Network


Latest external collaboration on country level. Dive into details by clicking on the dots.

Hotspot


Dive into the research topics where Zhigang Xu is active.

Publication


Featured researches published by Zhigang Xu.


Analytical and Bioanalytical Chemistry | 2016

Barbell-shaped stir bar sorptive extraction using dummy template molecularly imprinted polymer coatings for analysis of bisphenol A in water

Ruimei Liu; Feng Feng; Guolin Chen; Zhimin Liu; Zhigang Xu

This study reports the development of a novel dummy template molecularly imprinted polymer (MIP)-coated barbell-shaped stir bar. The MIP stir bar coatings were prepared by using 2,2-bis(4-hydroxyphenyl)butane (BPB), 4,4-dihydroxydiphenylmethane (BPF), 4-tert-butylphenol (PTBP), and tetrabromobisphenol A (TBBA) as dummy templates using a capillary in situ polymerization method. Uniform coatings can be prepared controllably. The method is simple, easy, and reproducible. The barbell-shaped stir bar was developed by using medical silicone tubes as wheels. The wheels could be removed and reinstalled when necessary; therefore, the barbell-shaped stir bar was easy to disassemble and reassemble. The novel MIP-coated stir bar showed good selectivity for the target analyte, bisphenol A (BPA). The established method is selective and sensitive with a lower detection limit for BPA of 0.003xa0μg/L. The dummy template MIP-coated stir bar is suitable for trace BPA analysis in real environmental water samples without template leakage. The novel stir bar can be used at least 100 times.


Analytical and Bioanalytical Chemistry | 2018

β-Cyclodextrin molecularly imprinted solid-phase microextraction coatings for selective recognition of polychlorophenols in water samples

Yuanchen Liu; Yujian Liu; Zhimin Liu; Xianzhi Hu; Zhigang Xu

AbstractA series of β-cyclodextrin derivatives were designed and synthesized. The derivatives were investigated as functional monomers in molecularly imprinted polymeric solid-phase microextraction (MIP-SPME) fiber coatings. The coatings, with a layer thickness of 250 μm, were immobilized onto stainless steel using a capillary tube as a mold. This study employed a simple, easy, and reproducible method to prepare uniform coatings for polychlorophenols extraction. The combination of molecular inclusion effects and the molecular imprinting sites was expected to enhance the molecular recognition ability for polychlorophenols. Compared with non-imprinted polymer coatings and MIP coatings with methacrylic acid as the functional monomer, the β-cyclodextrin MIP-SPME coatings exhibited significantly higher extraction amounts and excellent selectivity to the template of triclosan. The MIP-SPME coatings exhibited a favorable synergistic extraction capacity resulting from the β-cyclodextrin cavity and molecularly imprinted binding sites. The method of β-cyclodextrin MIP-SPME coupled with high performance liquid chromatography (HPLC) for triclosan and polychlorophenols analysis in real water samples was developed. The limit of quantification was 1 μg/L for the three polychlorophenols. The recovery for three analytes ranged from 83.71% to 109.98%, with the relative standard deviation (RSD) of 2.83% to 12.19%. The β-cyclodextrin MIP-SPME fiber coatings could be used for at least 100 cycles.n Graphical AbstractSynergistic effects in β-cyclodextrin MIP-SPME


Advanced Materials Research | 2013

Mixed-Template Molecularly Imprinted Technique and its Application Research

Zhigang Xu; Zhimin Liu; Yun Li Chen

Molecularly imprinted techniques have been rapidly developed in recent decade. Some novel molecularly imprinted techniques and some novel application forms of molecularly imprinted polymers have been developed. And it has been widely used in sample pretreatment. In this paper, novel mixed-template molecularly imprinted techniques are introduced. The development and applications of mixed-template molecularly imprinted techniques in recent decade are reviewed, including dual-template molecularly imprinted technique and multi-template molecularly imprinted technique, and its application in chromatographic solid phase, solid phase extraction and microsphere extraction. Moreover, the trends of mixed-template molecularly imprinted techniques in sample pretreatment are prospected.


Advanced Materials Research | 2014

Molecularly Imprinted Polymers for the Analysis of Environmental Estrogen Bisphenol A

Zhigang Xu

Molecularly imprinted polymer (MIP) has the characteristics of predetermination, specific recognition and practicability. It can eliminate the interference of complicated matrix. It has been widely used as selective adsorption material in sample preparation. Bisphenol A is a common endocrine disruptor in environment. Its toxic effects and analysis have attracted widespread concern. In this paper, the molecularly imprinted sample preparation techniques for bisphenol A were comprehensively reported, including molecularly imprinted microspheres extraction, molecularly imprinted solid phase extraction, molecularly imprinted solid phase microextraction, molecularly imprinted stir bar sorptive extraction and molecularly imprinted membrane extraction. Moreover, the trends of BPA-molecularly imprinted techniques are prospected.


Microchemical Journal | 2018

Dummy-template molecularly imprinted micro-solid-phase extraction coupled with high-performance liquid chromatography for bisphenol A determination in environmental water samples

Yuanchen Liu; Dan Wang; Fuyou Du; Wenqian Zheng; Zhimin Liu; Zhigang Xu; Xianzhi Hu; Hongcheng Liu


Advanced Materials Research | 2015

Fast and Efficient Synthesis of Mono-(6-p-toluenesulfonyl)-β-cyclodextrin via Ultrasound Assisted Method

Wen Qian Zheng; Mei Xia Du; Feng Feng; Guo Lin Chen; Min Liao; Yu Jian Liu; Ling Tang; Zhigang Xu


Advanced Materials Research | 2015

Quercetin Molecularly Imprinted Polymers and its Application in the Separation and Analysis of Natural Products

Rui Mei Liu; Lai Gui; Shi Feng Dai; Yan Ju Zhang; Zhigang Xu


Advanced Materials Research | 2015

Novel β- Cyclodextrin Functional Monomers and its Application for Molecularly Imprinted Polymers

Feng Feng; Zhimin Liu; Zhigang Xu


international conference on mechatronics | 2014

Synthesis of a Novel Mono-(6-N- allylamino-6-deoxy)- -cyclodextrin Functional Monomer

Guolin Chen; Feng Feng; Min Liao; Yujian Liu; Ling Tang; Zhigang Xu; Zhimin Liu


Archive | 2014

Monomer cyclodextrin Functional Synthesis of a Novel Mono-(6-N- allylamino-6-deoxy)--

Guolin Chen; Feng Feng; Min Liao; Ling Tang; Zhimin Liu; Zhigang Xu

Collaboration


Dive into the Zhigang Xu's collaboration.

Top Co-Authors

Avatar

Zhimin Liu

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Feng Feng

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Guolin Chen

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Ling Tang

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Min Liao

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Xianzhi Hu

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Yuanchen Liu

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Yujian Liu

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Guo Lin Chen

Kunming University of Science and Technology

View shared research outputs
Top Co-Authors

Avatar

Lai Gui

Kunming University of Science and Technology

View shared research outputs
Researchain Logo
Decentralizing Knowledge