Arpita Adhikari

Studies on methylcellulose/pectin/montmorillonite nanocomposite films and their application possibilities.

Films based on methylcellulose (MC) and pectin (PEC) of different ratios were prepared. MC/PEC (90:10) (MP10) gave the best results in terms of mechanical properties. Sodium montmorillonite (MMT) (1, 3 and 5 wt%) was incorporated in the MP10 matrix. The resulting films were characterized by X-ray diffraction and transmission electron microscopy, and it was found that nanocomposites were intercalated in nature. Mechanical studies established that addition of 3 wt% MMT gave best results in terms of mechanical properties. However, thermo-gravimetric and dynamic mechanical analysis proved that decomposition and glass transition temperature increased with increasing MMT concentration from 1 to 5 wt%. It was also observed that moisture absorption and water vapor permeability studies gave best result in the case of 3 wt% MMT. Optical clarity of the nanocomposite films was not much affected with loading of MMT. In vitro drug release studies showed that MC/PEC/MMT based films can be used for controlled transdermal drug delivery applications.

Improving Rain Attenuation Estimation: Modelling of Effective Path Length Using Ku-Band Measurements at a Tropical Location

Rain attenuation is an important aspect of signal propagation above 10GHz frequency. The attenuation time series generation from point rain rate measurement is crucial due to unavailability of actual signal measurements. In this paper, a simple and realistic approach has been demonstrated for better estimation of rain attenuation using Ku-band signal propagation data and ground rain rate measurements at Kolkata, India. The ITU-R model of rain attenuation has been modifled by incorporating an efiective slant path model. The efiective slant path has been estimated and modelled in terms of a power-law relationship of rain rate data of 2007{2008. The methodology has been validated with the measured data of 2006. Comparison with ITU-R and SAM clearly demonstrates the improved predictability of the proposed model at the present tropical location.

Rain-Induced Scintillations and Attenuation of Ku-Band Satellite Signals at a Tropical Location

The phenomenon of scintillations in relation to rain attenuation of Ku-band satellite signals has been studied at a tropical location. The standard deviation (σ) of scintillations increases with attenuation up to a value in the range of 6-7 dB, beyond which σ decreases with attenuation. A technique is proposed to obtain some effective values of structure constant (C_n²) of refractive-index variation from the experimental observations of σ and rain rate (R). The value of C_n² also increases with attenuation up to values in the 6-7-dB range and decreases beyond that value. The eddies in turbulent raining medium grow with rain rate, and consequently with attenuation, causing an increase in the outer scale (L_O) of turbulence and thus increasing σ until L_O reaches the size of the first Fresnel zone. In a further development, the contribution of LO toward C_n² decreases, resulting in the decrease of fast fluctuations with rain attenuation.

Synthesis and characterization of graphene from waste dry cell battery for electronic applications

This study demonstrates the electronic applications of graphene synthesized from the graphite electrode of waste dry cell zinc–carbon batteries. Graphite powder [G (R)] is successfully recovered from the graphite electrode of waste batteries by acid treatment and used as starting material for synthesis of graphene oxide (GO) following Hummers method. Finally, reduced graphene oxide (RGO) was obtained from the chemical reduction of GO by hydrazine hydrate. RGO thus obtained was characterized by X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, UV-vis absorption spectroscopy, dynamic light scattering, energy dispersive X-ray spectra and transmission electron microscopy to get detailed information about the structure and morphology of the RGO. All the above characterization results confirmed the restoration of sp2 conjugation and removal of functional groups after the reduction of GO and also the sheet like morphology of RGO. The surface charge and stability of RGO in an aqueous medium are examined by measuring zeta potential. An electrochemical study demonstrated that, at different sweep rates, the current is the highest for RGO and lowest for GO and the current increases with an increasing sweep rate for all materials. The loop area of all the samples at the 100 mV s−1 sweep rate is the highest. The galvanostatic charging/discharging measurements have also been performed for both the GO and RGO samples at a current density of 1 mA g−1. Electro-conductivity measurement shows that RGO has higher conductivity than GO due to the restoration of the sp2 structure. The current voltage (I–V) characteristics show a non-linear behavior of GO and the ohmic nature of RGO.

Multi-technique observations on precipitation and other related phenomena during cyclone Aila at a tropical location

A severe cyclone, named Aila, passed over Kolkata on 25 May 2009. The strong convective activities manifested through rainfall during the cyclone were studied with multi-technique observations involving micro rain radar, disdrometer, rain gauges, and a Ku-band satellite signal receiving system. A number of features of precipitation, namely the presence of large rain drops, the large vertical extent of the precipitating layer, an unusual enhancement of cross-polar component, and strong scintillations of the co-polar component of the satellite signal due to strong turbulences associated with the cyclone, were observed. This study leads to a more comprehensive understanding of the precipitation associated with a cyclonic storm.

Cross-linked methyl cellulose/graphene oxide rate controlling membranes for in vitro and ex vivo permeation studies of diltiazem hydrochloride

Permeability characteristics of the anti-hypertensive drug, diltiazem hydrochloride, from uncross-linked and cross-linked methylcellulose (MC)/graphene oxide (GO) rate controlling membranes (RCMs) were investigated. The MC/GO membranes were cross-linked with different concentrations of glutaraldehyde (GLA) to examine the effect of cross-linking on the permeability characteristics. The ATR-FTIR spectra, along with solubility resistance, swelling studies, the molar mass between cross-links, and moisture absorption of cross-linked RCMs over the uncross-linked RCM confirmed the cross-linking between MC and GO. The cross sectional view of cross-linked and uncross-linked RCMs, as observed by SEM, showed that the porous and fibrillose structure of the uncross-linked RCM was disrupted after cross-linking. The cross-linked RCMs showed improved mechanical and thermal properties compared to the uncross-linked RCMs. In vitro and ex vivo drug release was found to depend on the concentration of the cross-linker, which suggests that drug delivery is controlled by the cross-link density of RCM.

An ex situ approach to fabricating nanosilica reinforced polyacrylamide grafted guar gum nanocomposites as an efficient biomaterial for transdermal drug delivery application

Recently transdermal drug delivery systems (TDDS) based on polymeric nanocomposites have been widely researched by polymer and biomedical scientists for the remedy of various diseases. Thus to develop an efficient patch, we have synthesized guar gum-g-polyacrylamide by free radical polymerization using potassium persulphate as an initiator. The transdermal membranes were fabricated via solution casting, by incorporating different wt% of nanosilica and diltiazem hydrochloride to the synthesized copolymer. The resulting copolymer and the nanocomposite membranes were characterized using solid state 13C nuclear magnetic resonance, Fourier transform infrared spectra, thermo-gravimetric analysis, electron microscopy and viscometry. A hydro-swelling study and surface contact angle measurement showed that the membrane containing 1 wt% nanosilica was the most hydrophobic. The in vitro drug release patterns of all the transdermal membranes showed that the nanocomposite containing 1 wt% nanosilica provides the best result with 8.58 and 24.76% drug release after 5 and 20 h, respectively. Furthermore, the nanocomposite formulation exhibited good cyto-compatibility and non-irritant behaviour, which are primary requirements for an efficient transdermal drug delivery system.

Prerain Scintillations of Ku-Band Satellite Signal in Relation to Cloud and Convective Parameters at a Tropical Location

In this letter, the tropospheric scintillations occurring just before rain commencement have been investigated. This letter indicates the association of the prerain scintillations with both the cloud thickness and the prevailing convection. The convective available potential energy has been considered as a parameter indicating the strength of the associated convection.

Pre-rain scintillation of Ku-band satellite signal at a tropical location

Tropospheric scintillation has relation with rain rate and signal attenuation. The present study indicates strong connection of the pre-rain scintillations with the turbulence associated with convective systems. The role of atmospheric structure constant in enhancing the scintillation effect is also observed.

Rain microphysical features as observed from ground based radar and disdrometer at a tropical location

Tropical region experiences a variety of rainfall types throughout the year. The rain can vary from stratiform to convective even within a single event. The rain parameters have been separately investigated for stratiform and convective cases. The rain phases have been classified into stratiform and convective on the basis of bright band signature in the rain rate profile of the micro rain radar. The rain drop size distributions exhibit discernible difference for stratiform and convective cases. The drop size distribution parameters consequently demonstrate distinguishable variations for the two types of rain.