Yudong Liu

Flexible Self-Powered GaN Ultraviolet Photoswitch with Piezo-Phototronic Effect Enhanced On/Off Ratio

Flexible self-powered sensing is urgently needed for wearable, portable, sustainable, maintenance-free and long-term applications. Here, we developed a flexible and self-powered GaN membrane-based ultraviolet (UV) photoswitch with high on/off ratio and excellent sensitivity. Even without any power supply, the driving force of UV photogenerated carriers can be well boosted by the combination of both built-in electric field and piezoelectric polarization field. The asymmetric metal-semiconductor-metal structure has been elaborately utilized to enhance the carrier separation and transport for highly sensitive UV photoresponse. Its UV on/off ratio and detection sensitivity reach to 4.67 × 10(5) and 1.78 × 10(12) cm·Hz(0.5) W(1-), respectively. Due to its excellent mechanical flexibility, the piezoelectric polarization field in GaN membrane can be easily tuned/controlled based on piezo-phototronic effect. Under 1% strain, a stronger and broader depletion region can be obtained to further enhance UV on/off ratio up to 154%. As a result, our research can not only provide a deep understanding of local electric field effects on self-powered optoelectronic detection, but also promote the development of self-powered flexible optoelectronic devices and integrated systems.

Lattice Strain Induced Remarkable Enhancement in Piezoelectric Performance of ZnO-Based Flexible Nanogenerators

In this work, by employing halogen elements (fluorine, chlorine, bromine, and iodine) as dopant we demonstrate a unique strategy to enhance the output performance of ZnO-based flexible piezoelectric nanogenerators. For a halogen-doped ZnO nanowire film, dopants and doping concentration dependent lattice strain along the ZnO c-axis are established and confirmed by the EDS, XRD, and HRTEM analysis. Although lattice strain induced charge separation was theoretically proposed, it has not been experimentally investigated for wurtzite structured ZnO nanomaterials. Tuning the lattice strain from compressive to tensile state along the ZnO c-axis can be achieved by a substitution of halogen dopant from fluorine to other halogen elements due to the ionic size difference between dopants and oxygen. With its focus on a group of nonmetal element induced lattice strain in ZnO-based nanomaterials, this work paves the way for enhancing the performance of wurtzite-type piezoelectric semiconductor nanomaterials via lattice strain strategy which can be employed to construct piezoelectric nanodevices with higher efficiency in a cost-effective manner.

Magnetic‐Mechanical‐Electrical‐Optical Coupling Effects in GaN‐Based LED/Rare‐Earth Terfenol‐D Structures

A multi-field coupling structure is designed and investigated, which combines GaN-based optoelectronic devices and Terfenol-D. The abundant coupling effects and multifunctionalities among magnetics, mechanics, electrics, and optics are investigated by a combination of non-magnetic GaN-based piezoelectronic optoelectronic characteristics and the giant magnetomechanical properties of Terfenol-D. A few potential new areas of studies are proposed.

A flexible p-CuO/n-MoS2 heterojunction photodetector with enhanced photoresponse by the piezo-phototronic effect

Flexible functional devices based on two dimensional (2D) materials are extremely suitable for malleable, portable and sustainable applications, such as health monitoring, electronic skin and optoelectronics. In this work, we developed a flexible photodetector based on a p-CuO/n-MoS2 heterojunction with an enhancement in photocurrent and detection sensitivity. Because of the non-centrosymmetric structure in monolayer MoS2, the piezo-potential induced by applied strain adjusts the band structure at the heterojunction interface and broadens the depletion region based on the piezo-phototronic effect. The border depletion can be discreetly used to improve the photo-generated carrier separation and transport to enhance photoresponse performance. When illuminated by a 532 nm laser, the photocurrent of the heterojunction can be enhanced 27 times under a tensile strain of 0.65% compared to strain free conditions and the detection sensitivity can reach up to 3.27 × 108 Jones. As a result, our research provides a new strategy for novel design and performance optimization of 2D material heterostructures in the application of optoelectronics.

Large perpendicular exchange bias in IrMn/CoFe/[Pt/Co] multilayers grown on a Ta/Pt buffer layer

Bottom pinned IrMn/[Co/Pt] multilayer films with relatively thin Pt layers (~10 A) grown on a Ta/Pt buffer have been found to exhibit favourable perpendicular exchange bias (PEB) and well-defined perpendicular anisotropy at room temperature. However, even the optimum film suffers from the same problem as those reported previously, i.e. the exchange bias field is just slightly larger than the coercivity. By replacing the Co layer in contact with IrMn by a 6–8 A Co60Fe40 layer, the exchange bias is drastically enhanced while the large perpendicular anisotropy is sustained and the coercivity changes little. The exchange bias field for the IrMn/CoFe/[Pt/Co] films with sufficient high perpendicular anisotropy can reach a value as high as 950 Oe, which is almost three times the coercivity, and the corresponding unidirectional anisotropy, 0.22 erg cm−2, considerably exceeds the best result at room temperature for various PEB systems ever reported. The present result suggests that PEB strongly depends on the composition of the ferromagnetic layer across the interface, which opens an effective avenue to boost PEB.

Piezotronic Effect Enhanced Flexible Humidity Sensing of Monolayer MoS2

We report the piezotronic effect on the performance of humidity detection based on a back-to-back Schottky contacted monolayer MoS2 device. By introducing an upswept mechanical strain, the in-plane electrical polarization can be induced at the MoS2/metal junction region. The polarization charges can modify the Schottky barrier height at the interface of MoS2/metal junction, subsequently improving the sensitivity of the humidity sensing. An energy band diagram is proposed to explain the experiment phenomenon of the humidity sensor. This work provides a simple way to enhance the sensitivity of ultrathin two-dimensional-materials-based sensors by the piezotronic effect, which has great potential applications in electronic skin, human-computer interfacing, gas sensing, and environment monitoring.

Magnetic‐Induced‐Piezopotential Gated MoS2 Field‐Effect Transistor at Room Temperature

Utilizing magnetic field directly modulating/turning the charge carrier transport behavior of field-effect transistor (FET) at ambient conditions is an enormous challenge in the field of micro-nanoelectronics. Here, a new type of magnetic-induced-piezopotential gated field-effect-transistor (MIPG-FET) base on laminate composites is proposed, which consists of Terfenol-D, a ferroelectric single crystal (PMNPT), and MoS2 flake. When applying an external magnetic field to the MIPG-FET, the piezopotential of PMNPT triggered by magnetostriction of the Terfenol-D can serve as the gate voltage to effectively modulate/control the carrier transport process and the corresponding drain current at room temperature. Considering the two polarization states of PMNPT, the drain current is diminished from 9.56 to 2.9 µA in the Pup state under a magnetic field of 33 mT, and increases from 1.41 to 4.93 µA in the Pdown state under a magnetic field of 42 mT and at a drain voltage of 3 V. The current on/off ratios in these states are 330% and 432%, respectively. This work provides a novel noncontact coupling method among magnetism, piezoelectricity, and semiconductor properties, which may have extremely important applications in magnetic sensors, memory and logic devices, micro-electromechanical systems, and human-machine interfacing.

Thermoacoustically driven triboelectric nanogenerator: Combining thermoacoustics and nanoscience

A thermoacoustic heat engine (TAHE) is a type of regenerative heat engine that converts external heat into mechanical power in the form of an acoustic wave with no moving mechanical components. One significant application of the TAHE is the generation of electricity by coupling an acoustic-to-electric conversion unit such as a linear motor or a piezoelectric ceramic assembly. However, present-day conversion technologies have considerable drawbacks, including structural complexity, high cost, and low reliability. The advent of triboelectric nanogenerators (TENGs) offers an alternative means to overcoming these shortcomings. In this paper, we propose a thermoacoustically driven TENG (TA-TENG) that continuously harvests external heat. A test rig involving a standing-wave TAHE and a contact-separation mode TENG was fabricated to demonstrate this concept. Currently, the TA-TENG produces a maximum output voltage of 10 V and a corresponding output power of 0.008 μW with a load of 400 MΩ, demonstrating the viabil...