Zhihui Zhang

Bioinspired surface functionalization of metallic biomaterials

Metallic biomaterials are widely used for clinical applications because of their excellent mechanical properties and good durability. In order to provide essential biofunctionalities, surface functionalization is of particular interest and requirement in the development of high-performance metallic implants. Inspired by the functional surface of natural biological systems, many new designs and conceptions have recently emerged to create multifunctional surfaces with great potential for biomedical applications. This review firstly introduces the metallic biomaterials, important surface properties, and then elaborates some strategies on achieving the bioinspired surface functionalization for metallic biomaterials.

Study of the microstructure and mechanical properties of white clam shell.

The microstructure and mechanical properties of white clam shell were investigated, respectively. It can be divided into horny layer, prismatic layer and nacreous layer. Crossed-lamellar structure was the microstructural characteristic. The extension direction of lamellae in prismatic layer was different from that in nacreous layer, which formed an angle on the interface between prismatic layer and nacreous layer. The phase component of three layers was CaCO3 with crystallization morphology of aragonite, which confirmed the crossed-lamellar structural characteristic. White calm shell exhibited perfect mechanical properties. The microhardness values of three layers were 273HV, 240HV and 300HV, respectively. The average values of flexure and compression strength were 110.2MPa and 80.1MPa, respectively. The macroscopical cracks crossed the lamellae and finally terminated within the length range of about 80μm. It was the microstructure characteristics, the angle on the interface between prismatic and nacreous layer and the hardness diversity among the different layers that enhanced mechanical properties of white calm shell.

One-step fabrication of robust superhydrophobic and superoleophilic surfaces with self-cleaning and oil/water separation function

Superhydrophobic surfaces have great potential for application in self-cleaning and oil/water separation. However, the large-scale practical applications of superhydrophobic coating surfaces are impeded by many factors, such as complicated fabrication processes, the use of fluorinated reagents and noxious organic solvents and poor mechanical stability. Herein, we describe the successful preparation of a fluorine-free multifunctional coating without noxious organic solvents that was brushed, dipped or sprayed onto glass slides and stainless-steel meshes as substrates. The obtained multifunctional superhydrophobic and superoleophilic surfaces (MSHOs) demonstrated self-cleaning abilities even when contaminated with or immersed in oil. The superhydrophobic surfaces were robust and maintained their water repellency after being scratched with a knife or abraded with sandpaper for 50 cycles. In addition, stainless-steel meshes sprayed with the coating quickly separated various oil/water mixtures with a high separation efficiency (>93%). Furthermore, the coated mesh maintained a high separation efficiency above 95% over 20 cycles of separation. This simple and effective strategy will inspire the large-scale fabrication of multifunctional surfaces for practical applications in self-cleaning and oil/water separation.

Effect of Al content on impact resistance behavior of Al-Ti-B4C composite fabricated under air atmosphere

Reaction behavior, mechanical property and impact resistance of TiC-TiB2/Al composite reacted from Al-Ti-B4C system with various Al content via combination method of combustion synthesis and hot pressed sintering under air was investigated. Al content was the key point to the variation of mechanical property and impact resistance. Increasing Al content could increase the density, strength and toughness of the composite. Due to exorbitant ceramic content, 10wt.% and 20wt.% Al-Ti-B4C composites exhibited poor molding ability and machinability. Flexural strength, fracture toughness, compressive strength and impact toughness of 30-50wt.% Al-Ti-B4C composite were higher than those of Al matrix. The intergranular fracture dispersed and defused impact load and restricted crack extension, enhancing the impact resistance of the composite. The composite with 50wt.% Al content owned highest mechanical properties and impact resistance. The results were useful for the application of TiC-TiB2/Al composite in impact resistance field of ceramic reinforced Al matrix composite.

Study on temperature and near-infrared driving characteristics of hydrogel actuator fabricated via molding and 3D printing

A hydrogel material system which was fit for molding and 3D printing was developed to fabricate bilayer hydrogel actuators with controllable temperature and near infrared laser responses. Polymerization on interface boundary of layered structure enhanced the bonding strength of hydrogel actuators. By utilizing anisotropic of microstructure along with thickness direction, bilayer hydrogel actuators fabricated via molding realized intelligent bending/shrinking responses, which guided the preparation of hydrogel ink for 3D printing. In-situ free radical polymerization under vacuum realized the solidification of printed hydrogel actuators with graphene oxide. Based on anisotropic swelling/deswelling behaviors of precise structure fabricated via 3D printing, the printed bilayer hydrogel actuators achieved temperature and near infrared laser responsive deformation. Changes of programmable printing path effectively resulted in corresponding deformation patterns. Combination of advantages of molding and 3D printing can promote the design and fabrication of hydrogel actuators with high mechanical strength, response speed and deformation ability.

Design and fabrication of nanofibrillated cellulose-containing bilayer hydrogel actuators with temperature and near infrared laser responses

A novel type of nanofibrillated cellulose (NFC)-containing poly N-isopropylacrylamide-clay bilayer nanocomposite hydrogel actuator was successfully fabricated via one-step in situ free radical polymerization. The bilayer hydrogel exhibited rapid, reversible and efficient temperature and near infrared laser responses in air and water. With an increase in the NFC content, the cross-density of hydrogels enhanced, leading to an increase in the strength and deswelling rate and a decrease in the strain, swelling rate and bending degree. The two layers in the bilayer structure bonded tightly. The bilayer hydrogel dimensions affected the deformation ability. The smaller the bilayer hydrogel, the higher the bending degree exhibited by the actuators. Bending degree in poikilothermy temperature ranging from 32 to 50 °C was higher than that in the constant temperature of 50 °C. Based on the intelligent responsive property, the bilayer hydrogel was designed as a soft temperature-controlled manipulator, which can be treated as a candidate material for medicine and soft robotics.

From natural to biomimetic: The superhydrophobicity and the contact time.

The superhydrophobicities and the contact time of lotus leaf and reed leaf were investigated. The results indicated that both lotus leaf and reed leaf have good superhydrophobic properties, and the water contact time was 12.7 and 14.7 ms on the surface of lotus leaf and reed leaf, respectively. Surface structure plays a key role in the different contacting times. Homogeneous distribution of papillae on the surface of lotus leaf was more helpful to reduce the contact time than anisotropic groove‐shape on the surface of reed leaf. Based on the bionics coupling theory, the bionics sample possessing similar lotus‐leaf‐like surface structure on the aluminum alloy was designed and fabricated successfully. The water contact angle was about 153 ± 2°, sliding angle less than 5°, and the water contact time was 13.4 ms on the surface of bionics sample, which presented excellent superhydrophobic property, and achieved the aim of bionic design. Microsc. Res. Tech. 79:712–720, 2016.

Effects of Bionic Units in Different Scales on the Wear Behavior of Bionic Impregnated Diamond Bits

Based on anti-wear theory of soil animals, the samples of impregnated diamond bit with bionic self-regenerated non-smooth surface were designed and fabricated. Such a bionic surface was characterized by concave-shape units of different scales that continuously maintained their shape and function during the whole working process. Abrasion tests were carried out to investigate the performance of samples. Results showed that the bionic samples exhibit excellent wear resistance and drilling performance under the action of bionic self-regenerated units, especially those with units of 2 mm–3 mm diameter. The particle- trapping mechanism coming from the self-regenerated concaves and the lubricating mechanism coming from the continuously self-supplying of solid lubricant are important reasons for reducing or even avoiding the severe abrasions. The improved drilling performance of bionic samples derives from, on the one hand, the back edge of bionic unit that contributes to exposing new diamond and supplying additional shear stresses to increase the cutting ability, on the other hand, the enhanced load per unit area due to the decreased contact area at the frictional interface. The relationship between the wear behavior and the scale of bionic unit was revealed. The unit of smaller scale on the bionic samples can enhance the shear stress level. Further reducing the scale to a contain extent will diminish the wear resistance of sample. While increasing the scale can lead to the poor lubricating effect.

Experimental study and numerical simulation on the structural and mechanical properties of Typha leaves through multimodal microscopy approaches

The Typha leaf, with special multi-level structure, low density and excellent mechanical properties, is an ideal bionic prototype utilized for lightweight design. In order to further study the relationship between the structure and mechanical properties, the three-dimensional macroscopic morphology of Typha leaves was characterized by micro computed tomography (Micro-CT) and its internal microstructure was observed by scanning electron microscopy (SEM). The combination of experimental and computational research was carried out in this paper, to reveal and verify the effect of multi-level structure on the mechanical properties. A universal testing machine and a self-developed mechanical testing apparatus with high precision and low load were used to measure the mechanical properties of the axial compression and lateral bending of the leaves, respectively. Three models with different internal structures were established based on the above-mentioned three-dimensional morphologies. The result demonstrated that the structure of partitions and diaphragms within the Typha leaf could form a reinforcement ribs structure which could provide multiple load paths and make the process of compression and bending difficult. The further nonlinear finite element analysis through LS-DYNA proved that internal structure could improve the ability of the models to resist compression and deformation. The investigation can be the reference for lightweight thin-walled structure design and inspire the application of the bionic structural materials.

The Structure and Flexural Properties of Typha Leaves

The Typha leaf has a structure of lightweight cantilever beam, exhibiting excellent mechanical properties with low density. Especially, the leaf blade evolved high strength and low density with high porosity. In this paper, the structure of Typha leaf was characterized by microcomputed tomography (Micro-CT) and scanning electron microscopy (SEM), and the relationship with flexural properties was analyzed. The three-point bending test was performed on leaves to examine flexural properties, which indicated that the flexural properties vary from the base to the apex in gradient. The cross-sectional geometry shape of the leaf blade presented a strong influence on the optimized flexural stiffness. The load carrying capacity of the leaf depended on the development level of the epidermal tissue, the vascular bundle, the mechanical tissue, and the geometric properties. The investigation can be the basis for lightweight structure design and the application in the bionic engineering field.