Z.-M. Zong
China University of Mining and Technology
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Featured researches published by Z.-M. Zong.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2013
J. Zhou; Z.-M. Zong; Bo Chen; Zhu-Sheng Yang; Peng Li; Yao Lu; X.-M. Yue; X.-S. Cong; Y.-B. Wei; Yu-Gao Wang; Xing Fan; Y.-P. Zhao; Xian-Yong Wei
Shengli lignite was subjected to thermal dissolution in a methanol/benzene mixed solvent at 240°C for 1 h. The soluble fraction was sequentially eluted with petroleum ether and 5, 10, and 15% carbon disulfide/petroleum ether mixed solvents through a silica gel-packed column to afford eluted fractions 1 to 4 (EF1 to EF4). In total, 15 methyl alkanones from C15 to C27, including 2 methyl side-chain alkanones and 13 methyl straight-chain alkanones were enriched in EF4 and identified with gas chromatography/mass spectrometry.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2009
L. Zhou; Z.-M. Zong; S.-R. Tang; Y. Zong; Rui-Lun Xie; M.-J. Ding; Wei Zhao; X.-F. Zhu; Z.-L. Xia; L. Wu; X.-Y. Wei
Abstract Bio-oil prepared from flash pyrolysis of rice stalk around 500°C was upgraded by filtration and catalytic esterification. Both raw and upgraded bio-oils were observed with an optical microscope. The upgraded bio-oil was extracted with benzene, carbon disulfide, hexane, and carbon tetrachloride, respectively, and the soluble fractions were analyzed with FTIR and GC/MS. In addition, ion trap mass spectrometer was used for analysis of the benzene-soluble fraction. The results show that the upgrading substantially improved the dispersity of organic droplets in the bio-oil and completely removed char particles from the bio-oil, but heavy species are still the main components in the upgraded bio-oil; the soluble fractions contain aliphatic, benzene-ring-containing, ester, and bonded hydroxyl moieties, and methoxy-containing species are the most abundant GC/MS-detectable compounds.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2010
Y.-B. Wei; Z.-M. Zong; Rui-Lun Xie; Yaoli Peng; J. Mou; Yumiao Ma; Xiao Zhou; Yao-Guo Huang; L. Wu; X.-Y. Wei
Abstract Shengli coal liquefaction residue was demineralized; the demineralized Shengli coal liquefaction residue (DMSCLR) was then subject to non-catalytic and SO4 2−/ZrO2- or SO4 2−/TiO2-catalyzed hydroconversion in methanol under microwave irradiation. The results show that both, SO4 2−/ZrO2 and SO4 2−/TiO2, significantly catalyzed DMSCLR hydroconversion. The MESs of hydrogenated DMSCLR were analyzed with gas chromatography/mass spectrometer. The MESs and methanol-inextractable fractions of hydrogenated DMSCLR were characterized with Fourier transform infrared spectrometer.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2014
Zhan-Ku Li; Z.-M. Zong; Zhu-Sheng Yang; Hui-Long Yan; Xing Fan; X.-Y. Wei
Sequential thermal dissolution (STD) of Geting bituminous coal (GBC) in benzene, methanol, ethanol, and isopropanol was conducted at 150 to 300°C for 2 h. Anthracene was added into the system as the hydrogen acceptor to trace hydrogen transfer (HT) behavior during the STD. All of the soluble portions (SPs) were analyzed with a gas chromatograph/mass spectrometer. The once-through yields of SPs did not fluctuate obviously with raising the thermal dissolution (TD) temperature from 150 to 250°C, but significantly increased over 250°C. HT from GBC to anthracene in benzene, methanol, and ethanol occurred at 300°C and in isopropanol at 250°C. Unlike TD in benzene, alkanolysis significantly proceeded during TD in alkanols at 300°C.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2013
Da-Ling Shi; Xian-Yong Wei; Bo Chen; Yao Lu; L. Li; Yu-Gao Wang; Peng Li; L. Zhao; Z.-M. Zong; Wei Zhao; Xing Fan; Y.-P. Zhao
Geting bituminous coal was sequentially extracted with petroleum ether, carbon disulfide, methanol, acetone, and isometric carbon disulfide/acetone mixed solvent at room temperature, affording extracts 1 to 5 (E1 to E5). In total, 77 organooxygen compounds (OOCs) were identified from E3 by gas chromatography/mass spectrometry analysis. The OOCs include 4 alkanols, 8 arenols, 5 ethers, 5 aldehydes, 14 non-nitrogen ketones, 19 nitrogen-containing ketones, 11 alkanoic acids, and 11 esters. This investigation provides an effective approach to the enrichment of OOCs in coals, favoring understanding of the diversity of the organooxygen compounds.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2013
Peng Li; X.-Y. Wei; X.-H. Sun; Yao Lu; Z.-M. Zong; R. Mukasa; Yu-Gao Wang; Da-Ling Shi; L. Li; L. Zhao; Xing Fan; Y.-P. Zhao; J.-N. Hou; Q. C. Liu
Shenmu-Fugu subbituminous coal liquefaction residue was exhaustively extracted with petroleum ether (PE) to afford PE-extractable fraction (PEEF), which was then eluted with petroleum ether through a silica gel-filled column. The PEEF and eluates were analyzed with a gas chromatographer/mass spectrometer and a Fourier transform infrared spectrometer. As a result, a number of 4- to 7-ring condensed arenes (CAS) were detected in the PEEF series of 4- to 6-ring CAs along with long-chain alkanes were isolated from the PEEF by column chromatography.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2010
Z.-M. Zong; Jiawei Zhang; Rui-Lun Xie; Taoxia Wang; J. Gao; Youqing Wu; F.-C. Wang; Bao-Min Li; X.-Y. Wei
Abstract A series of chars were prepared by rapidly heating Shenfu coal, a Chinese bituminous coal, to different temperatures. Ash, volatile matter, and elemental contents of the chars were compared. The chars were extracted with carbon disulfide, benzene, and tetrahydrofuran sequentially, and the extraction solutions were analyzed with gas chromatography/mass spectrometer (GC/MS). The results show that raising charring temperature increases the ash and carbon contents, but decreases the hydrogen and nitrogen contents as well as the solubility, while change in sulfur content is very small with charring temperature. A series of alkanes and polycyclic arenes were detected in the extraction solutions.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2013
Yuelun Wang; X.-Y. Wei; X.-M. Yue; Bing Sun; Zhe Wen; Jing-Hui Lv; Shou-Ze Wang; Z.-M. Zong; Xing Fan; Y.-P. Zhao
Shengli lignite (SL) and Shenmu-Fugu subbituminous coal (SFSBC) were subjected to thermal dissolution in cyclohexane at 300°C for 1 h under hydrogen. The reaction mixtures were extracted with petroleum ether (PE) and the PE-extractable fractions (PEEFs) were analyzed with a gas chromatography/mass spectrometer. The results show that the PEEFs from thermally dissolved SL (TDSL) and thermally dissolved SFSBC (TDSFSBC) mainly consist of alkanes, alkenes, arenes, and oxygen-containing organic compounds (OCOCs); the yields of alkanes and alkenes in the PEEF from TDSFSBC are appreciably higher than those from TDSL, while the yields of arenes and oxygen-containing organic compounds in the petroleum ether-extractable fraction from thermally dissolved Shenmu-Fugu subbituminous coal are significantly lower than those from thermally dissolved Shengli lignite; arenols are dominant OCOCs in the PEEF from TDSL, while main OCOCs in the PEEFs from TDSFSBC are arenols and esters.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2013
Y.-B. Wei; Xian-Yong Wei; Li-Cheng Yu; Peng Li; Z.-M. Zong; Wei Zhao
Microwave-assisted hydroconversion of demineralized Shengli lignite liquefaction residue (DMSLLR) over Ni-B/SiO2 in methanol was investigated under mild conditions. The results show that Ni-B/SiO2 significantly catalyzed DMSLLR hydroconversion by increasing the methanol-extractable fraction of hydroconverted DMSLLR to 87.7% over Ni-B/SiO2 from 62.3% without catalyst. The yields of alkanes, hydroarenes, alkyl arenes, non-substituted arenes, organooxygen compounds, and organosulfur compounds from catalytic hydroconversion of DMSLLR are drastically higher than those from non-catalytic hydroconversion of DMSLLR. Benzo[ghi]perylene is the most abundant condensed arenes detected.
Energy Sources Part A-recovery Utilization and Environmental Effects | 2014
Man Ding; Y.-P. Zhao; Ying Zhu; Z.-M. Zong; X.-Y. Wei; Xing Fan
Shengli lignite (SL) and Xiaolongtan lignite (XL) were extracted with carbon disulfide, benzene, methanol, acetone, and tetrahydrofuran sequentially. The OFs of organinitrogen compounds in the lignites and their residues were characterized by X-ray photoelectron spectroscopic analysis, and the nitrogen-containing organic species in the extracts were identified with gas chromatography/mass spectrometer. The results show that pyridinic nitrogen Np, pyrrolic nitrogen Np′, quaternary nitrogen Nq, and oxidized nitrogen No are the four OFs of organic nitrogen in the two lignites, and the content of Np′ in XL is higher than that in SL. The relative contents (RCs) of pyridines and quinolines in the extracts from XL are higher than those from SL, while the RCs of amides and amines in the extracts from SL were higher than those from XL.