silicon substrate. The minimum surface superheat required for the onset of bubble nucleation is very low (∼9 °C), which cannot be explained by the established models of heterogeneous bubble nucleation. A modified bubble nucleation model indicates that the observed minimum superheat can be explained when one assumes the existence of a nanoscale interfacial gas phase with anomalously high contact angles (>160°). Our data therefore provide independent evidence that supports previous atomic force microscopy and infrared spectroscopy studies of the topography of nanobubbles.

A comparative study of the morphology and wetting characteristics of micro/nanostructured Cu surfaces for phase change heat transfer applications

A comparative study of oxidation methods to create Cu surfaces with controlled wettability is reported. Micro/nanostructures of Cu oxides are formed on Cu substrates using different chemical and thermal oxidation methods. The morphology and wetting characteristics of the resulting surfaces are characterized using atomic force microscopy, scanning electron microscopy, X-ray diffraction, and contact angle measurements. Chemical oxidation in alkali solutions can form uniform copper oxide layers with high roughness factors without causing thermal stress problems that often hamper thermal oxidation. By combining chemical oxidation with a hydrophobic coating, a wide range of wettability control is demonstrated from superhydrophilic (  < 10°) to superhydrophobic (  > 170°). Superhydrophilic CuO layers uniformly formed on Cu powder and Cu micropost wick surfaces lead to significant improvement in the capillary and heat transfer performance compared with comparable unoxidized Cu wicks. The present work motivates further studies to exploit the benefits of nanostructured Cu surfaces in various phase change heat transfer applications.

The effects of surface wettability on the fog and dew moisture harvesting performance on tubular surfaces

The efficient water harvesting from air-laden moisture has been a subject of great interest to address world-wide water shortage issues. Recently, it has been shown that tailoring surface wettability can enhance the moisture harvesting performance. However, depending on the harvesting condition, a different conclusion has often been reported and it remains unclear what type of surface wettability would be desirable for the efficient water harvesting under the given condition. Here we compare the water harvesting performance of the surfaces with various wettability under two different harvesting conditions–dewing and fogging, and show that the different harvesting efficiency of each surface under these two conditions can be understood by considering the relative importance of the water capturing and removal efficiency of the surface. At fogging, the moisture harvesting performance is determined by the water removal efficiency of the surface with the oil-infused surfaces exhibiting the best performance. Meanwhile, at dewing, both the water capturing and removal efficiency are crucial to the harvesting performance. And well-wetting surfaces with a lower barrier to nucleation of condensates exhibit a better harvesting performance due to the increasing importance of the water capture efficiency over the water removal efficiency at dewing.

Drop impact dynamics on oil-infused nanostructured surfaces.

We experimentally investigated the impact dynamics of a water drop on oil-infused nanostructured surfaces using high-speed microscopy and scalable metal oxide nano surfaces. The effects of physical properties of the oil and impact velocity on complex fluid dynamics during drop impact were investigated. We show that the oil viscosity does not have significant effects on the maximal spreading radius of the water drop, while it moderately affects the retraction dynamics. The oil viscosity also determines the stability of the infused lubricant oil during the drop impact; i.e., the low viscosity oil layer is easily displaced by the impacting drop, which is manifested by a residual mark on the impact region and earlier initiation of prompt splashing. Also, because of the liquid (water)-liquid (oil) interaction on oil-infused surfaces, various instabilities are developed at the rim during impact under certain conditions, resulting in the flower-like pattern during retraction or elongated filaments during spreading. We believe that our findings will contribute to the rational design of oil-infused surfaces under drop impact conditions by illuminating the complex fluid phenomena on oil-infused surfaces during drop impact.

Influence of Geometric Patterns of Microstructured Superhydrophobic Surfaces on Water-Harvesting Performance via Dewing

On superhydrophobic (SHPo) surfaces, either of two wetting states-the Cassie state (i.e., nonwetted state) and the Wenzel state (i.e., wetted state)-can be observed depending on the thermodynamic energy of each state and external conditions. Each wetting state leads to quite a distinctive dynamic characteristic of the water drop on SHPo surfaces, and it has been of primary interest to understand or induce the desirable wetting state for relevant thermofluid engineering applications. In this study, we investigate how the wetting state of microstructured SHPo surfaces influences the water-harvesting performance via dewing by testing two different patterns, including posts and grates with varying structural parameters. On grates, the observed Cassie wetting state during condensation is well described by the thermodynamic energy criteria, and small condensates can be efficiently detached from the surfaces because of the small contact line pinning force of Cassie droplets. Meanwhile, on posts, the observed wetting state is dominantly the Wenzel state regardless of the thermodynamic energy of each state, and the condensates are shed only after they grow to a sufficiently large size to overcome the much larger pinning force of the Wenzel state. On the basis of the mechanical force balance model and energy barrier consideration, we attribute the difference in the droplet shedding characteristics to the different dynamic pathway from the Wenzel state to the Cassie state between posts and grates. Overall, the faster droplet shedding helps to enhance the water-harvesting performance of the SHPo surfaces by facilitating condensation on the droplet-free area, as evidenced by the best water-harvesting performance of grates on the Cassie state among the tested surfaces.

Drag reduction in Stokes flows over spheres with nanostructured superhydrophilic surfaces

Nanostructured surfaces offer opportunities to modify flow induced drag on solid objects. Measurements of the terminal velocity reveal that the drag associated with laminar Stokes flows can be reduced for spheres with nanostructured superhydrophilic as well as superhydrophobic surfaces. Numerical simulations suggest that the formation of recirculating or nearly stagnant flow zones leads to significant reduction in the friction drag. Such reduction, however, is offset by an increase in the form drag that arises from nonuniform pressure distributions. Our work motivates further studies to optimally balance the friction and form drag and control resistance to laminar flows over objects with nanostructured surfaces.

Comparative Study of Copper Oxidation Schemes and Their Effects on Surface Wettability

We present a comparative study of different oxidation methods for Cu, focusing on their effects on surface wettability for potential heat transfer applications. Various Cu2 O/CuO nanostructures are formed on copper substrates using thermal and chemical oxidation methods. The morphology and chemical composition of the oxide layers are investigated using atomic force microscopy, scanning electron microscopy, and X-ray diffraction measurements. To evaluate the surface wettability, static contact angles are measured before and after each oxidation process. In thermal oxidation, the contact angle can be tailored from ∼15° to ∼90° by varying heating time (10 min ∼ 4 hrs) and temperature (150–250 °C). Chemical oxidation processes using hot alkali solutions yield stable CuO nanostructures with high roughness factors and unique morphologies, which cause significant changes in wettability. Both superhydrophilic and superhydrophobic surfaces are demonstrated using the chemical oxidation methods.© 2008 ASME