Alfonso Yuste

QUATERNARY ALLUVIAL SINKHOLES: RECORD OF ENVIRONMENTAL CONDITIONS OF KARST DEVELOPMENT, EXAMPLES FROM THE EBRO BASIN, SPAIN

The central Ebro Basin is an exceptional region for studying karstification through time and under different environmental conditions, as sinkholes have been developing since the Early Pleistocene. Knowledge of active sinkholes is complemented with research on paleosinkholes and contemporary deposits. Sedimentological, min- eralogical, geomorphological and structural approaches permit interpretation of the natural environmental conditions that favored karst in the past and the main genetic mechanisms involved. The sedimentary features of Pleistocene terraces indicate that they were deposited by a gravel braided fluvial system characterized by higher water and sediment availability than today, probably related to meltwater flows coming from glaciated source areas, mainly in the Pyrenees. Genesis of paleosinkholes was mainly linked to this high water supply. Some of them acted as small lakes where fine sediments are exceptionally well conserved to give clues about environmental conditions. The neo- formation of palygorskite and sepiolite suggests arid to semiarid climatic conditions, in agreement with the idea of cold glacial episodes. During Pleistocene times, development of sinkholes was influenced by tectonics. Currently, the genesis and evolution of numerous sinkholes are also influenced by water supplies from human activities such as irrigation or urbanization, sharply changing the nearly steady state exhibited in the past.

Microtexture and genesis of clay minerals from a turbiditic sequence in a Southern Pyrenees foreland basin (Jaca basin, Eocene)

Abstract A set of fine-grained samples from a turbiditic sequence in a Southern Pyrenees foreland basin (Jaca Basin, Eocene) were studied to determine the influence of tectonics (Pyrenean Orogeny) on phyllosilicate recrystallization and infer the grade and basin maturity. The samples from four different outcrops were examined by X-ray diffraction (XRD) and by scanning (SEM) and transmission electron microscopy (TEM) with special emphasis on clay-mineral characterization (e.g. illitic phases). The analysed samples have simple mineral assemblages and consist of detrital quartz, albite and calcite, scarce clay matrix (mainly illite with chlorite), and calcite and dolomite cement. The lack of other phyllosilicates such as mixed-layer illite-smectite (I-S), pyrophyllite, Na-micas, or kaolin minerals is quite remarkable. On the SEM scale, samples (with marl composition) have poorly sorted textures and high detrital contents. In many cases they show bedding and/or cleavage, and in some cases neither is observed. Most of the clay-sized illites show very similar crystallinity and b0 values (determined by XRD) and distributions of crystallite thickness (measured by TEM) in all the outcrops, which is typical of late-diagenesis illites forming under low-pressure conditions. These illites are parallel (or subparallel) to bedding or randomly orientated. They are also characterized by disordered polytypes and low K contents. In some TEM images, a second type of illite has been observed. This secondary illite occurs parallel to cleavage, with thicker crystals (25-35 layers), K contents in the interlayer, and a 2M1 polytype. The pole figure analysis shows that most of the clays have (00l) planes parallel (or subparallel) to bedding although there are abundant clays with random orientation. There is no trend in the clay orientation/disorientation from the south to the north of the basin. All the data indicate that the strain rate associated with the Pyrenean Orogeny has not been recorded in the turbidite sequence controlling the relative orientation of clays, although anchizonal clay crystallization is favoured as a minor process.

Clay mineral assemblages as palaeoclimatic indicators in a shallowing carbonate lacustrine system: Oligocene-Miocene, central Ebro Basin (NE Spain)

Abstract This paper focuses on the clay mineralogy (using XRD, SEM and TEM methods) of the lacustrine ‘‘Calizas de Torrente de Cinca’’ unit that represents the Oligocene-Miocene transition in the central part of the Ebro Basin (NE Spain).Phyllosilicates are mainly detrital although Mgsmectites could have been generated in the lake.Although a temperate, relatively humid climate dominated the source area during the Oligocene-Miocene transition (Chattian-Aquitanian), as deduced by detrital phyllosilicates assemblage, mineralogical vertical trends along with sedimentological studies indicate some changes.Relatively warmer and more humid conditions during the late Chattian, that favoured increasing chemical weathering, were replaced during the early Aquitanian by drier conditions coinciding with the Mi-1 glaciation effects; this change is coeval with a transition from deeper to shallower lacustrine facies. Phyllosilicate association analysis has also permitted an improvement in the palaeogeographical sketch and infers that the Pyrenees are the main source area for the lacustrine system.