Abdullah Yasar

Transesterification of oil extracted from different species of algae for biodiesel production.

In the current study, biodiesel production efficiency of C hlorella vulgaris, Rhizoclonium hieroglyphicum and mixed algae culture was measured by transesterification process. Growth rate of algal species was measured on the basis of increase in their dry matter in various media. Protein, carbohydrates and lipids in all selected algae were measured on dry matter basis. Extracted oil was analyzed for water contents, iodine value, saponification value, acid number and fatty acid composition. Transesterification of algal oil was performed by using sodium methoxide as a catalyst. Yield of biodiesel from extracted oil was calculated for C. vulgaris (95%), R. hieroglyphicum (91%) and mixed algae culture (92%). Produced biodiesel was analyzed for kinematic viscosity (4.9, 5.0 and 4.7 mm2/s), flash point (160, 156 and 155°C), specific gravity (0.91, 0.914 and 0.912 g/ml), cetain number (51, 49 and 47 min), iodine value (47, 53 and 49 mg/g), acid number (0.49, 0.5 and 0.46 mg.KOH/g), carbon residue (0.01, 0.02 and 0.01 mass%), sulfated ash (0.007, 0.003 and 0.004 mass%), sulphur (0.013, 0.012 and 0.01 wt%) and water contents (15, 23 and 17 mg/kg) for C. vulgaris, R. hieroglyphicum and mixed algae culture, respectively. Properties of biodiesel were compared with ASTM standards and it was found with high quality biodiesel. Key words: Biodiesel, oil extraction, algae, transesterification.

Comparison of cost and treatment efficiency of solar assisted advance oxidation processes for textile dye bath effluent

The study investigated the efficiency and cost effectiveness of solar-assisted photochemical processes in comparison with advance oxidation processes (AOPs) for the textile effluents treatment. Efficiency of UV irradiation alone for one hour in removing color was almost double in comparison to solar radiation alone for effluents of different dye concentrations (E1>E2>E3). For coupled UV/H2O2 process, there was higher color removal efficiency obtained for effluent E3 (85%) as compared to E2 (70%) and E1 (57%), while E1 showed higher COD removal efficiency (70%) as compared to E2 (50%) and E3 (62%). However, the efficiency of solar/H2O2 for COD removal was comparable to UV/H2O2, i.e., E2 (57%) and E3 (53%). In the case of UV and solar-assisted photo-Fenton processes, removal efficiency of the UV process was further increased as approached to almost 90% removal for E1; on the other hand, the solar-assisted process efficiency remained the same. The relative efficiencies of AOPs were found to be in the order of UV assisted photo-Fenton process>UV/H2O2>UV alone. Although, solar-assisted Fenton treatments were relatively low and slow but without any energy consumption in comparison to high energy consumption of UV. Among the UV processes, UV assisted photo-Fenton treatment appeared to have better color removal efficiency with energy requirements of 5 kWh/m3, 8 kWh/m3 and 3 kWh/m3 for E1, E2 and E3, respectively.

TECHNO-ECONOMIC IMPACTS OF INNOVATIVE COMMERCIAL- INDUSTRIAL SCALE BIOENERGY PLANT IN PAKISTAN

A case study of an innovative medium sized commercial-industrial bioenergy plant is portrayed. This plant effectively runs on various agricultural waste feedstocks like; animal-manure, vegetable, poultry and sugar wastes etc. The plant design is based on anaerobic fixed dome triple digester system connected via underground lagoon. Thus system is facilitating continuous flow of the input feedstock capacity up-to four tonnes per day. This modern scheme is built on innovation with the inclusion of mechanical stirrers, gas scrubbers, filtration, compression and storage systems. This research paper highlighted the potential techno-economic impacts of such bioenergy plant for the energy stressed small-medium industrial sector in developing countries like Pakistan. It has the capability of 142 MWh energy generations per year; rate of return 15.42% and employment growth prospects in SME sector up-to 55%.

Bioenergy recovery analysis from various waste substrates by employing a novel industrial scale AD plant

ABSTRACT In this novel industrial scale case study, the bioenergy recovery based on sole and mixed cow-buffalo (CBM) and potato waste (PW) substrates has been analyzed in real time, i.e., on-site on a full-scale operational anaerobic digestion (AD) plant. The plant employed in this study is a novel design, consisting of tri-digesters connected via an underground upflow anaerobic sludge blanket (UASB) type lagoon allowing it to function as a continuous-flow reactor. The system has been further equipped with CSTR, microwave heating, gas scrubbers, compression, and storage systems. The highest energy recovery readings were 123.9 m3/1,000 kg, 77 m3/1,000 kg, and 151.6 kWh/1,000 kg in terms of biogas, bio-methane, and electricity generated, respectively, with 75:25 ratio of CBM:PW. Operating with 100% CBM, yields of 79.9 m3/1,000 kg, 47 m3/1,000 kg, and 95 kWh/1,000 kg were obtained. The percentage of recovery in bio-methane production increased on using the mixed substrates, but it was the lowest with a 25:75 ratio of CBM:PW. The electrical power generation efficiency was found to be significantly increased, but not distinctively with the plant aggregate power rating that was probably associated with the variable quality of biogas which was fed to the power generator. A linear regression analysis had shown a significant and positive correlation between the rate of VS removal and biogas yield.

Phytoremediation of organochlorine and pyrethroid pesticides by aquatic macrophytes and algae in freshwater systems

ABSTRACT Extensive use of Pesticides in agriculture and its surface runoff in river water is a major environmental concern. The present study evaluated the phytoremediation potential of Eichornia crassipes, Pistia strateotes and algae (Chaetomorpha sutoria, Sirogonium sticticum and Zygnema sp.) for organochlorine and pyrethroid pesticides. Water and plant samples were extracted by liquid phase and solid phase extraction respectively and analyzed by high-performance liquid chromatography. Eleven treatments (T1–T11) with and without plants were used for phytoremediation of organochlorine and pyrethroid pesticides. During the experiment, P. strateotes, E. crassipes and algae (C. sutoria, S. sticticum and Zygnema sp.) showed the highest removal efficiency with 62 (71% root, 29% shoot), 60 (67% root, 33% shoot), and 58% respectively for organochlorine and 76 (76% root, 24% shoot), 68 (69% root, 31% shoot), and 70% respectively for pyrethroids for the respective aquatic plants. Dissipation rate constant of treatments with plants (T2, T3, T5, T6, T8, and T9) was significantly higher (p < 0.05) as compared to that of treatments without plants (T10 and T11, control) for both organochlorine and pyrethroid. The bioconcentration factor of pyrethroid treatments (T3, T6, and T9) was significantly higher (p < 0.05) as compared to that of organochlorine treatments (T2, T5 and T8). The removal efficiency of E. crassipes, P. strateotes and algae (C. sutoria, S. sticticum and Zygnema sp.) for pyrethroids was significantly higher (p < 0.01) as compared to that of organochlorine.

Spatio-temporal variations in physico-chemical parameters and potentially harmful elements (PHEs) of Uchalli Wetlands Complex (Ramsar site), Pakistan

Uchalli Wetlands Complex (UWC) is located in District Khushab, Pakistan, which comprised of three lakes named Khabeki, Uchalli, and Jahlar. The UWC Pakistan is one of the Ramsar sites of international importance. However, the information regarding water quality parameters and concentration of potentially harmful elements (PHEs) is relatively short. Present study focused on spatio-temporal variations in the physico-chemical parameters and PHE (Cd, Pb, Ni, Cu, Zn, Cr, As, Mn) concentrations in water and fish samples using inductively coupled plasma. Sampling was done in summer (August 2016) and winter (January 2017) seasons. The overall concentrations of PHEs in water were in the following order: Mn > Zn > Cu > Cr > Ni > Cd > Pb > As for Khabeki; As >Ni > Cr > Mn > Zn > Cu > Cd > Pb for Uchalli; and Mn > Zn > Ni > Cu > As > Cr > Cd > Pb for Jahlar Lake. PHE concentration in fish followed the order Ni > Cd > Mn > Pb > Cu > Zn > Cr > As. PHEs analysis showed that Mn; Ni and As; and Ni and Mn in summer were above the Pakistan Environmental Quality Standards (PEQS) and World Health Organization (WHO) standards in Khabeki, Uchalli, and Jahlar Lakes respectively while in winter, Mn; Cd, Ni, and As; and Ni and Mn were higher than standard values in Khabeki, Uchalli, and Jahlar Lakes respectively. In fish samples, only Cd (0.0942) was higher in summer as compared to winter (0.0512) while other seven PHEs observed were higher in winter. Conclusively, the metal pollution index showed that water quality of UWC is not very fit for human consumption directly. The bioconcentration factor results indicated potential to accumulate PHEs, i.e., Cd (29.4375 and 9.4814), Pb (16.66 and 4.375), and Ni (4.9875 and 6.206), in fish during both sampling campaigns. Target hazard quotient (THQ), target carcinogenic risk (TR), hazard index (HI), estimated daily intake (EDI), and international safe standard limits of PHEs for fish species indicated that fish from UWC is safe for human consumption. Variations in physic-chemical parameters and PHE concentration were observed spatially and temporally that could be caused by precipitation amount or natural geochemistry of the lakes’ crust. The water quality was not suitable for direct human consumption. Fish was only found in Khabeki Lake that had potential to accumulate Cd, Pb, and Ni more as compared to other studied PHEs.

Determination and dispersion of pollutants from different fuel types used in brick kilns by using Gaussian’s plume model

ABSTRACT The present study was conducted to compare the concentration of pollutants and their level of dispersion in the atmosphere from the plume of brick kilns using different types of fuels. For this purpose, two brick kilns were selected based on their fuel type. One type of fuel was good quality coal (F1) and the other was low-quality coal mixed with wood (F2). The air emissions data illustrated that carbon monoxide concentration was more (108 ± 0.90 ppm) in the plume of F1 than in the plume of F2 (82 ± 0.98 ppm) and sulfur dioxide was more (1955 ± 3.76 ppm) in the plume of F2 than in the plume of F1 (6 ± 0.07 ppm). The Gaussian plume model showed that plume from good quality coal as fuel (F1) disperses 0.7 ± 0.01 km horizontally and 4 ± 0.03 km vertically whereas the plume from low-quality coal mixed with wood (F2) disperse 1 ± 0.01 km horizontally and 2 ± 0.02 km vertically. Pearson correlation also showed a significant (p < 0.05) difference between both fuel types. These high concentrations can have negative impacts on the atmospheric environment as well as community health.

Refuse-derived fuels as a renewable energy source in comparison to coal, rice husk, and sugarcane bagasse

ABSTRACT The calorific potential of refuse-derived fuels (RDFs) was investigated with different coals, rice husk, and sugarcane bagasse. Carbon-sulfur analysis, gross calorific value (kJ/kg), and proximate analysis (%) were carried out. Total carbon of coal samples was found to be in the range from 62.65 to 79.19%, while RDF samples were ranged from 40.21 to 57.34% which were almost similar to rice husk (49.13%) and sugarcane bagasse (46.13%). Comparison of the total sulfur content of the coal (Duki) (10.52%) was very high as compared to RDF samples ranged from 0.17 to 0.46% and almost similar to rice husk (0.34%) and sugarcane bagasse (0.187%), while other coal samples ranged from 2.1 to 4.5%. The gross calorific value of the coal (Duki) (6,163 kJ/kg) was higher to other coal samples ranged from 4,935 to 4,972 kJ/kg, while found to be almost double to rise husk (3,518 kJ/kg), sugarcane bagasse (3,285 kJ/kg), and RDF samples (3,125–4,689 kJ/kg). The moisture content, volatile matter, and ash content were found higher in RDF 1 (42.14%), RFD 2 (66.55%), and coal (stone) (33.14%), respectively. Appropriate gross calorific value and very low sulfur content of the RDFs, especially RDF 2, appeared adequate to be used as a fuel with a lesser pollution potential and as an alternative fuel in mega cement industry of Pakistan.

Human Health Risk Surveillance Through the Determination of Organochlorine Pesticides by High-Performance Liquid Chromatography in Water, Sediments, and Fish from the Chenab River, Pakistan

ABSTRACT The current study assessed the spatiotemporal variations and human health surveillance associated with organochlorine pesticide (OCP) contamination in water, sediments, and fish from Chenab River, Pakistan. The OCP determinations were performed using high-performance liquid chromatography with a reverse-phase C18 column. The total OCP levels ranged from 13.33 to 274.59 ng/L in water, 4.63 to 239.11 ng/g in sediments, and 23.79 to 387.12 ng/g in fish species. The overall pattern of mean OCP concentrations followed the order as ΣDDTs > Σendosulfan > aldrin and OCP pollution pattern among the headworks were Khanki Barrage > Qadirabad Barrage > Trimmu Barrage > Marala Barrage in all three environmental matrixes during both seasons. The estimated daily intake (EDI) for ∑OCPs was found to be 22.44 ng/kg/day. The hazard ratios calculated to assess the carcinogenic risk indicated that the values for ∑DDT and aldrin at the 95th percentile concentrations were greater than one, indicating the probability of carcinogenic risk occurrence of one in million populations due to fish consumption. Therefore, these high levels of OCPs and carcinogenic risk through fish consumption highlight the needs of immediate elimination of OCPs from riverine environment of Chenab River and we recommend long-term monitoring-based freshwater ecological studies to be conducted in the study area.

Phytoremediation Using Aquatic Macrophytes

Phytoremediation is a plant-based technology that is also called green technology. After the discovery of hyperaccumulating plants, this technology gained increasing attention. These hyperaccumulating plants are having the ability to uptake, store, transport, and focus on large quantity of specific poisonous elements in their body parts such as aboveground parts and harvestable parts. Phytoremediation has a number of processes that are phytoextraction, rhizofiltration, phytovolatilization, etc. Both type of plants (terrestrial and aquatic) have been tested, and these are having characteristics to treat polluted soils and waters. A number of aquatic macrophytes have been found that are used for the removal of toxic contaminants such as arsenic, zinc, cadmium, copper, lead, chromium, and mercury. Some of these aquatic macrophytes are water hyacinth, water spinach, water ferns, hydrilla, and watercress. Metal uptake ability and mechanisms of many other macrophytes have been studied or investigated. Many of these studies proved that aquatic macrophytes have potential for phytoremediation. Phytoremediation is cost-effective, environment-friendly, and has gained rising appreciation. More than 400 plant species have been known that are having the ability to remediate soil and water. This chapter provides a look into new developments in research and practical applications of phytoremediation by using aquatic macrophytes.