Adam D. Downey

Characterization of thermoelectric elements and devices by impedance spectroscopy.

This article describes a new measurement technique that utilizes impedance spectroscopy for the characterization of thermoelectric materials and devices. Two circuit models were developed and used to help explain the impedance spectroscopy data using transmission line theory and a coupled electrothermal model. Two testing configurations have been investigated including one based on a sinusoidal source (ac lock-in technique) and one based on a pulsed wave source. Methods for reducing the measurement times for this technique are discussed. In addition, the influence of radiation losses on this measurement technique has also been analyzed to further understand the limitations of this technique at higher temperatures.

Temperature dependent thermoelectric material power factor measurement system

Thermoelectric materials can be used for cooling/heating applications, or converting waste heat into electricity. Novel thermoelectric materials have been discovered in recent years. Characterization of an electrical conductivity and thermopower of a sample from room temperature to > or = 900 K is often necessary for thermoelectric materials. This paper describes a system built for measurement of the power factor of thermoelectric materials from 300 to 1273 K. Characterization results of the system are also presented.

Statistical Analysis of a Round-Robin Measurement Survey of Two Candidate Materials for a Seebeck Coefficient Standard Reference Material.

In an effort to develop a Standard Reference Material (SRM™) for Seebeck coefficient, we have conducted a round-robin measurement survey of two candidate materials—undoped Bi2Te3 and Constantan (55 % Cu and 45 % Ni alloy). Measurements were performed in two rounds by twelve laboratories involved in active thermoelectric research using a number of different commercial and custom-built measurement systems and techniques. In this paper we report the detailed statistical analyses on the interlaboratory measurement results and the statistical methodology for analysis of irregularly sampled measurement curves in the interlaboratory study setting. Based on these results, we have selected Bi2Te3 as the prototype standard material. Once available, this SRM will be useful for future interlaboratory data comparison and instrument calibrations.

Transport behavior and thermal conductivity reduction in the composite system PbTe-Pb-Sb

We report the synthesis of nanostructured composite PbTe with excess Pb and Sb metal inclusions. Scanning and transmission electron microscopy reveal these inclusions in both the nano- and macroscales. The electrical conductivity and Seebeck coefficient dependence on temperature show unusual trends which depend on the inclusion Pb/Sb ratio. Several ratios showed marked enhancements in power factor at 700 K. The thermal conductivity of these composites is reported.

Application of Transmission Line Theory for Modeling of a Thermoelectric Module in Multiple Configurations for AC Electrical Measurements

Measurements of assembled thermoelectric modules commonly include investigations of the module output power versus load resistance. Such measurements include non-ideal effects such as electrical and thermal contact resistances. Using an AC electrical measurement, two models for a thermoelectric module have been developed utilizing electrical circuits for both the thermal and electrical characteristics of the module. Measurements were taken over the frequency range of 1mHz to 500Hz using lock-in amplifiers. We present data showing the extraction of ZT from such measurements on commercially available modules utilizing both the magnitude and phase of the measured impedance. Here we extend upon a simple RC equivalent circuit model by utilizing transmission line theory in electrical circuits to explain the thermal activity in a thermoelectric module. This model includes all components of a module such as nickel traces and ceramic end caps, and makes use of their corresponding thermal conductivities, thermal capacitance, and density. This model can then be applied to pn unicouples in either a standard or inline configuration, and to individual p or n legs of the module. Data is presented showing the advantages of both models. Measurements on new thermoelectric materials and modules are also presented.

Progress on the Fabrication and Characterization of High Efficiency Thermoelectric Generators

Timothy P. Hogan, Adam D. Downey, Jarrod Short, Jonathan D’Angelo, Eric Quarez, John Androulakis, Pierre F. P. Poudeu, Mercouri G. Kanatzidis, Ed Timm, Kim Sarbo, Harold Schock Department of Electrical and Computer Engineering, Michigan State University, East Lansing, MI 48824, U.S.A. Chemistry Department, Michigan State University, East Lansing, MI 48824, U.S.A. Department of Mechanical Engineering, Michigan State University, East Lansing, MI 48824, U.S.A.

Effects of Antimony on the Thermoelectric Properties of the Cubic Pb 9.6 Sb y Te 10−x Se x Materials

The thermoelectric properties of Pb9.6SbyTe10-xSex were investigated in the intermediate temperature range of 300 – 700 K. The effect of the variation of Sb content (y) on the electronic properties of the materials is remarkable. Samples with compositions Pb9.6Sb0.2Te10xSex (y = 0.2) show the best combination of low thermal conductivity with moderate electrical conductivity and thermopower. For Pb9.6Sb0.2Te8Se2 (x = 2) a maximum figure of merit of ZT~ 1.1 was obtained around 700 K. This value is nearly 1.4 times higher than that of PbTe at 700 K. This enhancement of the figure of merit of Pb9.6Sb0.2Te8Se2 derives from its extremely low thermal conductivity (~0.7 at W/m.K at 700 K). High resolution transmission electron microscopy of Pb9.6Sb0.2Te10-xSex samples shows broadly distributed Sb-rich nanocrystals, which may be the key feature responsible for the suppression of the thermal conductivity.

Investigation of Low Resistance Contacts to Pb-Sb-Ag-Te (LAST) Materials for Module Fabrication

Low electrical contact resistance is essential for the fabrication of high efficiency thermoelectric generators. These contacts must be stable to high temperatures and through thermal cycling. Here we present the fabrication procedure and characterization of several contacts to Pb-Sb-Ag-Te (LAST) compounds. Contact materials investigated include tungsten, antimony, tin, nickel, and a bismuth antimony based solder. The contacts were typically deposited by an electron beam evaporation method after careful preparation of the sample surface. The resistances were measured by using the transmission line model (TLM), and ohmic behavior was verified through current vs. voltage measurements. The best contact resistivities of less than 20 µΩ·cm 2 have been measured for annealed antimony to n-type LAST samples. We present these procedures for fabricating low resistance contacts and the use of these contact materials toward the fabrication of high efficiency thermoelectric generator modules.

Characterization of Thermoelectric Power Generation Modules Made from New Materials

Lead-Antimony-Silver-Tellurium (L-A-S-T) materials, synthesized at Michigan State University, show promising thermoelectric properties at high temperatures for use in power generation applications. Recent scaled-up quantities of L-A-S-T show a ZT=1.4 at 700 K approaching the figure of merit for samples made in small quantities [1]. These materials are of great interest for power generation applications with hot side temperatures in the range of 600800 K. Developing these materials into working devices requires minimization of the thermal and electrical parasitic contact resistances, so various fabrication methods are under investigation. To examine each method, a new measurement system has been developed to characterize these devices under various load and temperature gradients. An introduction to the system will be presented, as well as results for devices made of the L-A-S-T materials.