Aleksander K. Wójcik

Nanoscale imaging magnetometry with diamond spins under ambient conditions

Magnetic resonance imaging and optical microscopy are key technologies in the life sciences. For microbiological studies, especially of the inner workings of single cells, optical microscopy is normally used because it easily achieves resolution close to the optical wavelength. But in conventional microscopy, diffraction limits the resolution to about half the wavelength. Recently, it was shown that this limit can be partly overcome by nonlinear imaging techniques, but there is still a barrier to reaching the molecular scale. In contrast, in magnetic resonance imaging the spatial resolution is not determined by diffraction; rather, it is limited by magnetic field sensitivity, and so can in principle go well below the optical wavelength. The sensitivity of magnetic resonance imaging has recently been improved enough to image single cells, and magnetic resonance force microscopy has succeeded in detecting single electrons and small nuclear spin ensembles. However, this technique currently requires cryogenic temperatures, which limit most potential biological applications. Alternatively, single-electron spin states can be detected optically, even at room temperature in some systems. Here we show how magneto-optical spin detection can be used to determine the location of a spin associated with a single nitrogen-vacancy centre in diamond with nanometre resolution under ambient conditions. By placing these nitrogen-vacancy spins in functionalized diamond nanocrystals, biologically specific magnetofluorescent spin markers can be produced. Significantly, we show that this nanometre-scale resolution can be achieved without any probes located closer than typical cell dimensions. Furthermore, we demonstrate the use of a single diamond spin as a scanning probe magnetometer to map nanoscale magnetic field variations. The potential impact of single-spin imaging at room temperature is far-reaching. It could lead to the capability to probe biologically relevant spins in living cells.

Giant superfluorescent bursts from a semiconductor magneto-plasma

Superfluorescence—the emission of coherent light from an initially incoherent collection of excited dipoles—is now identified in a semiconductor. Laser-excited electron–hole pairs spontaneously polarize and then abruptly decay to produce intense pulses of light.

Collective antenna effects in the terahertz and infrared response of highly aligned carbon nanotube arrays

We study macroscopically aligned single-wall carbon nanotube arrays with uniform lengths via polarizationdependent terahertz and infrared transmission spectroscopy. Polarization anisotropy is extreme at frequencies less than ∼100 cm −1 with no sign of attenuation when the polarization is perpendicular to the alignment direction. The attenuation for both parallel and perpendicular polarizations increases with increasing frequency, exhibiting a pronounced and broad peak around 450 cm −1 in the parallel case. We model the electromagnetic response of the sample by taking into account both radiative scattering and absorption losses. We show that our sample acts as an effective antenna due to the high degree of alignment, exhibiting much larger radiative scattering than absorption in the mid/far-infrared range. Our calculated attenuation spectrum clearly shows a non-Drude peak at ∼450 cm −1 in agreement with the experiment.

Generation of picosecond pulses and frequency combs in actively mode locked external ring cavity quantum cascade lasers

We propose a robust and reliable method of active mode locking of mid-infrared quantum cascade lasers and develop its theoretical description. Its key element is the use of an external ring cavity, which circumvents fundamental issues undermining the stability of mode locking in quantum cascade lasers. We show that active mode locking can give rise to the generation of picosecond pulses and phase-locked frequency combs containing thousands of the ring cavity modes.

External ring-cavity quantum cascade lasers

An external ring-cavity quantum cascade laser (QCL) is demonstrated. Gain competition between the clockwise and anticlockwise ring-cavity modes results in a transition from bidirectional to directional emission as current is increased. In the directional regime, spatial hole burning (SHB) is suppressed, and the spectrum evolves to a single longitudinal mode, in contrast with the multimode spectrum of a comparable Fabry-Perot QCL. The absence of SHB and the long path-length of the external cavity make this laser an excellent candidate for active mode-locking and high-sensitivity spectroscopic applications in the mid-infrared. A proof-of-principle intracavity absorption spectroscopic detection of water vapor is demonstrated.

Fermi-edge superfluorescence from a quantum-degenerate electron-hole gas

Nonequilibrium can be a source of order. This rather counterintuitive statement has been proven to be true through a variety of fluctuation-driven, self-organization behaviors exhibited by out-of-equilibrium, many-body systems in nature (physical, chemical, and biological), resulting in the spontaneous appearance of macroscopic coherence. Here, we report on the observation of spontaneous bursts of coherent radiation from a quantum-degenerate gas of nonequilibrium electron-hole pairs in semiconductor quantum wells. Unlike typical spontaneous emission from semiconductors, which occurs at the band edge, the observed emission occurs at the quasi-Fermi edge of the carrier distribution. As the carriers are consumed by recombination, the quasi-Fermi energy goes down toward the band edge, and we observe a continuously red-shifting streak. We interpret this emission as cooperative spontaneous recombination of electron-hole pairs, or superfluorescence (SF), which is enhanced by Coulomb interactions near the Fermi edge. This novel many-body enhancement allows the magnitude of the spontaneously developed macroscopic polarization to exceed the maximum value for ordinary SF, making electron-hole SF even more “super” than atomic SF.

Nonlinear optical interactions of laser modes in quantum cascade lasers

We overview the results of recent experimental and theoretical studies of nonlinear dynamics of mid-infrared quantum cascade lasers (QCLs) associated with nonlinear interactions of laser modes. Particular attention is paid to phase-sensitive nonlinear mode mixing which turns out to be quite prominent in QCLs of different kinds and which gives rise to frequency and phase locking of laser modes. Nonlinear phase coupling of laser modes in QCLs leads to a variety of ultrafast and coherent phenomena: synchronization of transverse modes, beam steering, the RNGH multimode instability, and generation of mode-locked ultrashort pulses.

Above-bandgap magneto-optical Kerr effect in ferromagnetic Ga(1-x)Mn(x)As

We have performed a systematic magneto-optical Kerr spectroscopy study of GaMnAs with varying Mn densities as a function of temperature, magnetic field, and photon energy. Unlike previous studies, the magnetization easy axis was perpendicular to the sample surface, allowing us to take remanent polar Kerr spectra in the absence of an external magnetic field. The remanent Kerr angle strongly depended on the photon energy, exhibiting a large positive peak at

Generation of superfluorescent bursts from a fully tunable semiconductor magneto-plasma

\sim1.7

Nonlinear coupling of transverse modes in quantum cascade lasers

eV. This peak increased in intensity and blue-shifted with Mn doping and further blue-shifted with annealing. Using a 30-band