Zoltán Pécskay

Petrology and geochemistry of late Tertiary/Quaternary mafic alkaline volcanism in Romania

Abstract Alkaline volcanic activity occurred in the Persani Mountains (eastern Transylvanian Basin) and Banat (eastern Pannonian Basin) regions of Romania between 2.5 Ma and 0.7 Ma. This volcanism followed an extended period of subduction-related mostly andesitic and dacitic magmatism in the Eastern Carpathian arc. The Persani Mts. alkaline activity coincided with the last phase of subduction-related activity. Several lava flows and pyroclastic deposits in the Persani Mts. carry peridotitic mantle xenoliths and amphibole megacrysts. Major- and trace-element geochemistry indicates that the alkaline magmas are primitive, silica-undersaturated alkali basalts and trachybasalts (7.8–12.3 wt.% MgO; 119–207 ppm Ni; 210–488 ppm Cr) which are LREE-enriched. Mantle-normalised trace-element diagrams reveal an overall similarity to continental intraplate alkali basalts, but when compared with a global average of ocean island basalts (OIB), the Banat lavas are similar to average OIB, whereas the Persani Mts. basalts have higher Rb, Ba, K and Pb and lower Nb, Zr and Ti. These features slightly resemble those of subduction-related magmas, particularly those of a basaltic andesite related to the nearby older arc magmas. With 87 Sr 86 Sr varying from 0.7035-0.7045 and 143 Nd 144 Nd from 0.51273-0.51289, the Romania basalts are indistinguishable from those of the western Pannonian basin (Hungary and Austria) and Neogene alkali basalts throughout Europe. Amphibole megacrysts have similar isotopic signatures, and their REE patterns indicate derivation by crystallisation from a mafic alkaline magma. The age-corrected Sr and Nd isotopic compositions of a calc-alkaline basaltic andesite related to the preceeding period of subduction also lies within the field of the younger alkaline magmas. Pb isotopic ratios of the Romanian alkali basalts do not lie on the NHRL, but overlap the field of Tertiary alkali basalts from the western Pannonian basin, and have unusually high 207 Pb 204 Pb at a given 206 Pb 204 Pb . Thus it is probable that, although the Romanian alkali basalts have a strong asthenospheric (i.e. OIB-type mantle source) component, their Pb isotopic characteristics were derived from mantle which was affected by the earlier subduction.

Magmagenesis in a subduction-related post-collisional volcanic arc segment: the Ukrainian Carpathians

Abstract Calc-alkaline magmatism in the south-west Ukraine occurred between 13.8 and 9.1 Ma and formed an integral part of the Neogene subduction-related post-collisional Carpathian volcanic arc. Eruptions occurred contemporaneously in two parallel arcs (here termed Outer Arc and Inner Arc) in the Ukrainian part of the Carpathians. Outer Arc rocks, mainly andesites, are characterized by LILE enrichment (e.g. K and Pb), Nb depletion, low compatible trace element abundances, high 87Sr/86Sr, high δ18O and low 143Nd/144Nd isotopic ratios (0.7085–0.7095, 7.01–8.53, 0.51230–0.51245, respectively). Inner Arc rocks are mostly dacites and rhyolites with some basaltic and andesitic lavas. They also show low compatible element abundances but have lower 87Sr/86Sr, δ18O and higher 143Nd/144Nd ratios (0.7060–0.7085, 6.15–6.64, 0.5125–0.5126, respectively) than Outer Arc rocks. Both high-Nb and low-Nb lithologies are present in the Inner Arc. Based on the LILE enrichment (especially Pb), a higher fluid flux is suggested for the Outer Arc magmas compared with those of the Inner Arc. Combined trace element and Sr–Nd–O isotopic modelling suggests that the factors which controlled the generation and evolution of magmas were complex. Compositional differences between the Inner and Outer Arcs were produced by introduction of variable proportions of slab-derived sediments and fluids into a heterogeneous mantle wedge, and by different extents of upper crustal contamination. Degrees of magmatic fractionation also differed between the two arcs. The most primitive magmas belong to the Inner Arc. Isotopic modelling shows that they can be produced by adding 3–8% subducted terrigenous flysch sediments to the local mantle wedge source. Up to 5% upper crustal contamination has been modelled for fractionated products of the Inner Arc. The geochemical features of Outer Arc rocks suggest that they were generated from mantle wedge melts similar to the Inner Arc primitive magmas, but were strongly affected by both source enrichment and upper crustal contamination. Assimilation of 10–20% bulk upper crust is required in the AFC modelling, assuming an Inner Arc parental magma. We suggest that magmagenesis is closely related to the complex geotectonic evolution of the Carpathian area. Several tectonic and kinematic factors are significant: (1) hydration of the asthenosphere during subduction and plate rollback directly related to collisional processes; (2) thermal disturbance caused by ascent of hot asthenospheric mantle during the back-arc opening of the Pannonian Basin; (3) clockwise translational movements of the Intracarpathian terranes, which facilitated eruption of the magmas.

Late Neoproterozoic to Early Palaeozoic palaoegeography of the Holy Cross Mountains (Central Europe): an integrated approach

Study of geochemistry, examination of isotope ages of detrital minerals, palaeomagnetic analysis, and a study of the trilobites were performed to provide constraints on the palaeogeographical position of the Holy Cross Mountains in Late Ediacaran–Early Palaeozoic time. The geochemical results indicate an active continental margin or continental island arc provenance of the Ediacaran sediments. Sediments from a passive continental margin were deposited here during the Cambrian and Ordovician. The palaeomagnetic pole isolated from Cambrian rocks of the Małopolska region of the Holy Cross Mountains corresponds to the Cambrian segment of the Baltic apparent polar wander path. Isotope age estimations indicate that Cambrian sediments of the Małopolska region contain detritus not only from a latest Neoproterozoic source but also from sources with ages of c. 0.8–0.9 Ga, 1.5 Ga and 1.8 Ga. The Małopolska, Brunosilesia, Dobrugea and Moesia terranes, which originally developed near the present southern edge of Baltica and were partly involved in the Cadomian orogen, were dextrally relocated along its Trans-European Suture Zone margin. The first stage of this movement took place as early as latest Ediacaran time, while Baltica rotated anticlockwise. Anticlockwise rotation of Baltica at the Cambrian–Ordovician boundary implies further dextral movement of the Małopolska block.

Neogene-Quaternary Volcanic forms in the Carpathian-Pannonian Region: a review

Neogene to Quaternary volcanic/magmatic activity in the Carpathian-Pannonian Region (CPR) occurred between 21 and 0.1 Ma with a distinct migration in time from west to east. It shows a diverse compositional variation in response to a complex interplay of subduction with rollback, back-arc extension, collision, slab break-off, delamination, strike-slip tectonics and microplate rotations, as well as in response to further evolution of magmas in the crustal environment by processes of differentiation, crustal contamination, anatexis and magma mixing. Since most of the primary volcanic forms have been affected by erosion, especially in areas of post-volcanic uplift, based on the level of erosion we distinguish: (1) areas eroded to the basement level, where paleovolcanic reconstruction is not possible; (2) deeply eroded volcanic forms with secondary morphology and possible paleovolcanic reconstruction; (3) eroded volcanic forms with remnants of original morphology preserved; and (4) the least eroded volcanic forms with original morphology quite well preserved. The large variety of volcanic forms present in the area can be grouped in a) monogenetic volcanoes and b) polygenetic volcanoes and their subsurface/intrusive counterparts that belong to various rock series found in the CPR such as calc-alkaline magmatic rock-types (felsic, intermediate and mafic varieties) and alkalic types including K-alkalic, shoshonitic, ultrapotassic and Na-alkalic. The following volcanic/subvolcanic forms have been identified: (i) domes, shield volcanoes, effusive cones, pyroclastic cones, stratovolcanoes and calderas with associated intrusive bodies for intermediate and basic calclkaline volcanism; (ii) domes, calderas and ignimbrite/ash-flow fields for felsic calc-alkaline volcanism and (iii) dome flows, shield volcanoes, maars, tuffcone/tuff-rings, scoria-cones with or without related lava flow/field and their erosional or subsurface forms (necks/ plugs, dykes, shallow intrusions, diatreme, lava lake) for various types of K- and Na-alkalic and ultra-potassic magmatism. Finally, we provide a summary of the eruptive history and distribution of volcanic forms in the CPR using several sub-region schemes.

Dolerites of Svalbard, north-west Barents Sea Shelf: age, tectonic setting and significance for geotectonic interpretation of the High-Arctic Large Igneous Province

The dolerites of Svalbard are mineralogically and geochemically homogeneous with geochemical features typical of continental within-plate tholeiites. Their geochemistry is similar to tholeiites belonging to a bimodal suite defined as the High-Arctic Large Igneous Province (HALIP). K–Ar dating of numerous dolerites sampled from many locations across Svalbard define a narrow time span of this magmatism from 125.5±3.6 to 78.3±2.6 Mya. Discrete peaks of intensive activity occurred at 115.3, 100.8, 91.3 and 78.5 Mya corresponding to (1) breakup of the continental crust and formation of an initial rift as a result of mantle plume activity, located in the southern part of the Alpha Ridge; (2) magmatic activity related to spreading along the Alpha Ridge that led to the development of the initial oceanic crust and (3) continuation of spreading along the Alpha Ridge and termination of magmatic activity related to HALIP (last two peaks at 91.3 and 78.5 Mya).

Time-evolution of magma sources in a continental back-arc setting: The Cenozoic basalts from Sierra de San Bernardo (Patagonia, Chubut, Argentina)

East of the Patagonian Andes, mafic volcanic rocks (mainly lava flows and scoriae) are exposed in the Sierra de San Bernardo fold belt and neighbouring areas (central Patagonia; 44.5–46° S, 69–71° W). They were erupted over a wide interval of time (late Eocene–Pleistocene; 14 new K–Ar ages), and show systematic chemical and Sr–Nd–Pb isotopic variations in time. The alkaline lavas (Mg number 57–66) erupted during the late Eocene and early Miocene, have an intraplate geochemical affinity, and have the highest 143 Nd/ 144 Nd and 206 Pb/ 204 Pb and the lowest 87 Sr/ 86 Sr ratios of the dataset. Their compositions indicate that their depth of equilibration in the mantle was greater than that of subsequent lavas. In contrast, the Plio-Pleistocene alkaline lavas (Mg number 58–71) are the most enriched in incompatible elements, still showing an intra-plate signature, and have the lowest 143 Nd/ 144 Nd and 206 Pb/ 204 Pb and the highest 87 Sr/ 86 Sr ratios. A distinctive group of early Miocene subalkaline lavas is characterized by slightly more evolved compositions (Mg number 56–59), coupled with very low incompatible element contents, flat LREE and fractionated HREE patterns (‘kinked’ pattern), and intermediate Sr–Nd–Pb isotope compositions. The Pleistocene basanites (Mg number 71–72) from the Cerro Ante monogenetic cone, on the easternmost slopes of the Patagonian Andes, have a marked orogenic geochemical signature and Sr–Nd–Pb isotope ratios that overlap with those of volcanic rocks from the adjacent active Andean arc. They originated in a mantle source extensively modified by the addition of materials from the subducting Pacific oceanic plates. We suggest that the wide chemical and isotopic variability of the Sierra de San Bernardo lavas reflects the upwelling of asthenospheric mantle beneath the study area, which induced lithospheric erosion and progressive involvement of enriched mantle domains in the genesis of magmas. In this context, late Eocene and early Miocene alkaline magmatism was dominantly sourced from the asthenospheric mantle, whereas Plio-Pleistocene alkaline magmas contain the largest proportion of an enriched lithospheric component. The peculiar compositional features of the early Miocene subalkaline lavas are interpreted in terms of high-degree mantle melting followed by melt–lithospheric mantle reaction processes. Based on current knowledge about the relative movement and decoupling between lithosphere and asthenosphere, we propose that the asthenosphere below the study area rose up to compensate for the westward drift of the mantle wedge coupled with the South American lithosphere.

The Miocene granitoid rocks of Mt. Bukulja (central Serbia): evidence for pannonian extension-related granitoid magmatism in the northern Dinarides

The study presents evidence about the origin and evolution of the Miocene (20–17 Ma) granitoid pluton of Mt. Bukulja, situated within the southern Pannonian/northern Dinarides region (central Serbia, south-central Europe). The pluton is composed of slightly peraluminous two-mica granite (TMG), metaluminous hornblende-biotite and biotite-bearing (H-BG) granite and rare aplite granite. A lamprophyre dyke (BLD) similar in composition and age to other Serbian primitive minettes has been found in the vicinity of Mt. Bukulja. The available and newly determined radiometric age suggests that the TMG was emplaced around 20 Ma whereas the age of the H-BG is inadequately constrained. TMG and H-BG show similar petrographic characteristics but evidence of open system magma processes is found only in the H-BG. In comparison to the H-BG, the TMGs are less enriched in most trace elements, including REE, and have a more fractionated REE-pattern and stronger negative Eu-anomaly. The TMGs display a wider range of initial Sr-Nd isotope ratios (87Sr/86Sr20 Ma = 0.70652–0.71368 and 143Nd/144Nd20 Ma = 0.51223–0.51283) than the H-BG (87Sr/86Sr20 Ma = 0.70768–0.70781 and 143Nd/144Nd20 Ma = 0.51242–0.51256). Geochemical modeling suggests that the H-BG could have derived from a BLD-like melt by mixing plus fractionation processes assuming a batch of TMG-like magma as the acid end-member. On the other hand, the geochemical variability of the TMG is reproduced by an AFC model with an assimilation/fractionation ratio ( r ) of 0.5 and with high amount of crustal component (~20–50 %) starting from the least evolved TMG rocks. In the modeling, the average composition of the least evolved TMG samples was used to represent the parental magma composition whereas the composition of adjacent metamorphic rocks was adopted as possible contaminant. The composition of the least evolved TMG implies that the TMG parental magma likely originated by melting of a mafic lithology such as earlier basalts underplating in the lower crust. The high proportions of crustal assimilation along with other geochemical and geological evidence suggest that the Mt. Bukulja TMG originated within the same geotectonic setting as acid volcanics of the north Pannonian Basin. The results of this study support the hypothesis that the Mt. Bukulja pluton is related to tectonomagmatic events controlled by the early extensional phases in the opening of the Pannonian basin.

Petrogenetic and tectonic inferences from the study of the Mt Cer pluton (West Serbia)

The Mt Cer Pluton, Serbia, is a complex laccolith-like intrusion (~ 60 km 2 ), situated along the junction between the southern Pannonian Basin and northern Dinarides. It intrudes Palaeozoic metamorphic rocks causing weak to strong thermal effects. Based on modal and chemical compositions, four rock-types can be distinguished: (1) metaluminous I-type quartz monzonite/quartz monzodiorite (QMZD); (2) peraluminous S-type two-mica granite (TMG), which intrudes QMZD; (3) Stražanica granodiorite/quartz monzonite (GDS); and (4) isolated mafic enclaves (ME), found only in QMZD. 40 K– 39 Ar dating and geological constraints indicate that the main quartz monzonite/quartz monzodiorite body of Mt Cer was emplaced not later than 21 Ma, whereas the emplacement ages of the Stražanica granodiorite/quartz monzonite and two-mica granites are estimated at around 18 and 16 Ma, respectively. The Mt Cer pluton is similar to the Mt Bukulja pluton, some 80 km southwestwards. Genesis of QMZD cannot be interpreted by fractional crystallization coupled with mixing or assimilation. It is best explained by a convection–diffusion process between mantle-derived minette/leucominette magmas and GDS-like magmas followed by two end-member magma mixing. The composition of GDS rocks suggests that GDS-like magmas could have formed by melting of lower crustal lithologies similar to amphibolite/metabasalts. The geochemistry of TMG is reproduced by an Assimilation/Fractional Crystallization model with a ratio of rate of assimilation to rate of fractional crystallization of 0.4, using the compositions of the least evolved TMG of the Bukulja pluton and adjacent metamorphic rocks as proxies for the parental magma and contaminant, respectively. The origin and evolution of the Mt Cer and adjacent Mt Bukulja plutons provide new constraints on the Tertiary geodynamics of the northern Dinarides–southern Pannonian region. The quartz monzonite/quartz monzodiorite is interpreted as a result of the Oligocene post-collisional Dinaride orogen-collapse, which included a limited lithosphere delamination, small-scale mantle upwelling, and melting of the lower crust. By contrast, the two-mica granite magmas formed through melting in shallower crustal levels during the extensional collapse in the Pannonian area.

Late Miocene volcanic activity in the České středohoří Mountains (Ohře/Eger Graben, northern Bohemia)

Late Miocene volcanic activity in the České středohoří Mountains (Ohře/Eger Graben, northern Bohemia) First occurrences of superficial bodies of Late Miocene volcanic activity were found in the western part of the České středohoří Volcanic Complex (CSVC) and extended our knowledge of its volcanostratigraphy. Their K-Ar ages (9.59, 9.61 and 11.36 Ma) correspond to the age of alkaline basaltic rocks of the youngest known Intrusive Suite of this area. Unlike the previously known subvolcanic bodies of this system, the newly observed bodies are represented by superficial products: two scoria cones with remnants of lava flows and one exclusive lava flow produced from a lava cone. The magmas forming all three occurrences are basanitic. Their primitive chemical composition Sr (0.70347-0.70361) and Nd (0.51279-0.51284) isotope ratios are similar to the products of the first and third volcanic formation of the CSVC. The proved existence of superficial products of the youngest volcanic formation, together with clear superposition relations to sedimentary formations and the chemical character of the youngest magmas in the central part of the Ohře (Eger) Graben support the stratigraphic scheme of volcanic activity in the České středohoří Mts. The eruptive style of the youngest formation volcanoes was purely magmatic (Strombolian) with no phreatic influence.

Hyaloclastites, peperites and soft-sediment deformation textures of a shallow subaqueous Miocene rhyolitic dome-cryptodome complex, Pálháza, Hungary

Abstract The NE Tokaj Mountains at Pálháza in NE Hungary are made up of a complex association of Miocene rhyolitic shallow intrusions, cryptodomes and endogenous lava domes emplaced into and onto soft, wet pelitic sediment in a shallow submarine environment. The intrusive–extrusive complex shows a range of interaction textures with the host muddy sediment, ranging from blocky peperites, formed on a 0.1 m-scale, through to irregular contacts closely resembling globular mega-peperites, on a >10 m-scale. The over 200 m-thick igneous succession is interpreted to result from the pulsatory growth of shallow cryptodomes through muddy saturated host sediment. The intrusions eventually breached the sedimentary cover to build up thick in situ hyaloclastite piles in the shallow subaqueous environment. The coherent rhyolitic cryptodome facies is surrounded by intrusive hyaloclastite in the contact zone to the pelitic host sediment. In the upper level of the complex, rhyolitic dome rock is capped and surrounded by hyaloclastite formed due to quench fragmentation upon contact of the lava surface with sea water.