Andrew W. Rollins

The NASA Airborne Tropical Tropopause Experiment: High-altitude aircraft measurements in the Tropical Western Pacific

AbstractThe February–March 2014 deployment of the National Aeronautics and Space Administration (NASA) Airborne Tropical Tropopause Experiment (ATTREX) provided unique in situ measurements in the western Pacific tropical tropopause layer (TTL). Six flights were conducted from Guam with the long-range, high-altitude, unmanned Global Hawk aircraft. The ATTREX Global Hawk payload provided measurements of water vapor, meteorological conditions, cloud properties, tracer and chemical radical concentrations, and radiative fluxes. The campaign was partially coincident with the Convective Transport of Active Species in the Tropics (CONTRAST) and the Coordinated Airborne Studies in the Tropics (CAST) airborne campaigns based in Guam using lower-altitude aircraft (see companion articles in this issue). The ATTREX dataset is being used for investigations of TTL cloud, transport, dynamical, and chemical processes, as well as for evaluation and improvement of global-model representations of TTL processes. The ATTREX da...

Evaluation of UT/LS hygrometer accuracy by intercomparison during the NASA MACPEX mission

Acquiring accurate measurements of water vapor at the low mixing ratios (< 10 ppm) encountered in the upper troposphere and lower stratosphere (UT/LS) has proven to be a significant analytical challenge evidenced by persistent disagreements between high-precision hygrometers. These disagreements have caused uncertainties in the description of the physical processes controlling dehydration of air in the tropical tropopause layer and entry of water into the stratosphere and have hindered validation of satellite water vapor retrievals. A 2011 airborne intercomparison of a large group of in situ hygrometers onboard the NASA WB-57F high-altitude research aircraft and balloons has provided an excellent opportunity to evaluate progress in the scientific community toward improved measurement agreement. In this work we intercompare the measurements from the Midlatitude Airborne Cirrus Properties Experiment (MACPEX) and discuss the quality of agreement. Differences between values reported by the instruments were reduced in comparison to some prior campaigns but were nonnegligible and on the order of 20% (0.8 ppm). Our analysis suggests that unrecognized errors in the quantification of instrumental background for some or all of the hygrometers are a likely cause. Until these errors are understood, differences at this level will continue to somewhat limit our understanding of cirrus microphysical processes and dehydration in the tropical tropopause layer.

Observational constraints on the efficiency of dehydration mechanisms in the tropical tropopause layer

The efficiency of dehydration in the tropical tropopause layer (TTL) determines how closely water vapor will be reduced to the lowest saturation mixing ratio encountered along a trajectory to the stratosphere, thereby strongly influencing stratospheric humidity. The NASA Airborne Tropical Tropopause Experiment (ATTREX) provided an unprecedented number and quality of in situ observations to constrain the key mechanisms controlling this dehydration. Statistical analyses of the ATTREX data show that nucleation, growth, and sedimentation each result in TTL dehydration becoming increasingly inefficient at temperatures below 200 K. Because of these inefficiencies, models that ignore these mechanisms likely underestimate water vapor at the stratospheric entry point by ~10–20% at the lowest temperatures.

On the Susceptibility of Cold Tropical Cirrus to Ice Nuclei Abundance

AbstractNumerical simulations of cirrus formation in the tropical tropopause layer (TTL) during boreal wintertime are used to evaluate the impact of heterogeneous ice nuclei (IN) abundance on cold cloud microphysical properties and occurrence frequencies. The cirrus model includes homogeneous and heterogeneous ice nucleation, deposition growth/sublimation, and sedimentation. Reanalysis temperature and wind fields with high-frequency waves superimposed are used to force the simulations. The model results are constrained by comparison with in situ and satellite observations of TTL cirrus and relative humidity. Temperature variability driven by high-frequency waves has a dominant influence on TTL cirrus microphysical properties and occurrence frequencies, and inclusion of these waves is required to produce agreement between the simulated and observed abundance of TTL cirrus. With homogeneous freezing only and small-scale gravity waves included in the temperature curtains, the model produces excessive ice con...

The role of sulfur dioxide in stratospheric aerosol formation evaluated by using in situ measurements in the tropical lower stratosphere

Stratospheric aerosols (SAs) are a variable component of the Earths albedo that may be intentionally enhanced in the future to offset greenhouse gases (geoengineering). The role of tropospheric-sourced sulfur dioxide (SO2) in maintaining background SAs has been debated for decades without in-situ measurements of SO2 at the tropical tropopause to inform this issue. Here we clarify the role of SO2 in maintaining SAs by using new in-situ SO2 measurements to evaluate climate models and satellite retrievals. We then use the observed tropical tropopause SO2 mixing ratios to estimate the global flux of SO2 across the tropical tropopause. These analyses show that the tropopause background SO2 is about 5 times smaller than reported by the average satellite observations that have been used recently to test atmospheric models. This shifts the view of SO2 as a dominant source of SAs to a near-negligible one, possibly revealing a significant gap in the SA budget.

Efficient transport of tropospheric aerosol into the stratosphere via the Asian summer monsoon anticyclone

Significance Nonvolcanic stratospheric aerosols account for 20% of the radiative forcing of the entire atmospheric aerosol system since 1850. The Asian summer monsoon (ASM) effectively pumps Asian pollutants to the upper troposphere and lower stratosphere, leading to enhanced aerosol formation. Our in situ measurements combined with modeling work show that the aerosol formed within the ASM anticyclone is exported to the entire Northern Hemispheric stratosphere. On an annual average basis, we estimate that ∼15% of the Northern Hemisphere column stratospheric aerosol surface area originates from the Asian summer monsoon anticyclone region. This surface area is comparable to the modeled contribution from the sum of the small volcanic eruptions over the period 2000 to 2015. An enhanced aerosol layer near the tropopause over Asia during the June–September period of the Asian summer monsoon (ASM) was recently identified using satellite observations. Its sources and climate impact are presently not well-characterized. To improve understanding of this phenomenon, we made in situ aerosol measurements during summer 2015 from Kunming, China, then followed with a modeling study to assess the global significance. The in situ measurements revealed a robust enhancement in aerosol concentration that extended up to 2 km above the tropopause. A climate model simulation demonstrates that the abundant anthropogenic aerosol precursor emissions from Asia coupled with rapid vertical transport associated with monsoon convection leads to significant particle formation in the upper troposphere within the ASM anticyclone. These particles subsequently spread throughout the entire Northern Hemispheric (NH) lower stratosphere and contribute significantly (∼15%) to the NH stratospheric column aerosol surface area on an annual basis. This contribution is comparable to that from the sum of small volcanic eruptions in the period between 2000 and 2015. Although the ASM contribution is smaller than that from tropical upwelling (∼35%), we find that this region is about three times as efficient per unit area and time in populating the NH stratosphere with aerosol. With a substantial amount of organic and sulfur emissions in Asia, the ASM anticyclone serves as an efficient smokestack venting aerosols to the upper troposphere and lower stratosphere. As economic growth continues in Asia, the relative importance of Asian emissions to stratospheric aerosol is likely to increase.

Radiative Forcing from Anthropogenic Sulfur and Organic Emissions Reaching the Stratosphere

Stratospheric aerosols cool the Earth by scattering sunlight. Although sulfuric acid dominates the stratospheric aerosol, this study finds that organic material in the lowermost stratosphere contributes 30-40% of the non-volcanic stratospheric aerosol optical depth (sAOD). Simulations indicate that non-volcanic sAOD has increased 77% since 1850. Stratospheric aerosol accounts for 21% of the total direct aerosol radiative forcing (which is negative) and 12% of the total AOD increase from organics and sulfate. There is a larger stratospheric influence on radiative forcing (i.e. 21%) relative to AOD (i.e. 12%) because an increase of tropospheric black carbon warms the planet while stratospheric aerosols (including black carbon) cool the planet. Radiative forcing from non-volcanic stratospheric aerosol mass of anthropogenic origin, including organics, has not been widely considered as a significant influence on the climate system.

A High-Sensitivity Low-Cost Optical Particle Counter Design

We report the design of a small optical particle counter with high sensitivity and low construction cost for atmospheric aerosol measurements. Particle sensing is based on the detection of the forward scattering of laser light. The separation of the laser beam and scattered light is achieved with a novel yet simple optical system. A laboratory prototype system with a 405-nm laser and photomultiplier tube detector has successfully detected polystyrene latex particles as small as 125 nm in diameter with unit efficiency. Theoretical calculations suggest that a lower detectable size limit of 100 nm can be achieved with reduction of background scattered light. The new counter will be useful in a variety of ground-based as well as small balloon-borne applications such as vertical profiling and in situ measurement of particles from explosive volcanic eruptions. Copyright 2013 American Association for Aerosol Research

Persistent Water-Nitric Acid Condensate with Saturation Water Vapor Pressure Greater than That of Hexagonal Ice.

A laboratory chilled mirror hygrometer (CMH), exposed to an airstream containing water vapor (H2O) and nitric acid (HNO3), has been used to demonstrate the existence of a persistent water-nitric acid condensate that has a saturation H2O vapor pressure greater than that of hexagonal ice (Ih). The condensate was routinely formed on the mirror by removing HNO3 from the airstream following the formation of an initial condensate on the mirror that resembled nitric acid trihydrate (NAT). Typical conditions for the formation of the persistent condensate were a H2O mixing ratio greater than 18 ppm, pressure of 128 hPa, and mirror temperature between 202 and 216 K. In steady-state operation, a CMH maintains a condensate of constant optical diffusivity on a mirror through control of only the mirror temperature. Maintaining the persistent condensate on the mirror required that the mirror temperature be below the H2O saturation temperature with respect to Ih by as much as 3 K, corresponding to up to 63% H2O supersaturation with respect to Ih. The condensate was observed to persist in steady state for up to 16 h. Compositional analysis of the condensate confirmed the co-condensation of H2O and HNO3 and thereby strongly supports the conclusion that the Ih supersaturation is due to residual HNO3 in the condensate. Although the exact structure or stoichiometry of the condensate could not be determined, other known stable phases of HNO3 and H2O are excluded as possible condensates. This persistent condensate, if it also forms in the upper tropical troposphere, might explain some of the high Ih supersaturations in cirrus and contrails that have been reported in the tropical tropopause region.

Physical processes controlling the spatial distributions of relative humidity in the tropical tropopause layer over the Pacific

The vertical distribution of relative humidity with respect to ice (RHI) in the Boreal wintertime Tropical Tropopause Layer (TTL, ≃14-18 km) over the Pacific is examined with the extensive dataset of measurements from the NASA Airborne Tropical TRopopause EXperiment (ATTREX). Multiple deployments of the Global Hawk during ATTREX provided hundreds of vertical profiles spanning the longitudinal extent of the Pacific with accurate measurements of temperature, pressure, water vapor concentration, ozone concentration, and cloud properties. We also compare the measured RHI distributions with results from a transport and microphysical model driven by meteorological analysis fields. Notable features in the distribution of RHI versus temperature and longitude include (1) the common occurrence of RHI values near ice saturation over the western Pacific in the lower-middle TTL (temperatures greater than 195 K); (2) low RHI values in the lower TTL over the central and eastern Pacific; (3) common occurrence of RHI values following a constant mixing ratio in the middle-to-upper TTL (temperatures between about 190 and 200 K), particularly for samples with ozone greater than about 50-100 ppbv indicating mixtures of tropospheric and stratospheric air; (4) RHI values typically near ice saturation in the coldest airmasses sampled (temperatures less than about 190 K); and (5) common occurrence of RHI values near 100% across the TTL temperature range in air parcels with low ozone mixing ratio (O3 < 50 ppbv) indicative of recent uplift by deep convection. We suggest that the typically saturated air in the lower TTL over the western Pacific is likely driven by a combination of the frequent occurrence of deep convection and the predominance of radiative heating (rising motion) in this region. The low relative humidities in the central/eastern Pacific lower TTL result from the lack of convective influence, the predominance of subsidence, and the relatively warm temperatures in the region. The nearly-constant water vapor mixing ratios in the middle-to-upper TTL likely result from the combination of slow ascent (resulting in long residence times) and wave driven temperature variability on a range of time scales (resulting in most air parcels having experienced low temperature and dehydration). The numerical simulations generally reproduce the observed RHI distribution features and sensitivity tests further emphasize the strong sensitivities of TTL relative humidity to convective input and vertical motions.