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Contributions to Mineralogy and Petrology | 1994

Geochemistry and argon thermochronology of the Variscan Sila Batholith, southern Italy: source rocks and magma evolution

Robert A. Ayuso; Antonia Messina; Benedetto De Vivo; Selma Russo; Laurel G. Woodruff; John F. Sutter; Harvey E. Belkin

The Sila batholith is the largest granitic massif in the Calabria-Peloritan Arc of southern Italy, consisting of syn to post-tectonic, calc-alkaline and metaluminous tonalite to granodiorite, and post-tectonic, peraluminous and strongly peraluminous, two-mica±cordierite±Al silicate granodiorite to leucomonzogranite. Mineral 40Ar/39Ar thermochronologic analyses document Variscan emplacement and cooling of the intrusives (293–289 Ma). SiO2 content in the granitic rocks ranges from ∼57 to 77 wt%; cumulate gabbro enclaves have SiO2 as low as 42%. Variations in absolute abundances and ratios involving Hf, Ta, Th, Rb, and the REE, among others, identify genetically linked groups of granitic rocks in the batholith: (1) syn-tectonic biotite±amphibole-bearing tonalites to granodiorites, (2) post-tectonic two-mica±Al-silicate-bearing granodiorites to leucomonzogranites, and (3) post-tectonic biotite±hornblende tonalites to granodiorites. Chondrite-normalized REE patterns display variable values of Ce/Yb (up to ∼300) and generally small negative Eu anomalies. Degree of REE fractionation depends on whether the intrusives are syn- or post-tectonic, and on their mineralogy. High and variable values of Rb/Y (0.40–4.5), Th/Sm (0.1–3.6), Th/Ta (0–70), Ba/Nb (1–150), and Ba/Ta (∼50–2100), as well as low values of Nb/U (∼2–28) and La/Th (∼1–10) are consistent with a predominant and heterogeneous crustal contribution to the batholith. Whole rock δ18O ranges from ∼+8.2 to +11.7‰; the mafic cumulate enclaves have the lowest δ18O values and the two-mica granites have the highest values. δ18O values for biotite±honblende tonalitic and granodioritic rocks (9.1 to 10.8‰) overlap the values of the mafic enclaves and two-mica granodiorites and leucogranites (10.7 to 11.7‰). The initial Pb isotopic range of the granitic rocks (206Pb/204Pb ∼18.17–18.45, 207Pb/204Pb ∼15.58–15.77, 208Pb/204Pb ∼38.20–38.76) also indicates the predominance of a crustal source. Although the granitic groups cannot be uniquely distinguished on the basis of their Pb isotope compositions most of the post-tectonic tonalites to granodiorites as well as two-mica granites are somewhat less radiogenic than the syn-tetonic tonalites and granodiorites. Only a few of the mafic enclaves overlap the Pb isotope field of the granitic rocks and are consistent with a cogenetic origin. The Sila batholith was generated by mixing of material derived from at least two sources, mantle-derived and crustal, during the closing stages of plate collision and post-collision. The batholith ultimately owes its origin to the evolution of earlier, more mafic parental magmas, and to complex intractions of the fractionating mafic magmas with the crust. Hybrid rocks produced by mixing evolved primarily by crystal fractionation although a simple fractionation model cannot link all the granitic rocks, or explain the entire spectrum of compositions within each group of granites. Petrographic and geochemical features characterizing the Sila batholith have direct counterparts in all other granitic massifs in the Calabrian-Peloritan Arc. This implies that magmatic events in the Calabrian-Peloritan Arc produced a similar spectrum of granitic compositions and resulted in a distinctive type of granite magmatism consisting of coeval, mixed, strongly peraluminous and metaluminous granitic magmas.


The Journal of Geology | 2000

A Lost Realm in the Internal Domains of the Betic‐Rif Orogen (Spain and Morocco): Evidence from Conglomerates and Consequences for Alpine Geodynamic Evolution

Agustín Martín-Algarra; Antonia Messina; Vincenzo Perrone; Selma Russo; Ali Maate; Manuel Martín-Martín

The Malaguide‐Ghomaride Complex is capped by Upper Oligocene–Aquitanian clastic deposits postdating early Alpine orogenesis but predating the main tectonic‐metamorphic evolution, end of nappe emplacement, unroofing, and exhumation of the metamorphic units of the Betic‐Rif Orogen. Two conglomerate intervals within these deposits are characterized by clasts of sedimentary, epimetamorphic, and mafic volcanic rocks derived from Malaguide‐Ghomaride units and by clasts of acidic magmatic and orthogneissic rocks of unknown provenance, here studied. Magmatic rocks originated from late‐Variscan two‐mica cordierite‐bearing granitoids and, subordinately, from aplitic dikes. Orthogneisses derive from similar plutonic rocks but are affected by an Alpine metamorphic overprint evolving from greenschist ( \documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \usepackage[OT2,OT1]{fontenc} \newcommand\cyr{ \renewcommand\rmdefault{wncyr} \renewcommand\sfdefault{wncyss} \renewcommand\encodingdefault{OT2} \normalfont \selectfont} \DeclareTextFontCommand{\textcyr}{\cyr} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} \landscape


Geological Society, London, Special Publications | 2006

‘Verrucano’ and ‘Pseudoverrucano’ in the Central-Western Mediterranean Alpine Chains: palaeogeographical evolution and geodynamic significance

Vincenzo Perrone; Agustín Martín-Algarra; Salvatore Critelli; F. A. Decandia; M. D’Errico; Antonio Estévez; A. Iannace; A. Lazzarotto; Manuel Martín-Martín; Ivan Martin-Rojas; S. Mazzoli; Antonia Messina; Giovanni Mongelli; S. Vitale; Mohamed Najib Zaghloul


Journal of Geochemical Exploration | 1991

Rock chemistry and fluid inclusion studies as exploration tools for ore deposits in the Sila batholith, southern Italy

B. De Vivo; Robert A. Ayuso; Harvey E. Belkin; Annamaria Lima; Antonia Messina; A. Viscardi

T=510^{\circ }


Geodinamica Acta | 2005

The Cambrian to Aquitanian geological record of the Longi-Taormina Unit (Calabria-Peloritani Arc, southern Italy): geodynamic implications

Roberta Somma; Antonia Messina; Vincenzo Perrone


Geochemistry-exploration Environment Analysis | 2015

Soil geochemical survey of abandoned mining sites in the Eastern-Central Peloritani Mountains, Sicily, Italy

Antonio Cosenza; Annamaria Lima; Robert A. Ayuso; Nora K. Foley; Stefano Albanese; Antonia Messina; B. De Vivo

\end{document} –530°C and \documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \usepackage[OT2,OT1]{fontenc} \newcommand\cyr{ \renewcommand\rmdefault{wncyr} \renewcommand\sfdefault{wncyss} \renewcommand\encodingdefault{OT2} \normalfont \selectfont} \DeclareTextFontCommand{\textcyr}{\cyr} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} \landscape


Bollettino Della Societa Geologica Italiana | 1991

Geological and petrochemical study of the Sila Massif plutonic rocks (northern Calabria, Italy)

Antonia Messina; Roberto Compagnoni; B. De Vivo; V. Perrone; Selma Russo; Mario Barbieri; B. A. Scott


Bollettino Della Societa Geologica Italiana | 2004

Peloritani continental crust composition (southern Italy); geological and petrochemical evidence

Antonia Messina; Roberta Somma; Elisa Macaione; Giovanna Carbone; Giuseppe Careri

P=5


Comptes Rendus Geoscience | 2005

Syn-orogenic extension in the Peloritani Alpine Thrust Belt (NE Sicily, Italy): Evidence from the Alì Unit

Roberta Somma; Antonia Messina; Stefano Mazzoli


Bollettino Della Societa Geologica Italiana | 1994

Il massiccio della Sila, settore settentrionale dell'arco Calabro-Peloritano

Antonia Messina; Selma Russo; Alessandro Borghi; Vincenzo Colonna; Roberto Compagnoni; Alfredo Caggianelli; Annamaria Fornelli; Giuseppe Piccarreta

\end{document} –6 kbar) to low‐temperature amphibolite facies ( \documentclass{aastex} \usepackage{amsbsy} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{bm} \usepackage{mathrsfs} \usepackage{pifont} \usepackage{stmaryrd} \usepackage{textcomp} \usepackage{portland,xspace} \usepackage{amsmath,amsxtra} \usepackage[OT2,OT1]{fontenc} \newcommand\cyr{ \renewcommand\rmdefault{wncyr} \renewcommand\sfdefault{wncyss} \renewcommand\encodingdefault{OT2} \normalfont \selectfont} \DeclareTextFontCommand{\textcyr}{\cyr} \pagestyle{empty} \DeclareMathSizes{10}{9}{7}{6} \begin{document} \landscape

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Annamaria Lima

University of Naples Federico II

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Robert A. Ayuso

United States Geological Survey

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Benedetto De Vivo

University of Naples Federico II

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Harvey E. Belkin

United States Geological Survey

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