Zhixin Jia

Effect of acetone extract from natural rubber on the structure and interface interaction in NR/CB composites

The influences of acetone extract (AE) from natural rubber on the interface structure of NR/CB composites were investigated through rubber process analyzer (RPA), scanning electron microscopy (SEM), Raman spectroscopy, X-ray diffraction (XRD), and differential scanning calorimetry (DSC). The results demonstrated that the crystallite size of CB was increased by AE, leading to the decrease of dispersive free energy (γds) on the CB surface, which results in a reduction of CB–NR interaction. Oppositely, AE also increased the number of physical entanglement points in NR/CB matrix for its polarity interaction with CB, which could promote the CB–NR interaction. Consequently, the optimized value of AE in NR/CB matrix is 2 phr, where the optimal mechanical and dynamical properties were obtained. Simultaneously, AE had a negative effect on the strain-induced crystallization behaviors of NR/CB composites. This research may draw attention to the evaluation of quality standards of NR.

Halloysite Tubes as Nanocontainers for Herbicide and Its Controlled Release in Biodegradable Poly(vinyl alcohol)/Starch Film

Commercial herbicide atrazine (AT) was first loaded into the lumen of halloysite nanotubes (HNTs) in the amount of 9 wt %, and then the AT-loaded HNTs (HNTs-AT) were further incorporated into poly(vinyl alcohol)/starch composites (PVA/ST, with the weight ratio of 80/20) to construct a dual drug delivery system. AT loaded in nanotubes displayed much slower release from PVA/ST film in water than free AT; for example, the total release amount of AT from PVA/ST film with loaded AT was only 61% after 96 h, while this value reached 97% in PVA/ST film with free AT. The release behavior of AT from PVA/ST film with HNTs-AT was first dominated by the mechanism of matrix erosion and then by the mechanism of Fickian diffusion. In addition, combining HNTs and PVA/ST blends together in the controlled release of herbicide also reduced its leaching through the soil layer, which would be useful for diminishing the environmental pollution caused by pesticide.

Characterization of Waste Printed Circuit Boards Nonmetals and its Reutilization as Reinforcing Filler in Unsaturated Polyester Resin

Waste printed circuit boards (WPCB) nonmetals were firstly recycled as reinforcing filler in a kind of novel room temperature cured unsaturated polyester (UPE) composites. The compositions and characteristics of WPCB nonmetals were detailly analyzed by SEM, FTIR, TGA and Py-GCMS, and the effects of the content of WPCB nonmetals on the mechanical performance and thermal behaviors of UPE composites were also systematically studied. Results suggested that UPE composites incorporated with WPCB nonmetals at appropriate content showed superior tensile strength, flexural strength and heat distortion temperature than UPE matrix. Based on the analysis of thermal degradation kinetic, the thermal stability of UPE composites were significantly enhanced by the incorporation of WPCB nonmetals. The highlight of this work lies in the fact that high-valued utilization of WPCB nonmetals is realized in room temperature cured UPE matrix, which may not only achieve favorable economic and social benefits, but also open up new opportunities for the preparation of high performance plastic composites.

Inorganic and Organic Hybrid Nanoparticles as Multifunctional Crosslinkers for Rubber Vulcanization with High-Filler Rubber Interaction

Improving the interfacial interaction between rubber and silica nanoparticles, and simultaneously reducing free sulfur and preventing migration and volatilization of a rubber vulcanizing agent, commercial sulfur compound aliphatic ether polysulfide (VA-7) was chemically attached to the silica surface to obtain a functionalized nanoparticle (silica-s-VA7). Functional nanoparticles can not only effectively crosslink rubber without sulfur as a novel vulcanizator, but are also evenly dispersed in the rubber matrix and improve the dispersion of the remaining pristine silica as an interfacial compatibilizer. In addition, the thicker immobilized polymer layer and prominent crosslinking density of SBR nanocomposites simultaneously demonstrate that the novel vulcanizing agent silica-s-VA7 gives rise to significant improvement on the rubber–filler interfacial adhesion on account of the covalent linkages of organic and inorganic interfaces between elastomer and nanofillers. We envisage that this strategy may provide a new avenue to implement high-efficiency design for a multifunctional rubber-vulcanizing agent through an organic and inorganic hybridization mechanism.