Yu-Sheng Tsai

Top Emission Organic Light-Emitting Diodes with Double-Metal-Layer Anode

In this study, we investigated the optimum thicknesses of organic light-emitting diode (OLED) layers using a high-reflectivity metal, Al, coupled with high-work-function alloys, e.g., AuSn, AuGe, and AuGeNi, as anodes, and LiF/Al/Ag multilayers as cathodes. The work function of a double-metal-layer, Al/AuGeNi (60/2 nm), was measured to be 4.7 eV, which is higher than that of a single Al layer of 4.2 eV. A high-work-function anode increased the number of holes injected from the anode into a hole transport layer and hence increased luminescence efficiency. After the optimization of each organic layer thickness, the device produced a maximum luminance of 2930 cd/m2 and a maximum luminance yield of 1.4 cd/A, which are the significant improvements of the performance characteristics of 537 cd/m2 and 0.28 cd/A obtained before the optimization of organic thickness, when the single Al layer was used as an anode, the device only exhibited a luminescence of 190 cd/m2 and a short lifetime.

Efficient Solution-Processed Green Phosphorescent Organic Light-Emitting Diodes Using Bipolar Host Material

Solution-based processing was applied to fabricate green phosphorescent organic light-emitting diodes (OLEDs). EPH31 was used as a phosphorescent host, doped with guest dopant green phosphorescent Ir(ppy)3, and dissolved in chlorobenzene solvent to form the emitting layer. Device structural parameters were controlled by changing the spin coating speed of the emitting layer and hole injection layer [poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate), PDOT:PSS] to adjust the thickness of the electron transport layer [tris(8-hydroxyquinolinato)aluminum, Alq3]. In addition, the differences in using CsF and LiF materials as the electron injection layer were investigated. A maximum current efficiency of 13.6 cdA-1 was obtained at a high emitting layer spin coating speed. Despite the close resemblance in both the luminance intensity and current efficiency when using CsF and LiF as the electron injection layer, CsF devices had a low driving voltage. Smooth and stable films resulting from the spin coated hole injection layer, along with the control of the thickness of the electron transport layer (Alq3) and electron injection layer (CsF), effectively improved the performance of green OLEDs. The emitting layer host material (CBP) and three guest dopants [Firpic, Ir(ppy)3, and Ir(piq)2] were dissolved in toluene solvent during solution preparation to fabricate white OLEDs. The properties of the resulting solution-processed white PHOLEDs are a current efficiency of 2.4 cdA-1 at 20 mAcm-2 and CIE coordinates of (0.33, 0.33) at 9 V. Results of these experiments demonstrate that solution processing can be used as an alternative to and in conjunction with thermal evaporation.

Power Efficiency Improvement of White Phosphorescent Organic Light-Emitting Diode with Thin Double-Emitting Layers and Hole-Trapping Mechanism

This study is carried out to discuss how to reduce the driving voltage of blue phosphorescent organic light-emitting diodes (PHOLEDs) by using a thin double-emission layer. A hole transport-type host (TCTA) is inserted between the hole transport layer (TAPC) and the emitting layer (EML), constituting a buffer layer between them with the aim of improving charge carrier balance. Furthermore, in this study, we also utilize the interface between double light-emitting layers of devices by codoping them with a red phosphorescent dopant [Os(bpftz)2(PPh2Me)2]. An Os complex with a high-lying highest occupied molecular orbital (HOMO) energy level (trapping holes) is codoped at the interface between emitting layers and an exciton-formation zone is expanded to obtain a white PHOLED with high efficiency. From the results, the optimal structure of the white device exhibits a yield of 35 cd A-1, a power efficiency of 22 lm W-1, and CIE coordinates of (0.33,0.38) at a luminance of 1000 cd m-2. Furthermore, the power efficiency can be improved to 30 lm W-1 by attaching the outcoupling enhancement film.

Easy Process and Performance Improvement for Top-Emission Organic Light-Emitting Diodes by Using UV Glue as the Insulation Layer on Copper Substrate

A high heat dissipation material (copper, Cu) was employed as the substrate for top emission organic light-emitting diodes (TEOLEDs). The UV glue was spin-coated onto the Cu substrate as the insulation layer to effectively improve Cu surface roughness and reduce process complexity. From the optoelectronic results, the optimized device with the Cu substrate shows the maximum luminance of 14110 cd/m2 and luminance efficiency of 7.14 cd/A. The surface and junction temperatures are measured to discuss the heat-dissipating effect on device performance. From the results, TEOLED fabricated on a Cu substrate has lower junction (55.34°C) and surface (25.7°C) temperatures, with the lifetime extended seven times. We employed Cu foil as the substrate for flexible TEOLED with maximum luminance of 10310 cd/m2 and luminance efficiency of 7.3 cd/A obtained.

Lifetime Improvement of Organic Light Emitting Diodes using LiF Thin Film and UV Glue Encapsulation

This work demonstrates the use of lithium fluoride (LiF) as a passivation layer and a newly developed UV glue for encapsulation on the LiF passivation layer to enhance the stability of organic light-emitting devices (OLEDs). Devices with double protective layers showed a 25-fold increase in operational lifetime compared to those without any packaging layers. LiF has a low melting point and insulating characteristics and it can be adapted as both a protective layer and pre-encapsulation film. The newly developed UV glue has a fast curing time of only 6 s and can be directly spin-coated onto the surface of the LiF passivation layer. The LiF thin film plus spin-coated UV glue is a simple packaging method that reduces the fabrication costs of OLEDs.

Efficiency Improvement of Organic Solar Cells by Slow Growth and Changing Spin-Coating Parameters for Active Layers

The derivatives of C60, [6,6]-phenyl C61-butyric acid methyl ester (PCBM), and 3-hexylthiophene (P3HT) were dissolved in o-dichlorobenzene (DCB) solvent, and then spin-coated as an active layer for polymer solar cells. The experimental parameters including the spin-coating speed and drying conditions for the active layer, were studied carefully to obtain the optimum power conversion efficiency (PCE). In the active layer drying procedure, the DCB solvent saturated/unsaturated vapor pressure was adjusted by controlling the amount of solvent at a half-open capacity. The DCB solution was used to enhance the self-organization of the active layer of P3HT and to reduce the number of pure PCBM clusters. In the DCB optimum solution, the PCE of a polymer solar cell can be increased from 1.36 to 1.79%. The structure corresponds to a nano-to-micron scale ordering in the unsaturation-treatment films. In the optimum unsaturation procedure, the PCE of a polymer solar cell can be increased from 1.79 to 2.53%. Using two steps with optimum rotation speeds in the active layer spin-coating, the surface uniformity can be improved, with the PCE increased from 2.53 to 3.13%.

Material Structure Selection of Solution Blue OLEDs Using a Design of Experiment

A blue small-molecular organic light-emitting diode (SM-OLEDs) based on a solution-process is investigated in this study. Design of experiment (DOE) with response surface methodology (RSM) was applied to optimize the driving voltage and current efficiency of blue SM-OLED devices. The spin-coating speed of the PEDOT: PSS as hole injection layer and the 26DCzPPy: FIrpic as emitting layer were chosen as two main process input factors. Analysis of variance (ANOVA) was adopted to identify significant factors before regression models were obtained. The optimal material structure was determined by minimizing and maximizing a desirability function relating to selected critical quality characteristics including the driving voltage and current efficiency, respectively.

Current–Voltage Numerical Simulation of Organic Light Emitting Diodes with Dual-Layer Structures

The use of numerical simulation method to study the current–voltage (I–V) of organic light emitting diode (OLED) has always been an effective method to upgrade the luminous efficiency of OLED. As the I–V theoretical simulation equations are based on injected carrier passing through Schottky barrier, and considering that carrier capturing defect and carrier mobility rate might be generated within the inner organic layer of Pool–Frenkel model, the study had made a comparison between the I–V theoretical model with a double-layer device and the experimental data, and proposed the best parameters for the theoretical model after careful adjustment and comparison to establish an optimal simulated numerical model with a double-layer OLED current–voltage. Finally, a study was made on the carrier capturing defect and mobility rate affected by electric field and temperature.

Blue Fluorescent Organic Light-Emitting Diodes with Optimized Electron Transportation Layer

In this research, the optimization of device structures of blue fluorescent organic light emitting diode (OLED) with WBH-301 doped with WBD-701 was fabricated. By adjusting the thickness of each layer in OLED structure as well as total thickness of device, the position of recombination zone was controlled and located in the central region of emitting layer (EML) that significantly increases device efficiency. The device showed the current efficiency of 8.7 cd/A at current density 50 mA/cm2 and with Commission Internationale de L’Eclairage (CIE) coordinates (x = 0.17, y = 0.34). This efficiency enhancement is important for understanding and further improving high-performance fluorescent OLEDs.

Top-Emission Organic Light Emitting Diode Fabrication Using High Dissipation Graphite Substrate

This study uses a synthetic graphite fiber as the heat dissipation substrate for top-emission organic light emitting diode (TEOLED) to reduce the impact from joule heat. UV glue (YCD91) was spin coated onto the substrate as the insulation layer. The TEOLED structure is (glass; copper; graphite) substrate/YCD91 glue/Al/Au/EHI608/TAPC/Alq3/LiF/Al/Ag. The proposed graphite fiber substrate presents better luminous performance compared with glass and copper substrate devices with luminance of 3055 cd/m2 and current efficiency of 6.11 cd/A at 50 mA/cm2. When lighting period of different substrates TEOLED, the substrate case back temperature was observed using different lighting periods. A glass substrate element operating from 5 to 25 seconds at 3000 cd/m2 luminance produced a temperature rate of 1.207°C/sec. Under 4000 cd/m2 luminance the copper and graphite substrate temperature rates were 0.125°C/sec and 0.088°C/sec. Graphite component lifetime was determined to be 1.875 times higher than the glass components and 1.125 times higher than that of copper.