A. V. Nikiforov

Isotopic and Geochemical Zoning of Devonian Magmatism in the Altai-Sayan Rift System: Composition and Geodynamic Nature of Mantle Sources

Based on the systematic investigation of the geochemical and isotopic (Sr and Nd) characteristics of basic rocks from various volcanic areas of the Devonian Altai-Sayan rift system, the compositions of mantle magma sources were characterized, and the geodynamic scenarios of their entrainment into rifting processes were reconstructed. It was found that the titanium-rich basic rocks (2.5 < TiO2 < 4.2 wt %) of this region are enriched in lithophile trace elements, including the rare earth elements, compared with N-MORB and are similar in composition to intraplate subalkali basalts of the OIB type. In contrast, moderate-titanium basic rocks (1.1 < TiO2 < 2.5 wt %) are mainly depleted in the highly charged incompatible elements Th, U, Nb, and Ta (La/Yb = 1.2−2.2) and, to a lesser extent, in Zr, Hf, and LREE ((La/Yb)N < 7), but are enriched in Ba. With respect to these characteristics, the moderate-titanium basites are similar to rocks formed in subduction environments. The geochemical parameters of the basites are strongly variable, which probably reflects the heterogeneity of the mantle sources that contributed to the formation of the rift system. In particular, the most notable variations in rock composition related to an increase in the contribution of an OIB-type source to magma composition were observed in the eastern direction, i.e., inland from the paleocontinent margin. The isotopic composition of the basites is relatively stable within individual rift zones and significantly variable at a comparison of rocks from different zones of the region. Based on the isotopic characteristics of the rocks, three melt sources were identified. One of them is chemically similar to the PREMA and is a common component in all observed trends of isotopic variations, irrespective of the position of the particular assemblage in the structure of the region. This component dominates the composition of the titaniumrich basalts with geochemical signatures of the derivatives of enriched mantle reservoirs of the E-MORB and OIB types and is considered as a plume source. Two other isotopic melt sources are related to subduction processes, which is indicated by their dominance during the formation of the moderate-titanium basalts showing the geochemical signatures (primarily, Ta-Nb depletion) of typical volcanic-arc rocks. These differences are consistent with the formation of the Altai-Sayan rift system in a complex geodynamic setting, which developed under the influence of intraplate magma sources (mantle plume) on the region of melt generation in an active continental margin (subduction zone).

Middle Paleozoic basic magmatism of the northwestern Vilyui Rift: Composition, sources, and geodynamics

Middle Paleozoic magmatism at the eastern Siberian platform was related to riftogenic processes, which were most clearly expressed in the Vilyui Rift and led to the formation of rift depressions filled with sedimentary-volcanogenic rocks and extended basaltic dike belts in rift shoulders. Two fields of diamondiferous kimberlites were found along with basaltic dikes in the Vilyui-Markha dike belt surrounding rift in the northwest. Active subalkali basaltic magmatism predated the emplacement of kimberlite bodies, which occasionally (Nyurba pipe) are cut by dikes of potassium alkali basalts. Based on geochemical and Sr-Nd isotopic characteristics, deep-seated sources were determined for the intrusive and volcanic basalts of the northwestern shoulder of the Vilyui rift. The REE distribution patterns of the studied rocks normalized to the primitive mantle are close to that of OIB, except for somewhat higher HREE. In the diagrams of indicator ratios of trace and rare-earth elements, the basalts are also plotted in the OIB field, being located between the end member of plume composition (FOZO) and enriched mantle sources. The rocks have positive εSr (+3.5 and +28.6) and εNd (+1.3 and +5.3). In a diagram εNd(T)-εSr(T), two fields with distinct content of radiogenic Sr are distinguished, which can be regarded as derived by mixing of the moderately depleted PREMA-type mantle and a source enriched in radiogenic Sr. Available isotope-geochemical data confirm that OIB type basalts of the region were generated by plume activity. The geodynamic setting of Middle Paleozoic magmatism and rifting in the eastern part of the Siberian platform is considered in light of plume-lithosphere interaction. The sequence of tectonomagmatic events during evolution of the Vilyui rift is consistent with the model of plume-lithosphere interaction or the model of active rifting.

Rare-metal granitoids of the Ulug-Tanzek deposit (Eastern Tyva): Age and tectonic setting

95 Raremetal magmatism covering the age range of more than 1 billion years, from the Late Riphean to the Triassic, is widely abundant within the southern margin of the Siberian Platform and its folded sur� rounding. Late Riphean massifs of alkali-ultrabasic rocks with carbonatite of the Beloziminsk Complex, Ordovician-Triassic massifs of alkali granite (Arys� kan, Zashikhin, Ermakov, and others), as well as numerous massifs of lithium-fluorine granite includ� ing the spodumene variety, are related to the most wellknown manifestations of raremetal magmatism, which control the formation of large deposits of rare metals, rare elements, and rare earth elements. Until recently, the ideas about their age were based mainly on geological data. Only in the last few years have geo� chronological investigations, which allowed us to esti� mate the age and tectonic conditions of related mag� matic processes in geological evolution of the southern surroundings of the Siberian Platform, been carried out (1). However, the regularities of raremetal mag� matism in the structures of this region are not under� stood completely for some epochs. In particular, this relates to the epoch when the unique complex rare� metal-rareearth deposit UlugTanzek (Eastern Tyva) was formed. The existing estimations of age for host alkaline granitoids vary within very broad limits (229- 217 Ma, K-Ar method by potassic feldspar) and cover the whole Triassic (2). However, this age range in the region is amagmatic as a whole. Because of this, the reliability of age estimations obtained is doubtful and, therefore, there is a question about the geological events that controlled the formation of the deposit. In this paper we present the results of dating of alkaline granitoids of the UlugTanzek Massif by the U-Pb method for zircon and the Ar-Ar method. With account for the geochronological data obtained, we analyzed its position in the structure of magmatic areals of the same age and, on this basis, reconstructed the geodynamic environment of raremetal magma� tism in the corresponding epoch. The UlugTanzek Massif of alkaline granitoids is located in southeastern Tyva within the Sangilen part of the Tyva-Mongol microcontinent, where it intrudes metamorphosed Vendian-Cambrian terrige� nous-carbonate deposits of the Kaakhem structural- facial zone. The massif is composed of quartz-albite- microcline granite with complex (Ta, Nb, Zr, Hf, REE, Li, Th, U, and cryolite) ore.

Compositions of Magmas, Formation Conditions, and Genesis of Carbonate-Bearing Ijolites and Carbonatites of the Belaya Zima Alkaline Carbonatite Complex, Eastern Sayan

Based on the investigation of melt inclusions using electron and ion microprobe analysis, we estimated the composition, evolution, and formation conditions of magmas responsible for the calcite-bearing ijolites and carbonatites of the Belaya Zima alkaline carbonatite complex (eastern Sayan, Russia). Primary melt and coexisting crystalline inclusions were found in the nepheline and calcite of these rocks. Diopside, amphibole (?), perovskite, potassium feldspar, apatite, calcite, pyrrhotite, and titanomagnetite were identified among the crystalline inclusions. The melt inclusions in nepheline from the ijolites are completely crystallized. The crystalline daughter phases of these inclusions are diopside, phlogopite, apatite, calcite, magnetite, and cuspidine. During thermometric experiments with melt inclusions in nepheline, the complete homogenization of the inclusions was attained through the dissolution of a gas bubble at temperatures of 1120–1130°C. The chemical analysis of glasses from the homogenized melt inclusions in nepheline of the ijolites revealed significant variations in the content of components: from 36 to 48 wt % SiO2, from 9 to 21 wt % Al2O3, from 8 to 25 wt % CaO, and from 0.6 to 7 wt % MgO. All the melts show very high contents of alkalis, especially sodium. According to the results of ion microprobe analysis, the average content of water in the melts is no higher than a few tenths of a percent. The most salient feature of the melt inclusions is the extremely high content of Nb and Zr. The glasses of melt inclusions are also enriched in Ta, Th, and light rare earth elements but depleted in Ti and Hf. Primary melt inclusions in calcite from the carbonatites contain a colorless glass and daughter phlogopite, garnet, and diopside. The silicate glass from the melt inclusions in calcite of the carbonatite is chemically similar to the glasses of homogenized melt inclusions in nepheline from the ijolites. An important feature of melt inclusions in calcite of the carbonatites is the presence in the glass of carbonate globules corresponding to calcite in composition. The investigation of melt inclusions in minerals of the ijolites and carbonatites and the analysis of the alkaline and ore-bearing rocks of the Belaya Zima Massif provided evidence for the contribution of crystallization differentiation and silicate-carbonate liquid immiscibility to the formation of these rocks. Using the obtained trace-element compositions of glasses of homogenized melt inclusions and various alkaline rocks and carbonatites, we determined to a first approximation the compositions of mantle sources responsible for the formation of the rock association of the Belaya Zima alkaline-carbonatite complex. The alkaline rocks and carbonatites were derived from the depleted mantle affected by extensive metasomatism. It is supposed that carbonate melts enriched in sodium and calcium were the main agents of mantle metasomatism.

Bastnaesite: a promising U-Pb geochronological tool

One of the most complex problems in geochrono� logical studies is dating endogenous ore processes. The application of the U–Pb method in solving this prob� lem is constrained by the sufficiently narrow range of traditional mineral geochronometers, which, if present in ores, are strongly altered. This problem was also encountered in dating deposits related to the occurrences of alkaline and carbonatite magmatism. At the same time, alkaline magmatic rocks and car�

Andradite–Morimotoite Garnets as Promising U–Pb Geochronometers for Dating Ultrabasic Alkaline Rocks

U–Pb geochronological studies of garnet of the andradite–morimotoite series and Sm–Nd geochronological studies of this garnet and apatite from the Chikskii Massif (Tuva-Mongolia microcontinent) were carried out. The garnet studied is characterized by relatively high concentrations of U (14–16 ppm) and by a low level of common Pb (Pbс/Pbt = 0.07–0.1). The concordia age of garnet is 492 ± 2 Ma (MSWD = 0.01, probability 92%) and matches within the error with the Sm–Nd age determined by the isochrone for apatite, garnet, and bulk rock (489 ± 9 Ma, MSWD = 0.86). This allows us to consider calcic garnets of the andradite–morimotoite series as promising mineral geochronometers for U–Pb dating of ultrabasic alkaline rocks.

Composition, sources, and mechanisms of origin of rare-metal granitoids in the Late Paleozoic Eastern Sayan zone of alkaline magmatism: A case study of the Ulaan Tolgoi massif

The Ulaan Tolgoi massif of rare-metal (Ta, Nb, and Zr) granites was formed at approximately 300Ma in the Eastern Sayan zone of rare-metal alkaline magmatism. The massif consists of alkaline salic rocks of various composition (listed in chronologic order of their emplacement): alkaline syenite → alkaline syenite pegmatite → pantellerite → alkaline granite, including ore-bearing alkaline granite, whose Ta and Nb concentrations reach significant values. The evolution of the massif ended with the emplacement of trachybasaltic andesite. The rocks of the massif show systematic enrichment in incompatible elements in the final differentiation products of the alkaline salic magmas. The differentiation processes during the early evolution of the massif occurred in an open system, with influx of melts that contained various proportions of incompatible elements. The magma system was closed during the origin of the ore-bearing granites. Rare-metal granitoids in the Eastern Sayan zone were produced by magmas formed by interaction between mantle melts (which formed the mafic dikes) with crustal material. The mantle melts likely affected the lower parts of the crust and either induced its melting, with later mixing the anatectic and mantle magmas, or assimilated crustal material and generated melts with crustal–mantle characteristics. The origin of the Eastern Sayan zone of rare-metal alkaline magmatism was related to rifting, which was triggered by interaction between the Tarim and Barguzin mantle plumes. The Eastern Sayan zone was formed in the marginal part of the Barguzin magmatic province, and rare-metal magmas in it were likely generated in relation with the activity of the Barguzin plume.