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Dive into the research topics where Alexander A. Govyadinov is active.

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Featured researches published by Alexander A. Govyadinov.


Nano Letters | 2012

Nano-FTIR Absorption Spectroscopy of Molecular Fingerprints at 20 nm Spatial Resolution

Florian Huth; Alexander A. Govyadinov; Sergiu Amarie; Wiwat Nuansing; Fritz Keilmann; Rainer Hillenbrand

We demonstrate Fourier transform infrared nanospectroscopy (nano-FTIR) based on a scattering-type scanning near-field optical microscope (s-SNOM) equipped with a coherent-continuum infrared light source. We show that the method can straightforwardly determine the infrared absorption spectrum of organic samples with a spatial resolution of 20 nm, corresponding to a probed volume as small as 10 zeptoliter (10(-20) L). Corroborated by theory, the nano-FTIR absorption spectra correlate well with conventional FTIR absorption spectra, as experimentally demonstrated with poly(methyl methacrylate) (PMMA) samples. Nano-FTIR can thus make use of standard infrared databases of molecular vibrations to identify organic materials in ultrasmall quantities and at ultrahigh spatial resolution. As an application example we demonstrate the identification of a nanoscale PDMS contamination on a PMMA sample.


Nature Communications | 2013

Structural analysis and mapping of individual protein complexes by infrared nanospectroscopy

Iban Amenabar; Simon Poly; Wiwat Nuansing; Elmar H. Hubrich; Alexander A. Govyadinov; Florian Huth; Roman Krutokhvostov; Lianbing Zhang; Mato Knez; Joachim Heberle; Alexander M. Bittner; Rainer Hillenbrand

Mid-infrared spectroscopy is a widely used tool for material identification and secondary structure analysis in chemistry, biology and biochemistry. However, the diffraction limit prevents nanoscale protein studies. Here we introduce mapping of protein structure with 30 nm lateral resolution and sensitivity to individual protein complexes by Fourier transform infrared nanospectroscopy (nano-FTIR). We present local broadband spectra of one virus, ferritin complexes, purple membranes and insulin aggregates, which can be interpreted in terms of their α-helical and/or β-sheet structure. Applying nano-FTIR for studying insulin fibrils—a model system widely used in neurodegenerative disease research—we find clear evidence that 3-nm-thin amyloid-like fibrils contain a large amount of α-helical structure. This reveals the surprisingly high level of protein organization in the fibril’s periphery, which might explain why fibrils associate. We envision a wide application potential of nano-FTIR, including cellular receptor in vitro mapping and analysis of proteins within quaternary structures.


Physical Review B | 2006

Metamaterial photonic funnels for subdiffraction light compression and propagation

Alexander A. Govyadinov; Viktor A. Podolskiy

We present waveguides with photonic crystal cores, supporting energy propagation in subwavelength regions with a mode structure similar to that in telecom fibers. We design meta-materials for near-, mid-, and far-IR frequencies, and demonstrate efficient energy transfer to and from regions smaller than 1/25-th of the wavelength. Both positive- and negative-refractive index light transmissions are shown. Our approach, although demonstrated here in circular waveguides for some specific frequencies, is easily scalable from optical to IR to THz frequency ranges, and can be realized in a variety of waveguide geometries. Our design may be used for ultra high-density energy focusing, nm-resolution sensing, near-field microscopy, and high-speed all-optical computing.


Applied Physics Letters | 2007

Active metamaterials: sign of refractive index and gain-assisted dispersion management

Alexander A. Govyadinov; Viktor A. Podolskiy; M. A. Noginov

We derive an approach to determine the causal direction of wavevectors of modes in optical metamaterials, which, in turn, determines signs of refractive index and impedance as a function of real and imaginary parts of dielectric permittivity and magnetic permeability. We use the developed technique to demonstrate that the interplay between resonant response of constituents of metamaterials can be used to achieve efficient dispersion management. Finally, we demonstrate broadband dispersionless index and impedance matching in active nanowire-based negative index materials. Our work has a potential to open new practical applications of negative index composites for broadband lensing, imaging, and pulse routing.


Journal of Physical Chemistry Letters | 2013

Quantitative Measurement of Local Infrared Absorption and Dielectric Function with Tip-Enhanced Near-Field Microscopy.

Alexander A. Govyadinov; Iban Amenabar; Florian Huth; P. Scott Carney; Rainer Hillenbrand

Scattering-type scanning near-field optical microscopy (s-SNOM) and Fourier transform infrared nanospectroscopy (nano-FTIR) are emerging tools for nanoscale chemical material identification. Here, we push s-SNOM and nano-FTIR one important step further by enabling them to quantitatively measure local dielectric constants and infrared absorption. Our technique is based on an analytical model, which allows for a simple inversion of the near-field scattering problem. It yields the dielectric permittivity and absorption of samples with 2 orders of magnitude improved spatial resolution compared to far-field measurements and is applicable to a large class of samples including polymers and biological matter. We verify the capabilities by determining the local dielectric permittivity of a PMMA film from nano-FTIR measurements, which is in excellent agreement with far-field ellipsometric data. We further obtain local infrared absorption spectra with unprecedented accuracy in peak position and shape, which is the key to quantitative chemometrics on the nanometer scale.


Physical Review B | 2008

From Slow to Superluminal Propagation: Dispersive Properties of Surface Plasmon Polaritons in Linear Chains of Metallic Nanospheroids

Alexander A. Govyadinov; Vadim A. Markel

We consider propagation of surface plasmon polaritons (SPPs) in linear periodic chains (LPCs) of prolate and oblate metallic spheroids. We show that the SPP group velocity can be efficiently controlled by varying the aspect ratio of the spheroids. For sufficiently small aspect ratios, a gap appears in the first Brillouin zone of the chain lattice in which propagating modes do not exist. Depending on the SPP polarization, the gap extends to certain intervals of the Bloch wave number


Applied Physics Letters | 2015

Nanoscale-resolved chemical identification of thin organic films using infrared near-field spectroscopy and standard Fourier transform infrared references

Stefan Mastel; Alexander A. Govyadinov; Thales V. A. G. de Oliveira; Iban Amenabar; Rainer Hillenbrand

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Optics Express | 2012

Enhanced resolution in subsurface near-field optical microscopy

Roman Krutokhvostov; Alexander A. Govyadinov; Johannes M. Stiegler; Florian Huth; Andrey Chuvilin; P. Scott Carney; Rainer Hillenbrand

. Thus, for transverse polarization, no propagating SPPs exist with wave numbers


ACS Nano | 2014

Recovery of Permittivity and Depth from Near-Field Data as a Step toward Infrared Nanotomography

Alexander A. Govyadinov; Stefan Mastel; Federico Golmar; Andrey Chuvilin; P. Scott Carney; Rainer Hillenbrand

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ACS Nano | 2012

Phase in Nanooptics

P. Scott Carney; Bradley Deutsch; Alexander A. Govyadinov; Rainer Hillenbrand

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Viktor A. Podolskiy

University of Massachusetts Lowell

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Dzmitry Melnikau

Spanish National Research Council

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Javier Aizpurua

University of the Basque Country

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