Aaswath Raman

Fundamental limit of nanophotonic light-trapping in solar cells

Establishing the fundamental limit of nanophotonic light-trapping schemes is of paramount importance and is becoming increasingly urgent for current solar cell research. The standard theory of light trapping demonstrated that absorption enhancement in a medium cannot exceed a factor of 4n2/ sin2θ, where n is the refractive index of the active layer, and θ is the angle of the emission cone in the medium surrounding the cell. This theory, however, is not applicable in the nanophotonic regime. Here we develop a statistical temporal coupled-mode theory of light trapping based on a rigorous electromagnetic approach. Our theory reveals that the conventional limit can be substantially surpassed when optical modes exhibit deep-subwavelength-scale field confinement, opening new avenues for highly efficient next-generation solar cells.

Fundamental limit of light trapping in grating structures

We use a rigorous electromagnetic approach to analyze the fundamental limit of light-trapping enhancement in grating structures. This limit can exceed the bulk limit of 4n², but has significant angular dependency. We explicitly show that 2D gratings provide more enhancement than 1D gratings. We also show the effects of the grating profiles symmetry on the absorption enhancement limit. Numerical simulations are applied to support the theory. Our findings provide general guidance for the design of grating structures for light-trapping solar cells.

Fundamental Limit of Nanophotonic Light-trapping in Solar Cells

Establishing the fundamental limit of nanophotonic light-trapping schemes is of paramount importance and is becoming increasingly urgent for current solar cell research. The standard theory of light trapping demonstrated that absorption enhancement in a medium cannot exceed a factor of 4n2 / sin2 θ, where n is the refractive index of the active layer, and θ is the angle of the emission cone in the medium surrounding the cell. This theory, however, is not applicable in the nanophotonic regime. Here we develop a statistical temporal coupled-mode theory of light trapping based on a rigorous electromagnetic approach. Our theory reveals that the standard limit can be substantially surpassed when optical modes in the active layer are confined to deep-subwavelength scale, opening new avenues for highly efficient next-generation solar cells.

Ultrabroadband photonic structures to achieve high-performance daytime radiative cooling.

If properly designed, terrestrial structures can passively cool themselves through radiative emission of heat to outer space. For the first time, we present a metal-dielectric photonic structure capable of radiative cooling in daytime outdoor conditions. The structure behaves as a broadband mirror for solar light, while simultaneously emitting strongly in the mid-IR within the atmospheric transparency window, achieving a net cooling power in excess of 100 W/m(2) at ambient temperature. This cooling persists in the presence of significant convective/conductive heat exchange and nonideal atmospheric conditions.

Radiative cooling of solar absorbers using a visibly transparent photonic crystal thermal blackbody

Significance The coldness of the universe is an enormous but strikingly underexploited thermodynamic resource. Its direct utilization on Earth therefore represents an important frontier for renewable energy research. In many applications, including solar cells and outdoor structures, the absorption of sunlight is intrinsic either from operational or aesthetic considerations, but the resulting heating by sunlight is undesirable. Here we experimentally demonstrate a thermal photonic scheme that can cool these structures by thermal radiation to outer space, while preserving the structures’ solar absorption. Our work shows, for the first time to our knowledge, that radiative cooling can be used in combination with the utilization of sunlight, and opens new possibilities for using the coldness of the universe to improve the performance of terrestrial energy systems. A solar absorber, under the sun, is heated up by sunlight. In many applications, including solar cells and outdoor structures, the absorption of sunlight is intrinsic for either operational or aesthetic considerations, but the resulting heating is undesirable. Because a solar absorber by necessity faces the sky, it also naturally has radiative access to the coldness of the universe. Therefore, in these applications it would be very attractive to directly use the sky as a heat sink while preserving solar absorption properties. Here we experimentally demonstrate a visibly transparent thermal blackbody, based on a silica photonic crystal. When placed on a silicon absorber under sunlight, such a blackbody preserves or even slightly enhances sunlight absorption, but reduces the temperature of the underlying silicon absorber by as much as 13 °C due to radiative cooling. Our work shows that the concept of radiative cooling can be used in combination with the utilization of sunlight, enabling new technological capabilities.

Radiative cooling to deep sub-freezing temperatures through a 24-h day–night cycle

Radiative cooling technology utilizes the atmospheric transparency window (8–13 μm) to passively dissipate heat from Earth into outer space (3 K). This technology has attracted broad interests from both fundamental sciences and real world applications, ranging from passive building cooling, renewable energy harvesting and passive refrigeration in arid regions. However, the temperature reduction experimentally demonstrated, thus far, has been relatively modest. Here we theoretically show that ultra-large temperature reduction for as much as 60 °C from ambient is achievable by using a selective thermal emitter and by eliminating parasitic thermal load, and experimentally demonstrate a temperature reduction that far exceeds previous works. In a populous area at sea level, we have achieved an average temperature reduction of 37 °C from the ambient air temperature through a 24-h day–night cycle, with a maximal reduction of 42 °C that occurs when the experimental set-up enclosing the emitter is exposed to peak solar irradiance.

Improving web spam classification using rank-time features

In this paper, we study the classification of web spam. Web spam refers to pages that use techniques to mislead search engines into assigning them higher rank, thus increasing their site traffic. Our contributions are two fold. First, we find that the method of datset construction is crucial for accurate spam classification and we note that this problem occurs generally in learning problems and can be hard to detect. In particular, we find that ensuring no overlapping domains between test and training sets is necessary to accurately test a web spam classifier. In our case, classification performance can differ by as much as 40% in precision when using non-domain-separated data. Second, we show rank-time features can improve the performance of a web spam classifier. Our paper is the first to investigate the use of rank-time features, and in particular query-dependent rank-time features, for web spam detection. We show that the use of rank-time and query-dependent features can lead to an increase in accuracy over a classifier trained using page-based content only.

Roadmap on optical energy conversion

For decades, progress in the field of optical (including solar) energy conversion was dominated by advances in the conventional concentrating optics and materials design. In recent years, however, conceptual and technological breakthroughs in the fields of nanophotonics and plasmonics combined with a better understanding of the thermodynamics of the photon energy-conversion processes reshaped the landscape of energy-conversion schemes and devices. Nanostructured devices and materials that make use of size quantization effects to manipulate photon density of states offer a way to overcome the conventional light absorption limits. Novel optical spectrum splitting and photon-recycling schemes reduce the entropy production in the optical energy-conversion platforms and boost their efficiencies. Optical design concepts are rapidly expanding into the infrared energy band, offering new approaches to harvest waste heat, to reduce the thermal emission losses, and to achieve noncontact radiative cooling of solar cells as well as of optical and electronic circuitries. Light–matter interaction enabled by nanophotonics and plasmonics underlie the performance of the third- and fourth-generation energy-conversion devices, including up- and down-conversion of photon energy, near-field radiative energy transfer, and hot electron generation and harvesting. Finally, the increased market penetration of alternative solar energy-conversion technologies amplifies the role of cost-driven and environmental considerations. This roadmap on optical energy conversion provides a snapshot of the state of the art in optical energy conversion, remaining challenges, and most promising approaches to address these challenges. Leading experts authored 19 focused short sections of the roadmap where they share their vision on a specific aspect of this burgeoning research field. The roadmap opens up with a tutorial section, which introduces major concepts and terminology. It is our hope that the roadmap will serve as an important resource for the scientific community, new generations of researchers, funding agencies, industry experts, and investors.

Perturbation Theory for Plasmonic Modulation and Sensing

We develop a general perturbation theory to treat small parameter changes in dispersive plasmonic nanostructures and metamaterials. We specifically apply it to dielectric refractive index, and metallic plasma frequency modulation in metaldielectric nanostructures. As a numerical demonstration, we verify the theory’s accuracy against direct calculations, for a system of plasmonic rods in air where the metal is defined by a two-pole fit of silver’s dielectric function. We also discuss new optical behavior related to plasma frequency modulation in such systems. Our approach provides new physical insight for the design of plasmonic devices for biochemical sensing and optical modulation, and future active metamaterial applications.

Exceptional contours and band structure design in parity-time symmetric photonic crystals

We investigate the properties of two-dimensional parity-time symmetric periodic systems whose non-Hermitian periodicity is an integer multiple of the underlying Hermitian systems periodicity. This creates a natural set of degeneracies that can undergo thresholdless PT transitions. We derive a k·p perturbation theory suited to the continuous eigenvalues of such systems in terms of the modes of the underlying Hermitian system. In photonic crystals, such thresholdless PT transitions are shown to yield significant control over the band structure of the system, and can result in all-angle supercollimation, a PT-superprism effect, and unidirectional behavior.