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Anthony L. Stuart

University of Texas at Austin

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Journal of Chemical Crystallography | 1983

Structure of chlorotristrimethylphosphine cobalt(I), C9H27ClCoP3

Richard A. Jones; Anthony L. Stuart; Jerry L. Atwood; William E. Hunter

The crystal structure of CoCl(PMes3)3 has shown that the compound is not isostructural with its rhodium analogue. The title compound crystallizes in the cubic space groupPa3 (No. 205) whereas the analogous Rh compound belongs to the triclinic space groupP ¯1. The cobalt derivative exhibits unit cell constanta=15.490(7) Å andZ=8 forDc=1.15 g cm−3. Full-matrix least-squares refinement gave a finalR value of 0.055 for 283 observed reflections. The Co-Cl bond in the molecule lies along a crystallographic three-fold axis with a Co-Cl distance of 2.21(1) Å. The unique Co-P distance is 2.240(6) Å.

Journal of the American Chemical Society | 1984

Synthesis and structures of free and coordinated phosphaalkenes

Alan H. Cowley; Richard A. Jones; J. G. Lasch; Nicholas C. Norman; C. A. Stewart; Anthony L. Stuart; Jerry L. Atwood; William E. Hunter; Hongming Zhang

Journal of the American Chemical Society | 1983

Synthesis and structure of an .eta.2-phosphaalkene nickel complex

Alan H. Cowley; Richard A. Jones; C. A. Stewart; Anthony L. Stuart; Jerry L. Atwood; William E. Hunter; Hongming Zhang

Organometallics | 1983

Substitution reactions of di-tert-butylphosphido complexes of nickel(I). Crystal structures of Ni2[.mu.-(Me3C)2P]2(CO)2(PMe3) (Ni-Ni) and Ni2[.mu.-(Me3C)2P]2(CO)3 (Ni-Ni)

Richard A. Jones; Anthony L. Stuart; Jerry L. Atwood; William E. Hunter

Organometallics | 1982

Steric effects of phosphido ligands. Synthesis and crystal structures of bis(tert-butylphosphido)-bridged dinuclear metal-metal-bonded complexes of iron(II), cobalt(I, II) and nickel(I)

Richard A. Jones; Anthony L. Stuart; Jerry L. Atwood; William E. Hunter; Robin D. Rogers

Organometallics | 1983

Synthesis of di-tert-butylphosphido-bridged dimers of cobalt(I) containing cobalt-cobalt double bonds. Crystal structures of [Co{.mu.-(Me3C)2P}(CO)2]2 and [Co{.mu.-(Me3C)2P}(PMe3)L]2 (L = CO or N2)

Richard A. Jones; Anthony L. Stuart; Jerry L. Atwood; William E. Hunter

Organometallics | 1984

Heterobimetallic di-tert-butylphosphido-bridged complexes of chromium-nickel and chromium-rhodium. Synthesis and x-ray structures of (CO)4(PMe3)Cr[.mu.-(Me3C)2P]Ni(PMe3)Cl(Cr-Ni) and (CO)4(PMe3)Cr[.mu.-(Me3C)2P]Rh(PMe3)CO(Cr-Rh)

Richard A. Jones; J. G. Lasch; Nicholas C. Norman; Anthony L. Stuart; Thomas C. Wright; Bruce R. Whittlesey

Organometallics | 1984

Synthesis and ligand exchange reactions of heterobimetallic di-tert-butylphosphido-bridged complexes of chromium-cobalt, chromium-rhodium and iron-cobalt. X-ray crystal structures of (CO)5Cr(.mu.-tert-Bu2P)Rh(COD) (Cr-Rh) (COD = 1,5-cyclooctadiene), (CO)3(PMe3)Cr(.mu.-tert-Bu2P)(.mu.-CO)Co(PMe3)(CO) (Cr-Co), and (CO)3(PMe3)Fe(.mu.-tert-Bu2P)Co(CO)2(PMe3) (Fe-Co)

Don J. Chandler; Richard A. Jones; Anthony L. Stuart; Thomas C. Wright

Inorganic Syntheses, Volume 25 | 2007

Dinuclear Phosphido and Arsenido Derivatives of Molybdenum

Richard A. Jones; Stuart T. Schwab; Anthony L. Stuart; J. L. Petersen

Organometallics | 1984

Heterobimetallic Di-tert-butylphosphido-bridged complexes of Cr−Ni and Cr−Rh. Synthesis and X-ray structures of (CO)4(PMe3)Cr(u-t-Bu2P)Ni(PMe3)Cl(Cr−Ni) and (CO)4(PMe3)Cr(μ-t-Bu2P)Rh(PMe3)CO(Cr−Rh)

Richard A. Jones; J. G. Lasch; Nicholas C. Norman; Anthony L. Stuart; Thomas C. Wright; Bruce R. Whittlesey

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Richard A. Jones

University of Texas at Austin

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Jerry L. Atwood

University of Missouri

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William E. Hunter

University of Alabama

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J. G. Lasch

University of Texas at Austin

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Thomas C. Wright

University of Texas at Austin

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Nicholas C. Norman

University of Bristol

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Alan H. Cowley

University of Texas at Austin

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Bruce R. Whittlesey

University of Texas at Austin

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Hongming Zhang

University of Alabama

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Don J. Chandler

University of Texas at Austin

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