Andreas Treu

Toxic hazard and chemical analysis of leachates from furfurylated wood

The furfurylation process is an extensively investigated wood modification process. Furfuryl alcohol molecules penetrate into the wood cell wall and polymerize in situ. This results in a permanent swelling of the wood cell walls. It is unclear whether or not chemical bonds exist between the furfuryl alcohol polymer and the wood. In the present study, five different wood species were used, both hardwoods and softwoods. They were treated with three different furfurylation procedures and leached according to three different leaching methods. The present study shows that, in general, the leachates from furfurylated wood have low toxicity. It also shows that the choice of leaching method is decisive for the outcome of the toxicity results. Earlier studies have shown that leachates from wood treated with furfuryl alcohol prepolymers have higher toxicity to Vibrio fischeri than leachates from wood treated with furfuryl alcohol monomers. This is probably attributable to differences in leaching of chemical compounds. The present study shows that this difference in the toxicity most likely cannot be attributed to maleic acid, furan, furfural, furfuryl alcohol, or 2-furoic acid. However, the difference might be caused by the two substances 5-hydroxymethylfurfural and 2,5-furandimethanol. The present study found no difference in the amount of leached furfuryl alcohol between leachates from furfurylated softwood and furfurylated hardwood species. Earlier studies have indicated differences in grafting of furfuryl alcohol to lignin. However, nothing was found in the present study that could support this. The leachates of furfurylated wood still need to be

Anatomical differences in the structural elements of fluid passage of Scots pine sapwood with contrasting treatability

Treatability of wood is a function of anatomical properties developed under certain growing conditions. While Scots pine sapwood material normally is considered as easy to impregnate, great variations in treatability can be observed. In order to study anatomical differences in the structural elements of transverse fluid passage, wood material with contrasting treatability has been compared. Ray composition and resin canal network, membrane areas of fenestriform pits in the cross-field as well as dimension and properties of bordered pits were investigated. The results showed large anatomical differences between the two contrasting treatability groups. Refractory Scots pine sapwood samples developed more rays per mm2 tangential section, while they were on average lower in cell numbers than rays found in easily treatable material. Easily treatable material had more parenchyma cells in rays than refractory material. At the same time, a larger membrane area in fenestriform pits in the cross-field was observed in the easily treatable sample fraction. Differences in the composition of resin canal network were not observed. Refractory samples developed on average smaller bordered pit features, with relatively small formed pit apertures compared to the easily treatable samples. In refractory Scots pine sapwood material, the structural elements of fluid passage such as bordered pit dimensions, fenestriform pits in the cross-field and parenchyma cells were altogether developed in smaller dimensions or number. Wood samples from better growing conditions and sufficient water supply showed a better treatability in this study.

Combined evaluation of durability and ecotoxicity: A case study on furfurylated wood

Abstract Modified wood is commercially available and merchandized as a new, environmentally friendly and durable wood species. However, there are no standards focusing on the evaluation of modified wood. Combining resistance against fungal decay and good ecotoxicological properties may be a start. In this study softwood and hardwood species were furfurylated using different treatment processes and treating solutions. The durability was determined by exposing the treated wood to a range of Basidiomycetes and the ecotoxicity was studied on two aquatic organisms. It was the purpose to come to a strategy and how to unite efficacy and ecotoxicity, since this is important in product development. The results show that the selection of fungus used for mass loss determination and the choice of ecotoxicity method is decisive, confirming that a combination of methods is valuable. A tiered approach to find the optimal treatment seems the best option. First, adequate protection against wood-rotting fungi should be attained, followed by ecotoxicity evaluation of the wood leachates. If necessary, the optimization process should be repeated until both durability and ecotoxicity are within satisfactory limits. This process could be extended with other evaluation criteria, e.g. dimensional stability of the modified wood or a risk analysis of its leachate.

Utilisation of chemically modified lampante oil for wood protection

Within the Slovenian region of Istria, the olive growing and oil production industry is strong. This industry has a long history and the olives grown here have high levels of biologically active compounds including a variety of phenolic compounds. Using residual materials generated by this industry in potential wood protection systems would not only valorise low-value materials and stimulate rural economies but would also provide an alternative to currently used oil-based protection systems. The objective of this study was to produce an oil treatment for wood protection and assess its efficacy in reducing leaching, weathering effects, and fungal decay. Two maleinisation techniques were used to chemically modify low-value lampante oil in an attempt to limit leaching when impregnated in wood. Pinus sylvestris (Scots pine) and Fagus sylvatica (European beech) were treated with the modified oils and underwent leaching, accelerated weathering, and decay tests. Leaching of the treatment oils was relatively low compared with other experiments and beech wood specimens treated with a direct maleinisation treatment showed improvement in performance compared to control specimens. In addition, it was found that the modified oils were not completely removed from the wood after solvent extraction indicating that they could potentially be used as an immobilisation agent in combination with other treatments thereby reducing the amount of active component of the protective agent.

Classification of creosote bleeding from timber bridges by means of wood anatomical factors

ABSTRACT Creosote is commonly used as a wood preservative for highway timber bridges in Norway. However, excessive creosote bleeding at various highway timber bridge sites lead to complaints, and a potentially bad reputation for wooden timber bridges. Macro-and micro-anatomical factors such as the amount of heartwood, annual ring width, annual ring orientation, ray-height and composition and resin canal area were investigated in order to classify seven timber bridges in Norway into bleeding- and non-bleeding bridges. A classification into bleeding and non-bleeding was possible for discriminant categories based on three anatomical factors analysed on wood core samples. The amount of heartwood content dominated the influencing factors, even obscuring the significance of other factors. Classification with a low amount of variables was done preferably on sample level instead of bridge level, due to the restricted number of 17 core samples per bridge.