Yu-Ping Sun

Numerical analysis on optical limiting performance of a series of phthalocyanines for nanosecond pulses

The optical limiting properties of a series of peripherally substituted phthalocyanines with different central metals and axial chloride ligand for nanosecond pulses have been studied by solving nu ...

Rotational Doppler Effect: A Probe for Molecular Orbitals Anisotropy

The vibrationally resolved X-ray photoelectron spectra of X2Σg+(3σg−1) and B2Σu+(2σu−1) states of N2+ were recorded for different photon energies and orientations of the polarization vector. Clear dependencies of the spectral line widths on the X-ray polarization as well as on the symmetry of the final electronic states are observed. Contrary to the translational Doppler, the rotational Doppler broadening is sensitive to the photoelectron emission anisotropy. On the basis of theoretical modeling, we suggest that the different rotational Doppler broadenings observed for gerade and ungerade final states result from a Youngs double-slit interference phenomenon.

Slowdown and compression of a strong X-ray free-electron pulse propagating through the Mg vapors

Here we study the propagation of a strong X-ray free-electron pulse through the resonant medium of atomic Mg accompanied by the self-seeded stimulated resonant X-ray Raman scattering. The X-ray pul ...

The propagation of a strong x-ray pulse followed by pulse slowdown and compression, amplified spontaneous emission and lasing without inversion

We study self-seeded stimulated resonant x-ray Raman scattering and show a 20-fold compression of the strong XFEL pulse propagating through the resonant medium of atomic argon with the frequency (2 ...

Raman Scattering at Resonant or Near-Resonant Conditions: A Generalized Short-Time Approximation

We investigate the dynamics of resonant Raman scattering in the course of the frequency detuning. The dephasing in the time domain makes the scattering fast when the photon energy is tuned from the absorption resonance. This makes frequency detuning to act as a camera shutter with a regulated scattering duration and provides a practical tool of controlling the scattering time in ordinary stationary measurements. The theory is applied to resonant Raman spectra of a couple of few-mode model systems and to trans-1,3,5-hexatriene and guanine-cytosine (G-C) Watson-Crick base pairs (DNA) molecules. Besides some particular physical effects, the regime of fast scattering leads to a simplification of the spectrum as well as to the scattering theory itself. Strong overtones appear in the Raman spectra when the photon frequency is tuned in the resonant region, while in the mode of fast scattering, the overtones are gradually quenched when the photon frequency is tuned more than one vibrational quantum below the first absorption resonance. The detuning from the resonant region thus leads to a strong purification of the Raman spectrum from the contamination by higher overtones and soft modes and purifies the spectrum also in terms of avoidance of dissociation and interfering fluorescence decay of the resonant state. This makes frequency detuning a very useful practical tool in the analysis of the resonant Raman spectra of complex systems and considerably improves the prospects for using the Raman effect for detection of foreign substances at ultra-low concentrations.