Antony Blundell

Detecting atmospheric pollution in surface soils using magnetic measurements: a reappraisal using an England and Wales database.

Industrial activity such as burning of fossil fuels produces magnetically enhanced particulates. These particulates consist of coarse-grained multidomain and stable single domain magnetic minerals. Two threshold values of low field magnetic susceptibility (chi(LF)) and frequency dependent susceptibility percentage (chi(FD)%) discriminate ferrimagnetic minerals of these sizes and can act as a tracer of magnetic pollution. Application of the thresholds to a magnetic topsoil data set (n=5656 across England and Wales) revealed 637 samples potentially dominated by pollution particulates. The magnetic parameters of these samples display a negative correlation with distance to urban areas and positive correlations with metals associated with anthropogenic activity (Cu, Pb, and Zn). Results of experimentation with threshold values and modelling of magnetic anomalies suggest that regional factors such as geology and potential for pedogenic secondary magnetic enhancement should be considered when setting threshold values.

Testing peatland testate amoeba transfer functions: Appropriate methods for clustered training-sets

Transfer functions are widely used in palaeoecology to infer past environmental conditions from fossil remains of many groups of organisms. In contrast to traditional training-set design with one observation per site, some training-sets, including those for peatland testate amoeba-hydrology transfer functions, have a clustered structure with many observations from each site. Here we show that this clustered design causes standard performance statistics to be overly optimistic. Model performance when applied to independent data sets is considerably weaker than suggested by statistical cross-validation. We discuss the reasons for these problems and describe leave-one-site-out cross-validation and the cluster bootstrap as appropriate methods for clustered training-sets. Using these methods we show that the performance of most testate amoeba-hydrology transfer functions is worse than previously assumed and reconstructions are more uncertain.

Testing competing hypotheses for soil magnetic susceptibility using a new chemical kinetic model

A chemical kinetic model is presented for the formation and accumulation of secondary ferrimagnetic minerals (SFMs) in soil constructed using experimentally determined rate constants and validated against field data. The primary objective is to critically assess the significance of competing causal mechanisms and disputed environmental controls under temperate conditions. Four findings are important in relation to current application of soil magnetic susceptibility data. First, transformation of hydrous ferric oxide to magnetite should dominate SFM formation, controlled primarily by parent material ferrous silicate concentration and climate. Second, abiotic reactions should account for most of the SFM production; the most significant impact of high Fe2+ concentrations created by dissimilatory iron-reducing bacteria is enhanced export of iron from the soil in runoff. Third, the model predicts a correlation between hematite and magnetite concentrations, weakening field support for direct transformation of hydrous ferric oxide to maghemite. Fourth, magnetic susceptibility enhancement should increase strongly with weathering duration.

Dating the Glen Garry tephra : a widespread late-Holocene marker horizon in the peatlands of northern Britain

The distal Icelandic tephra known as the Glen Garry layer has been dated by AMS 14C at eight ombrotrophic peat bogs from northern England and Scotland. The geochemistry of all the tephra layers is consistent with there being only one Glen Garry tephra, rather than two or more from eruptions of the same volcanic source. At seven of the sites, all in Scotland, the tephra layer was bracketed by 1 cm contiguous samples below, at and above the horizon. At the one English site, Walton Moss, Cumbria, a suite of 16 AMS dates was applied to a 116 cm section of a peat core containing the tephra. The resulting dates were calibrated and wiggle-matched using the BCal and Bpeat programmes to give an estimated age for the Glen Garry tephra of 2176 cal. BP, with a 2σ range of 2210—1966 cal. BP. This 244 year range is an improvement on the 410 years calibrated date range for the date without the wiggle-match. This age estimate will allow future work on peat profiles and other sediments containing the tephra to use the date as a pinning-point in age/depth models and obviate the need for radiocarbon dating at this period.

Microform‐scale variations in peatland permeability and their ecohydrological implications

1. The acrotelm-catotelm model of peatland hydrological and biogeochemical processes posits that the permeability of raised bogs is largely homogenous laterally but varies strongly with depth through the soil profile; uppermost peat layers are highly permeable while deeper layers are, effectively, impermeable. 2. We measured down-core changes in peat permeability, plant macrofossil assemblages, dry bulk density and degree of humification beneath two types of characteristic peatland microform – ridges and hollows – at a raised bog in Wales. Six 1424 C dates were also collected for one hollow and an adjacent ridge. 3. Contrary to the acrotelm-catotelm model, we found that deeper peat can be as highly permeable as near-surface peat and that its permeability can vary by more than an order of magnitude between microforms over horizontal distances of 1-5 metres. 4. Our palaeo-ecological data paint a complicated picture of microform persistence. Some microforms can remain in the same position on a bog for millennia, growing vertically upwards as the bog grows. However, adjacent areas on the bog (< 10 m distant) show switches between microform type over time, indicating a lack of persistence. 5. Synthesis. We suggest that the acrotelm-catotelm model should be used cautiously; spatial variations in peatland permeability do not fit the simple patterns suggested by the model. To understand how peatlands as a whole function both hydrologically and ecologically it is necessary to understand how patterns of peat physical properties and peatland vegetation develop and persist.

An 8000-year multi-proxy peat-based palaeoclimate record from Newfoundland: evidence of coherent changes in bog surface wetness and ocean circulation

Energy carried by warm tropical water, transported via the Atlantic Meridional Overturning Circulation (AMOC), plays a vital role in regulating the climate of regions bordering the North Atlantic Ocean. Previous phases of elevated freshwater input to areas of North Atlantic Deep Water (NADW) production in the early to mid-Holocene have been linked with slow-downs in the AMOC and changes in regional climate. Newfoundland’s proximity in the North Atlantic region to the confluence of the Gulf Stream and the Labrador Current and to an area of NADW production in the Labrador Sea makes it an ideal testing ground to investigate the influence of past fluctuations in ocean circulation on terrestrial ecosystems. We use multi-proxy peat-based records from the east coast of Newfoundland to derive a proxy-climate signal for the past 8000 years, which we have compared with changes in ocean circulation. Prominent shifts towards near-surface bog water-table levels, reflecting cooler/wetter climatic conditions, are evident in the early mid-Holocene at c. 7830, 7500, 7220 and 6600 cal. BP with minor changes occurring at c. 6340 and 6110 cal. BP. These events are coherent with evidence of meltwater injections into the N. Atlantic and of reduced NADW production. More recent increases in bog surface wetness in the mid- to late Holocene at c. 4290 and c. 2610 cal. BP are also consistent with reported periods of reduced NADW production. Coherence between the bog-derived palaeoclimate record developed from Newfoundland and evidence of fluctuations in ocean current strength is apparent in the early mid-Holocene.