Zhaoshan Chang

U‐Pb dating of zircon by LA‐ICP‐MS

In this study we used LA-ICP-MS (laser ablation–inductively coupled plasma–mass spectrometry) to determine U-Pb ages of 5 zircon samples of known age (∼1800 Ma to ∼50 Ma) in order to determine the reproducibility, precision, and accuracy of this geochronologic technique. This work was performed using a ThermoFinnigan Element2 magnetic sector double-focusing ICP-MS coupled with a New Wave Research UP-213 laser system. The laser ablation pit sizes ranged from 30 to 40 μm in diameter. Laser-induced time-dependent fractionation is corrected by normalizing measured ratios in both standards and samples to the beginning of the analysis using the intercept method. Static fractionation, including those caused during laser ablation and due to instrumental discrimination, is corrected using external zircon standards. Total uncertainty for each laser analysis of an unknown is combined quadratically from the uncertainty in the measured isotope ratios of the unknown and the uncertainty in the fractionation factors calculated from the measurement of standards. For individual analyses we estimate that the accuracy and precision are better than 4% at the 2 sigma level, with the largest contribution in uncertainty from the measurement of the standards. Accuracy of age determinations in this study is on the order of 1% on the basis of comparing the weighted average of the LA-ICP-MS determinations to the TIMS ages. Due to unresolved contributions to uncertainty from the lack of a common Pb correction and from potential matrix effects between standards and unknowns, however, this estimate cannot be universally applied to all unknowns. Nevertheless, the results of this study provide an example of the type of precision and accuracy that may be possible with this technique under ideal conditions. In summary, the laser ablation technique, using a magnetic sector ICP-MS, can be used for the U-Pb dating of zircons with a wide range of ages and is a useful complement to the established TIMS and SHRIMP techniques. This technique is especially well suited to reconnaissance geochronologic and detrital zircon studies.

Sulfur isotopes in sediment-hosted orogenic gold deposits: Evidence for an early timing and a seawater sulfur source

We report sulfur isotopic compositions of sulfides of various paragenetic stages in the giant Sukhoi Log sediment-hosted orogenic Au deposit in Russia. The overall mean value and the significant variability in early pyrite indicate that the sulfur was from the reduction of seawater sulfate. The later generations of sulfide have δ34S values in successively smaller ranges, coincident with the mode that is around the median value of the whole data set. Together with textural evidence, sulfide trace element data, and gold occurrence, the data demonstrate that metamorphism has gradually homogenized the early sulfur, accompanied by the segregation of quartz and the release of Au from the lattice of early pyrite and its reprecipitation as inclusions in later pyrite. The S isotopic compositions of sulfides in Sukhoi Log, and many other major orogenic Au deposits hosted in sedimentary rocks of various ages, show a pattern generally parallel to the seawater sulfate curve through geologic time, indicating that the sulfur in most sediment-hosted orogenic Au deposits was probably also originally from the reduction of seawater sulfate. We conclude that sulfidation and gold mineralization in many sediment-hosted orogenic gold deposits was early during basin evolution when seawater was the principal active fluid, rather than later, during or after basin inversion, as proposed in current models.

The Louzidian Normal Fault near Chifeng, Inner Mongolia: Master Fault of a Quasi-Metamorphic Core Complex

A special metamorphic core complex underlain by a low-angle strike-slip ductile shear zone is present near Chifeng in eastern Inner Mongolia, northern China. The geology of the study area is similar to that of several Cordilleran metamorphic core complexes, but contrasts in significant ways as well. A major ESE-dipping normal fault, the Louzidian Range frontal fault, formed during Late Cretaceous extension. This fault separates a crystalline footwall locally containing mylonitic basement gneisses and granitic rocks (0 to >3 km thick) from a non-metamorphic hanging wall that is distended by normal faults. However, the shear sense of the underlying mylonitic shear zone, a low-angle strike-slip zone, is not compatible with the Louzidian fault. It may be related to a pre-Cretaceous regional sinistral strike-slip event rather than the Late Cretaceous regional crustal extension common throughout eastern China. Pre-existing mylonitic fabric anisotropy appears to have controlled the development of the Louzidian normal fault. Chloritic breccias locally developed along the fault indicate that it cut deeply into the crust of northern China.

Geochronologic and isotope geochemical constraints on magmatism and associated W-Mo mineralization of the Jitoushan W-Mo deposit, middle-lower Yangtze Valley

The Jitoushan W–Mo ore body is a typical skarn-type deposit with the potential for porphyry Mo mineralization at depth. As it is newly discovered, only a few studies have been conducted on the geochronology and ore genesis of this deposit. The ore district consists of Cambrian to Silurian sedimentary and low-grade metasedimentary strata, intruded by granodiorite, diorite porphyry, granite porphyry, and quartz porphyry. Skarn W–Mo ore bodies are hosted in the contact zone between the granodiorite and Cambrian limestone strata. Within the granodiorite near the contact zone, quartz vein type and disseminated sulphide mineralization are well developed. The Mo-bearing granite porphyry has been traced at depth by drilling. Our results reveal two discrete magmatic events at ca. 138 and ca. 127 Ma in the study area. The molybdenite Re–Os isochronal age of 136.6 ± 1.5 million years is consistent with the first magmatic event. The zircon Hf isotope (ϵHf(t) = −12.55−3.91), sulphide isotopes (δ34S = 3.32–5.59‰), and Re content of molybdenite (Recontent = 6.424–19.07 μg) indicate that the ore-forming materials were mainly derived from the deep crust. The regional tectonic system switched from a Late Jurassic transpressive regime to an earliest Cretaceous extensional regime at ca. 145 Ma, and at ca. 138 Ma, the Jitoushan W–Mo deposit formed in an extensional setting.

Delineating the structural controls on the genesis of iron oxide–Cu–Au deposits through implicit modelling: a case study from the E1 Group, Cloncurry District, Australia

Abstract Iron oxide–Cu–Au (IOCG) deposits encompass a range of ore body shapes, including strata-bound replacement ores and hydrothermal breccias. We use the implicit method to make a detailed three-dimensional geological model of a strata-bound IOCG in the Cloncurry District, the E1 Group, to elucidate structural controls on mineralization. This model is compared with the nearby, world-class, Ernest Henry breccia-hosted IOCG deposit. Cu–Au mineralization in the E1 Group occurs as structurally controlled, mainly strata-bound, replacement bodies hosted in metasedimentary and metavolcaniclastic rocks intercalated with barren meta-andesite. Replacement bodies in the E1 Group conform to a series of NNW-plunging folds formed in regional D2 during peak metamorphism. Folding was followed by local D3/regional D4 shortening, which formed a dextral, transpressional Riedel brittle to ductile system along the regional Cloncurry Fault Zone. Modelling suggests that much of the Cu–Au mineralization is controlled by synthetic R structures associated with this Riedel system. The deformation sequence at Ernest Henry is comparable, but differences in host rock rheology, permeability and fluid pressure may explain the variation in ore body types and total Cu–Au resource between the two deposits. The results carry implications for other districts containing these styles of IOCG mineralization.

Chlorite chemistry as a new exploration tool in the propylitic halo of porphyry-epithermal systems: a case study of the Batu Hijau porphyry Cu-Au system, Indonesia

Department of Earth Sciences, Natural History Museum, Cromwell Road, London SW7 5BD, UK. j.wilkinson@nhm.ac.uk Department of Earth Science and Engineering, Imperial College London, Exhibition Road, London SW7 2AZ, UK. College of Science, Technology & Engineering, James Cook University, 1 James Cook Drive, Townsville, Queensland, Australia 4811 ARC Centre of Excellence in Ore Deposit Research, University of Tasmania, Private Bag 79, Hobart, Tasmania, Australia 7001 ___________________________________________________________________________

Endoskarn and Cu-Zn mineralization at the Empire mine, Idaho, USA

The Empire mine is a Cu-Zn skam associated with the granite porphyry phase of the Mackay Stock, which consists of quartz monzodiorite, granophyre, granite porphyry, Mackay Granite, and numerous dikes. Both granite porphyry and Mackay Granite have high F and also have unusual, extremely vermicular quartz phenocrysts. Both endoskarn and exoskam are developed at the Empire mine, with more endoskam than exoskarn. The alteration of the intrusive rocks began with weak disseminated diopsidic pyroxene, actinolite, and titanite. Further endoskam formed by veins or as massive replacements of intrusive rocks. The earliest formed endoskarn veinlets contain scapolite, with or without wollastonite halo. This was followed by wollastonite-dominant (± Carich plagioclas and hedenbergitic pyroxene) veins as fronts or envelopes on garnet-dominant veins. Early pyroxene is diopsidic whereas pyroxene in distal/late veinlets is hedenbergitic. Similarly, garnet becomes more Fe-rich with time. In exoskam, all the pyroxene is diopsidic and garnet andraditic. Magnetite precipitated after garnet-pyroxene in both endoskarn and exoskam. Zn sulfide precipitated together with Cu in proximal locations, associated with retrograde quartz+calcite+chlorite. Massive endoskarn and exoskarn replacement formed at 500–550°C, whereas slightly higher temperatures were recorded by late minerals at the metasomatic front, >600°C. The highest temperatures, >700°C, occur in gamet-dominant veins that probably represent conduits insulated by earlier skarn. During retrograde alteration, quartz, calcite, chlorite, fluorite, and chalcopyrite precipitated in both endoskarn and exoskarn at 250–300°C. The extremely vermicular texture of quartz phenocrysts, abundant endoskarn, and proximal deposition of Zn, are all caused by the high F contents of the magma and magmatic fluid.