Yuliang Chen

Synthesis of tin-doped indium oxide nanowires by self-catalytic VLS growth

In this paper, bulk-quantity tin-doped indium oxide nanowires were successfully synthesized by direct thermal evaporation of a mixture of In and SnO powders in air at 920?C. Such nanowires have a uniform shape and single crystalline cubic bixbite structure, with the diameters varying from 100 to 200?nm and lengths in the range of tens to hundreds of micrometres. The growth process of these ternary oxide nanowires can be interpreted by a self-catalytic vapour?liquid?solid growth mechanism. This approach to synthesizing ternary oxides should be readily extensible to preparing other multinary oxide nanowires, such as Cd2SnO4, Zn?Sn?In?O, Ga?In?Sn?O, Cd?In?Sn?O and Zn?Sn?Cd?O nanowires or nanobelts.

Sequential insulator-metal-insulator phase transitions of VO2 triggered by hydrogen doping

We report modulation of a reversible phase transition in VO2 films by hydrogen doping. A metallic phase and a new insulating phase are successively observed at room temperature as the doping concentration increases. It is suggested that the polarized charges from doped hydrogens play an important role. These charges gradually occupy V3d-O2p hybridized orbitals and consequently modulate the filling of the VO2 crystal conduction band-edge states, which eventually evolve into new valence band-edge states. This demonstrates the exceptional sensitivity of VO2 electronic properties to electron concentration and orbital occupancy, providing key information for the phase transition mechanism.

Non-catalytic hydrogenation of VO 2 in acid solution

Hydrogenation is an effective way to tune material property1-5. Traditional techniques for doping hydrogen atoms into solid materials are very costly due to the need for noble metal catalysis and high-temperature/pressure annealing treatment or even high energy proton implantation in vacuum condition5-8. Acid solution contains plenty of freely-wandering protons, but it is difficult to act as a proton source for doping, since the protons always cause corrosions by destroying solid lattices before residing into them. Here we achieve a facile way to hydrogenate monoclinic vanadium dioxide (VO2) with protons in acid solution by attaching suitable metal to it. Considering the Schottky contact at the metal/VO2 interface, electrons flow from metal to VO2 due to workfunction difference and simultaneously attract free protons in acid solution to penetrate, forming the hydrogens dopants inside VO2 lattice. This metal-acid treatment constitutes an electron-proton co-doping strategy, which not only protects the VO2 lattice from corrosion, but also causes pronounced insulator-to-metal transitions. In addition, the metal-acid induced hydrogen doping behavior shows a ripple effect, and it can spread contagiously up to wafer-size area (>2 inch) even triggered by a tiny metal particle attachment (~1.0mm). This will stimulate a new way of simple and cost-effective atomic doping technique for some other oxide materials.Hydrogenation is an effective way to tune the property of metal oxides. It can conventionally be performed by doping hydrogen into solid materials with noble-metal catalysis, high-temperature/pressure annealing treatment, or high-energy proton implantation in vacuum condition. Acid solution naturally provides a rich proton source, but it should cause corrosion rather than hydrogenation to metal oxides. Here we report a facile approach to hydrogenate monoclinic vanadium dioxide (VO2) in acid solution at ambient condition by placing a small piece of low workfunction metal (Al, Cu, Ag, Zn, or Fe) on VO2 surface. It is found that the attachment of a tiny metal particle (~1.0 mm) can lead to the complete hydrogenation of an entire wafer-size VO2 (>2 inch). Moreover, with the right choice of the metal a two-step insulator–metal–insulator phase modulation can even be achieved. An electron–proton co-doping mechanism has been proposed and verified by the first-principles calculations.Hydrogenation is an effective way to tune the property of metal oxides. Here, the authors report a simple approach to hydrogenate VO2 in acid solution under ambient conditions by placing a small piece of low workfunction metal on VO2 surface.

Dynamic Electronic Doping for Correlated Oxides by a Triboelectric Nanogenerator

The metal-insulator transition of vanadium dioxide (VO2 ) is exceptionally sensitive to charge density and electron orbital occupancy. Thus three-terminal field-effect transistors with VO2 channels are widely adopted to control the phase transition by external gating voltage. However, current leakage, electrical breakdown, or interfacial electrochemical reactions may be inevitable if conventional solid dielectrics or ionic-liquid layers are used, which possibly induce Joule heating or doping in the VO2 layer and make the voltage-controlled phase transition more complex. Here, a triboelectric nanogenerator (TENG) and a VO2 film are combined for a novel TENG-VO2 device, which can overcome the abovementioned challenges and achieve electron-doping-induced phase modulation. By taking advantage of the TENG structure, electrons can be induced in the VO2 channel and thus adjust the electronic states of the VO2 , simultaneously. The modulation degree of the VO2 resistance depends on the temperature, and the major variation occurs when the temperature is in the phase-transition region. The accumulation of electrons in the VO2 channel also is simulated by finite element analysis, and the electron doping mechanism is verified by theoretical calculations. The results provide a promising approach to develop a novel type of tribotronic transistor and new electronic doping technology.