Zarina Yahya

Fly Ash-based Geopolymer Lightweight Concrete Using Foaming Agent

In this paper, we report the results of our investigation on the possibility of producing foam concrete by using a geopolymer system. Class C fly ash was mixed with an alkaline activator solution (a mixture of sodium silicate and NaOH), and foam was added to the geopolymeric mixture to produce lightweight concrete. The NaOH solution was prepared by dilute NaOH pellets with distilled water. The reactives were mixed to produce a homogeneous mixture, which was placed into a 50 mm mold and cured at two different curing temperatures (60 °C and room temperature), for 24 hours. After the curing process, the strengths of the samples were tested on days 1, 7, and 28. The water absorption, porosity, chemical composition, microstructure, XRD and FTIR analyses were studied. The results showed that the sample which was cured at 60 °C (LW2) produced the maximum compressive strength for all tests, (11.03 MPa, 17.59 MPa, and 18.19 MPa) for days 1, 7, and 28, respectively. Also, the water absorption and porosity of LW2 were reduced by 6.78% and 1.22% after 28 days, respectively. The SEM showed that the LW2 sample had a denser matrix than LW1. This was because LW2 was heat cured, which caused the geopolymerization rate to increase, producing a denser matrix. However for LW1, microcracks were present on the surface, which reduced the compressive strength and increased water absorption and porosity.

Effect of Solids-To-Liquids, Na2SiO3-To-NaOH and Curing Temperature on the Palm Oil Boiler Ash (Si + Ca) Geopolymerisation System

This paper investigates the effect of the solids-to-liquids (S/L) and Na2SiO3/NaOH ratios on the production of palm oil boiler ash (POBA) based geopolymer. Sodium silicate and sodium hydroxide (NaOH) solution were used as alkaline activator with a NaOH concentration of 14 M. The geopolymer samples were prepared with different S/L ratios (0.5, 1.0, 1.25, 1.5, and 1.75) and Na2SiO3/NaOH ratios (0.5, 1.0, 1.5, 2.0, 2.5, and 3.0). The main evaluation techniques in this study were compressive strength, X-Ray Diffraction (XRD), Fourier Transform Infrared Spectroscopy (FTIR), and Scanning Electron Microscope (SEM). The results showed that the maximum compressive strength (11.9 MPa) was obtained at a S/L ratio and Na2SiO3/NaOH ratio of 1.5 and 2.5 at seven days of testing.

Study on Physical and Chemical Properties of Fly Ash from Different Area in Malaysia

Fly ash is residue from the combustion of coal which widely available in worldwide and lead to waste management proposal. Moreover, the use of fly ash is more environmental friendly and save cost compared to OPC. Fly ash mostly consists of silicon dioxide (SiO2), aluminium oxide (Al2O3) and iron oxide (Fe2O3). The chemical compositions of the sample have been examined according to ASTM C618. Different sources of fly ash may result in different chemical composition. The fly ash is mainly an amorphous material with the presents of crystalline phase of quartz and mullite. Fly ash consists of mostly glassy, hollow and spherical particles.

Optimization of NaOH Molarity, LUSI Mud/Alkaline Activator, and Na2SiO3/NaOH Ratio to Produce Lightweight Aggregate-Based Geopolymer

This paper presents the mechanical function and characterization of an artificial lightweight geopolymer aggregate (ALGA) using LUSI (Sidoarjo mud) and alkaline activator as source materials. LUSI stands for LU-Lumpur and SI-Sidoarjo, meaning mud from Sidoarjo which erupted near the Banjarpanji-1 exploration well in Sidoarjo, East Java, Indonesia on 27 May 2006. The effect of NaOH molarity, LUSI mud/Alkaline activator (LM/AA) ratio, and Na2SiO3/NaOH ratio to the ALGA are investigated at a sintering temperature of 950 °C. The results show that the optimum NaOH molarity found in this study is 12 M due to the highest strength (lowest AIV value) of 15.79% with lower water absorption and specific gravity. The optimum LUSI mud/Alkaline activator (LM/AA) ratio of 1.7 and the Na2SiO3/NaOH ratio of 0.4 gives the highest strength with AIV value of 15.42% with specific gravity of 1.10 g/cm3 and water absorption of 4.7%. The major synthesized crystalline phases were identified as sodalite, quartz and albite. Scanning Electron Microscope (SEM) image showed more complete geopolymer matrix which contributes to highest strength of ALGA produced.

The Strength of Bottom Ash-Based Geopolymer Brick with Inclusion of Fly Ash

This paper studies the finding of compressive strength of bricks using bottom ash as a geopolymer raw material added with several percentages of fly ash, which act as a filler, besides can give better performance of strength to the bricks according to the chemical composition and the reaction of all the geopolymer materials. The study has been conducted to produce bottom ash-based geopolymer bricks by varying the percentage of fly ash added (20%, 40%, 60%, 80%) to the bottom ash-based geopolymer bricks in the mixing process. The compressive strength up to 13.69 MPa was obtained, the density is low at 20 % of fly ash added into the mixing and the water absorption is lower with the higher fly ash added using 70°C curing temperature within 24 hours at 7 days of ageing.

Mechanical Properties of Artificial Lightweight Geopolymer Aggregate (ALGA) Concreteusing Volcano Mud with Various Sintering Temperature

The mechanical propertiesof artificial lightweight geopolymer aggregate (ALGA) using volcano mud in concrete have been investigated at various sintering temperature. The volcano mud was mixed with alkaline activator, formed into spherical pellets, then sintered in the furnace at temperature of 500°C, 600°C, 700°C, 800°C, 900°C, 950°C, and 1000 °C. The lightweight concrete with density below than 1800 kg/m3 can be achieved at sintering temperature ALGA of 950 °C. The optimum compressive strength of 30.1 MPa was achieved at 28 days of testing. The lower water absorption of ALGA concrete was produced with 5-8 % in range.

Fly Ash Based Lightweight Geopolymer Concrete Using Foaming Agent Technology

This paper presents the mechanical properties of a lightweight geopolymer concrete synthesized by the alkali-activation of a fly ash source (FA) produced by mixing a paste of geopolymer with foam produced by using NCT Foam Generator. Two curing conditions are used, curing at room temperature and curing in an oven with a constant temperature which is 60 oC. Bulk density showed that fly ash-based geopolymer lightweight concrete is light with the density of 1225 kg/m3 - 1667 kg/m3 with an acceptable compressive strength of 17.60 MPa for the density of 1667 kg/m3.

Compressive Strength and Morphology of Fly Ash Based Geopolymer as Artificial Aggregate with Different Curing Temperature

This paper presented the compressive strength of geopolymer paste with different NaOH concentration and morphology analysis for sintered artificial aggregate. This artificial aggregate was produce based on mix design with highest compressive strength which is 12 M. The sample was cured at 70 °C for 24 hours and then it was exposed to different temperature at range 500 °C to 700 °C. Scanning Electron Microscopy (SEM) has been used to identify the formation of microstructure. The geopolymer artificial aggregate was an alternative ways to produce a greener environmental. In this study, the compressive strength for different Na2SiO3/NaOH ratio has been analyzed. The morphology for best mix design then were analyze for different curing temperature. The result shows fly ash based geopolymer paste with 12 M of NaOH concentration shows excellent result with 7.30 MPa at 2.5 ratio of Na2SiO3/NaOH and for geopolymer artificial aggregate, when temperature of heat treatment increased, the open porosity of porous geopolymer surface decreased.

Comparative study on early strength of sodium hydroxide (NaOH) activated fly ash based geopolymer

The urge to reduce carbon dioxide (CO2) emission has encourage researchers to introduce environmental friendly binder or known as geopolymer. This new binder was produced by mixing source materials rich in silica and alumina with alkaline liquids. For this study, class F fly ash was used as source material with two different types of alkaline activator; sodium hydroxide (NaOH) only and a combination of water glass with NaOH. The different concentration of the NaOH solutions (8M, 10M, 12M and 14M) is used in the production of geopolymer. The parameters such as curing regime, solid/liquid ratio, and water glass/NaOH ratio are controlled in the study. The samples with combination of NaOH and water glass as alkaline activator were prepared by mixing these two solution and stirred for 2 minutes. Then this solution were mixed together with fly ash for 3 minutes and casted in the mould. The performance of the fly ash based geopolymer are evaluated by the compressive strength, water absorption and density at the ...

Rice husk (RH) as additive in fly ash based geopolymer mortar

In recent year, the Ordinary Portland Cement (OPC) concrete is vastly used as main binder in construction industry which lead to depletion of natural resources in order to manufacture large amount of OPC. Nevertheless, with the introduction of geopolymer as an alternative binder which is more environmental friendly due to less emission of carbon dioxide (CO2) and utilized waste materials can overcome the problems. Rice husk (RH) is an agricultural residue which can be found easily in large quantity due to production of paddy in Malaysia and it’s usually disposed in landfill. This paper investigated the effect of rice husk (RH) content on the strength development of fly ash based geopolymer mortar. The fly ash is replaced with RH by 0%, 5%, 10%, 15% and 20% where the sodium silicate and sodium hydroxide was used as alkaline activator. A total of 45 cubes were casted and their compressive strength, density and water absorption were evaluated at 1, 3, and 7 days. The result showed compressive strength decrea...