Yurii M. Klimachev

The methods of singlet oxygen detection for DOIL program

The problem of development of a singlet delta oxygen O2(1Δg) (SDO) generators alternative to chemical one needs application of the accurate methods of measuring the SDO concentration. A chemical SDO generator providing efficient operation of a chemical oxygen-iodine laser (COIL) is proposed to be used as a reference source for absolute calibration of the system measuring the SDO concentration. The principle of the COIL operation results in the threshold and output COIL parameters make it possible to evaluate the SDO yield with a satisfactory accuracy. A convenient sparger chemical SDO generator was applied as a reference source for absolute calibration of detectors of dimole (λ=634nm) and b→X (λ=762 nm) radiations. The values of b-state concentration formed in a longitudinal electric discharge were evaluated. The intracavity laser spectroscopy (ICLS) was absolutely calibrated for measuring the SDO concentration. ICLS method has a very high sensitivity and makes it possible to monitor the absorption corresponding to the O2(1Δg)→O2(1Σg+) (λ = 1.91 μm) transition. The cross-sections of lines of the Q - branch of the vibrational 0-0 band of the a1Δg → b1Σg+ transition of molecular oxygen were measured. The method developed was applied to measure the concentration of singlet oxygen produced in the microwave discharge. He - Ne laser (λ = 633 nm) was used for absolute calibration of a system monitoring the dimole radiation. The rate constant of the process responsible for dimole emission was measured. The value obtained kd=7.34•10-23 cm3/s is in agreement with literature.

Singlet delta oxygen production in e-beam sustained discharge: theory and experiment

Singlet delta oxygen (SDO) production in a pulsed e-beam sustained discharge (EBSD) ignited in molecular oxygen with carbon monoxide stabilizing this discharge is theoretically and experimentally studied. Temporal behavior of SDO concentration and yield in the EBSD afterglow is analyzed. Experimentally measured SDO yield for oxygen mixture O2:Ar:CO=1:1:0.05 at total gas pressure 30 Torr comes up to 7% at specific input energy (SIE) of ~3.0 kJ/(1 atm(O2+CO)), whereas its theoretical value riches ~ 17.5%. The efficiency of SDO production is theoretically analyzed as function of the SIE.

Interaction of pulsed CO and CO2 laser radiation with rocks typical of an oil field

Experiments on laser-rock-fluid interactions have been carried out by using pulsed CO and CO2 lasers which irradiated rocks typical for oil field: sandstone, limestone, shale and granite. Energy fluence and laser intensity on rock surface were up to 1.0 kJ/cm2 and 107 W/cm2, respectively. The dependencies of specific energy consumption (i.e. energy per volume needed for rock excavation) on energy fluence, the number of pulses, saturated fluid, rock material and irradiation conditions have been obtained for various rock samples. The dependencies of momentum transferred to the rock on energy fluence for dry rocks and rocks with surface saturated by water or mineral oil have been measured. High-speed photography procedure has been used for analyzing laser plasma plume formation on a rock surface. Infrared spectra of reflectivity and absorption of rocks before and after irradiation have been measured.

Interaction of pulsed CO and CO2 laser radiation with rocks

Experiments on laser-rock-fluid interaction have been carried out by using pulsed CO and CO2 lasers which irradiated rocks typical for oil field: sandstone, limestone, shale and granite. Energy fluence and laser intensity on rock surface were up to 1.0 kJ/cm2 and 107W/cm2, respectively. The dependencies of specific energy consumption (i.e. energy per volume needed for rock excavation) on energy fluence, the number of pulses, saturated fluid, rock material and irradiation conditions have been obtained for various rock samples. The dependencies of momentum transferred to the rock on energy fluence for dry rocks and rocks with surface saturated by water or mineral oil have been measured. High-speed photography procedure has been used for analyzing laser plasma plume formation on a rock surface. Infrared spectra of reflectivity and absorption of rocks before and after irradiation have been measured.

Transverse gas flow RF slab discharge generator of singlet delta oxygen for oxygen-iodine laser

Results of experimental and theoretical study of singlet delta oxygen (SDO) production in transverse gas flow RF slab discharge for an electric discharge oxygen-iodine laser are presented. The electric discharge facility operating in both pulse-periodic and CW mode was manufactured: gas flow duct including multi-path cryogenic heat exchanger, dielectric slab channel, and slab electrode system incorporated in the channel for RF discharge ignition. Experiments on SDO production in transverse gas flow RF discharge were carried out. SDO production depending on gas mixture content and pressure, gas flow velocity, and RF discharge power was experimentally studied. It was shown that SDO yield increased with gas pressure decrease, gas flow deceleration and helium dilution of oxygen at the same input power. CW RF discharge was demonstrated to be the most efficient for SDO production as compared to pulse-periodic RF discharge with the same averaged input power. SDO yield was demonstrated to be not less than 10 percent. The model developed was further modified to do simulations of CW and pulse periodic RF discharges. A reasonable agreement between experimental and theoretical data on SDO production in CW and pulse-periodic RF discharges in oxygen is observed.

Electron-beam sustained discharge in oxygen gas mixtures: singlet delta oxygen production for oxygen-iodine laser

Electric properties and spectroscopy of an e-beam sustained discharge (EBSD) in oxygen and oxygen gas mixtures at gas pressure up to 100 Torr were experimentally studied. The pulsed discharge in pure oxygen and its mixtures with noble gases was shown to be very unstable and characterized by low input energy. When adding small amount of carbon monoxide or hydrogen, the electric stability of the discharge increases, specific input energy (SIE) per molecular component being more than order of magnitude higher and coming up to 6.5 kJ/(l atm) for gas mixture O2:Ar:CO = 1:1:0.1. The results of experiments on spectroscopy of the singlet delta oxygen O2(a1Δg)(SDO) and O2(b1Σg+) states in the EBSD are presented. The calibration of the optical scheme for measuring the SDO absolute concentration and yield using the detection of luminescence of the SDO going from a chemical SDO generator was done. The preliminary measurement of the SDO yield demonstrated that it was ~3% for the SIE of ~1 kJ/(l atm), which is close to the results of theoretical calculations for such a SIE. Theoretical calculations demonstrated that for the SIE of 6.5 kJ/(l atm) the SDO yield may reach ~20% exceeding its threshold value needed for oxygen-iodine laser operation at room temperature, although a part of the energy loaded into the EBSD goes into the vibrational energy of the molecular admixture, (which was experimentally demonstrated by launching a CO laser operating on an oxygen-rich mixture O2:Ar:CO = 1:1:0.1 and measuring its small-signal gain).

Application of CO laser for frequency selective surface heat treatment of polymer materials

Frequency selected Q-switched e-beam controlled-discharge CO- laser has been researched and developed for surface heat treatment of polymeric materials [poly(ethyleneterephthalate) and nylon] having strong absorption bands near wavelength of approximately 6 micrometer. The laser generates pulses (including short ones with duration (tau) 0.1 approximately 1 - 10 microsecond(s) ) having different spectral content within 4.9 - 6.5 micrometer spectral range. Different geometry and methods of irradiation were used to process samples with the laser radiation of different temporal, spectral and energy density characteristics. Different types of microstructure were formed on the surfaces of the samples. Experimental conditions corresponding to each type of microstructure were defined. Visual (macro) changes of polymeric material properties (if any) and their correlation with formed microstructures were analyzed.

MOPA carbon monoxide laser system emitting nanosecond pulses

A Master Oscillator - Power Amplifier (MOPA) carbon monoxide laser system emitting nanosecond pulses was developed on the basis of the wide-aperture pulsed electron-beam-sustained-discharge CO-laser facility. Amplification parameters including gain and saturation intensity of amplifying media consisted of gas mixtures CO : He or CO : Ar were measured. The MOPA system emitted a train of nanosecond pulses with peak power up to ~0.1MW on a single spectral line and up to ~0.4MW with multiline spectrum.

Electric properties, spectroscopy, and singlet delta oxygen yield of electron-beam sustained discharge in oxygen gas mixtures

Electric properties and spectroscopy of an e-beam sustained discharge (EBSD) in oxygen and oxygen gas mixtures at gas pressures up to 100 Torr was experimentally studied in large excitation volume (~18 liter). The discharge in pure oxygen and its mixtures with noble gases was shown to be very unstable and characterized by low input energy. When adding small amount of carbon monoxide or hydrogen, the electric stability of the discharge increases, specific input energy per molecular component being higher more than order of magnitude and coming up to 6.5 kJ/(l atm). Theoretical calculations demonstrated that for the experimental conditions the singlet delta oxygen yield may reach ~20% exceeding its threshold value needed for oxygen-iodine laser operation at room temperature. The results of experiments on spectroscopy of the singlet delta and singlet sigma oxygen states in the EBSD are presented.

Multiquantum VV-exchange modeling of the pulsed Q-switched frequency selected CO laser

The results are presented of computer modeling jointly with preliminary results of experimental investigations of sequentially Q-switched frequency selected CO laser. Calculations show the essential difference in pulse form and inversion restoration time between the models of single- and multi-quantum vibrational exchange kinetics.