Zhongqing Fang

Growth, spectroscopy, and laser performance of a 2.79 μm Cr,Er,Pr:GYSGG radiation-resistant crystal.

We demonstrate the growth, spectroscopy, and laser performance of a 2.79 μm Cr,Er,Pr:GYSGG radiation-resistant crystal. The lifetimes for the upper laser level (4)I(11/2) and lower laser level (4)I(13/2) are 0.59 and 0.84 ms, respectively, which are due to the doping of the Pr(3+) ions. A maximum pulse energy of 278 mJ operated at 10 Hz and 2.79 μm is obtained when pumped with a flash lamp, which corresponds to the electrical-to-optical efficiency of 0.6% and a slope efficiency of 0.7%. A maximum average power of 2.9 W at 60 Hz is achieved, which corresponds to the electrical-to-optical efficiency of 0.4% and slope efficiency of 0.8%. Compared with a Cr,Er:YSGG crystal, the Cr,Er,Pr:GYSGG crystal can be operated at a higher pulse repetition rate. These results suggest that doping deactivator Pr(3+) ions can effectively decrease the lower laser level lifetime and improve the laser repetition rate. Therefore, the application fields and range of the Cr,Er,Pr:GYSGG laser can be extended greatly due to its properties of radiation resistance and high repetition frequency.

Growth, structure, and spectroscopic properties of a Cr3+, Tm3+, Ho3+, and Pr3+ co-doped LuYAG single crystal for 2.9 μm laser

A new laser crystal from Lu2.4Y0.6Al5O12 (LuYAG) co-doped with Cr3+, Tm3+, Ho3+, and Pr3+ ions was grown successfully by the Czochralski method for the first time. The structure parameters of the Cr,Tm,Ho,Pr:LuYAG crystal are determined by the X-ray Rietveld refinement method. The main absorption bands are observed near 426 and 782 nm, and the fluorescence spectrum excited by a 450 nm or 783 nm LD presents an emission band near 2.911 μm, indicating that the co-doped Cr3+ and Tm3+ ions can be utilized as sensitizers for the Ho3+ ions. The lifetimes of the 5I6 and 5I7 levels of the Ho3+ ions were measured and fitted to be 0.070 ms and 1.852 ms, respectively. The energy transfer efficiencies of the processes 5I6 (Ho3+) → 3F3,4 (Pr3+) and 5I7 (Ho3+) → 3F2 (Pr3+) + 3H6 (Pr3+) were calculated, showing that the Pr3+ ions can play the role of a deactivator for the Ho3+ ions. Furthermore, the energy transfer mechanisms among the Cr3+, Tm3+, Ho3+, and Pr3+ ions were studied. The results suggest that the Cr,Tm,Ho,Pr:LuYAG crystal is a new promising laser medium operating at around 2.9 μm under flash lamp or 783 nm LD pumping.

Thermal analysis and laser performance of a GYSGG/Cr,Er,Pr:GYSGG composite laser crystal operated at 2.79 μm

We demonstrate the thermal analysis and laser performance of a GYSGG/Cr,Er,Pr:GYSGG composite crystal. The lifetime ratio of lower and upper levels of Er3+ in Cr,Er,Pr:GYSGG crystal is further reduced due to the optimized doping concentrations. The thermal effect of composite crystal is lower than that of Cr,Er,Pr:GYSGG crystal. A maximum pulse energy 342.8 mJ operated at 5 Hz and 2.79 μm is obtained on the composite crystal, corresponding to electrical-to-optical efficiency of 0.86% and slope efficiency of 1.08%. Under the same condition, these values on the Cr,Er,Pr:GYSGG crystal are only 315.8 mJ, 0.79% and 1.04%, respectively. Moreover, the composite crystal has also a relative high laser beam quality, exhibiting obvious advantage in reducing thermal effects and improving laser performances.

Influence of Cr 3+ concentration on the spectroscopy and laser performance of Cr,Er:YSGG crystal

Abstract. Cr,Er:YSGG (Y3Sc2Ga3O12) crystals with 30 at. % Er3+ and two different concentrations of Cr3+ ions were grown by the Czochralski method. The spectra show the absorption coefficients at 450 and 654 nm and the fluorescence intensity at 2794 nm for 3 at. % Cr,Er:YSGG which are larger than those of 2 at. % Cr,Er:YSGG. A maximum pulse energy 1151.0 mJ operated at 5 Hz and 2.79  μm is obtained on the 3 at. % Cr,Er:YSGG crystal, corresponding to electrical-to-optical efficiency of 1.40%, slope efficiency of 1.71%, and threshold of 8.6 J. Under the same conditions, the values are 1029.8 mJ, 1.23%, 1.50%, and 12.6 J for 2 at. % Cr,Er:YSGG, respectively. Therefore, the 3 at. % Cr,Er:YSGG exhibits a larger output energy, higher laser efficiency, and lower pumping threshold. These results suggest that the laser performance of the Cr,Er:YSGG crystal can be improved by further optimizing the doping ions concentration and pumping parameters.