B. S. Dwivedi

Soil physical quality as influenced by long-term application of fertilizers and manure under maize-wheat system.

Soil physical environment as affected by long-term fertilizer experiment application in a maize-wheat system on sandy loam soils of India was characterized and quantified using a unified soil physical quality index (S). Treatments were 100% and 150% of recommended nitrogen, phosphorus, and potassium (NPK); 100% NPK + farmyard manure; 100% NPK + sulfur; and control (no fertilizer or manure). Soil aggregation, bulk density, organic carbon in bulk soil (SOC) and aggregates, pore-size distribution, saturated hydraulic conductivity, field capacity moisture content, and plant-available water content were evaluated. Most of the effects were pronounced in 0- to 15-cm layer. Better aggregation was found with 100% NPK + farmyard manure, where macroaggregates were greater than 50% of total soil mass. Aggregation indices were positively and significantly correlated with SOC in 8- to 4-mm aggregates. Bulk density was significantly lower (1.51 Mg m−3) with manure, corresponding to maximum SOC content (6.8 g kg−1). The field capacity moisture content, plant-available water content, and saturated hydraulic conductivity were significantly higher in manure plots. Transmission and storage pores were more abundant in manure-treated plots. Effects of 150% NPK or 100% NPK + sulfur doses was better compared with 100% NPK, indicating that the recommended dose of NPK was suboptimal to maintain the desired soil physical health. Close associations of S with soil physical parameters was obtained, indicating potential of S in quantifying the modifications of soil physical environment through fertilizer and manure applications.

The impact of diversification of a rice–wheat cropping system on crop productivity and soil fertility

Field experiments were conducted at the Crop Research Centre of Govind Ballabh Pant University of Agriculture and Technology, Pantnagar during 1996/97 and 1997/98. Each experiment comprised 10 crop sequences: (a) wheat-rice, (b) chickpea-rice, (c) lentil-rice, (d) pea-rice, (e) wheat-mungbean green manure-rice, (f) wheat-Sesbania green manure-rice, (g) wheat-fodder-rice, (h) chickpea-fodder-rice, (i) lentil-fodder-rice and (j) pea-fodder-rice, in a randomized block design with four replications. The crop sequences were compared in terms of economic rice equivalent yield (REY), protein production, apparent nutrient balances and effect on soil fertility status. Amongst crop sequences involving two crops each year (200% cropping intensity), chickpea-rice gave highest REY and protein production. Of the sequences involving three crops each year (300% cropping intensity), chickpea-fodder rice and wheat-fodder-rice were superior to others. The P balances were positive for all sequences, whereas K balances were generally negative except for sequences involving green manure legumes. Green manuring with Sesbania or mungbean helped restore soil fertility, indicating the advantage of green manure for higher productivity and sustainability of rice-wheat system. Chickpea-rice and chickpea-fodder-rice appeared promising alternatives to rice-wheat crop sequence.

Wheat productivity and N use-efficiency as influenced by inclusion of cowpea as a grain legume in a rice-wheat system

In high productivity zones of the Indo–Gangetic Plain Region (IGPR) of India, the rice–wheat cropping system (RWCS) is exhibiting a decline in factor productivity, low N use-efficiency and deterioration in soil health. Inclusion of legumes in RWCS is advocated as one of the promising agro-techniques to sustain productivity. A field experiment was conducted during 1996/97 and 1997/98 on sandy loam (Typic Ustrochrept) soil of Modipuram, India (29°4′N, 77°46′E, 237 m above sea level) to explore the possibilities of inclusion of cowpea as a break crop in RWCS. The effect of rice or cowpea was measured on the yield, fertilizer N requirement and N use-efficiency in wheat, and also on the soil organic carbon and available N content. The yields of wheat following cowpea were significantly ( P

Distribution of fractions of zinc and their contribution towards availability and plant uptake of zinc under long-term maize (Zea mays L.)–wheat (Triticum aestivum L.) cropping on an Inceptisol

Intensive farming with high yielding cultivars, application of high analysis NPK fertilisers, and reduced use of organic manures caused a decrease in the availability of zinc (Zn) in Indian soils. We collected soil and plant samples from an ongoing long-term experiment at Indian Agricultural Research Institute, New Delhi, to study the distribution of different fractions of Zn in an Inceptisol and their contribution towards the Zn availability in soil and Zn uptake in maize-wheat crop rotation. The treatments used for the study were NPK, NPK + FYM, NPK + Zn, and control (no fertiliser or manure). The DTPA-Zn concentration in soil was higher where Zn had been applied and declined with an increase in soil depth. The distribution of different fractions of Zn under various treatments and depths was inconsistent, and varied in a cropping year. The average concentration of total Zn (mg/kg) was 183, 183, 171, and 211 in 0-0.15, 0.15-0.30, 0.30-0.45, and 0.45-0.60 m depth, respectively. Residual Zn was the dominant portion of total Zn at all soil depths. Grain and stover yield of maize ranged from 1.10 to 2.43 t/ha and 1.22 to 2.46 t/ha, respectively, under different treatments, whereas, the yield of wheat grain varied from 2.25 to 4.69 t/ha and that of wheat straw from 2.56 to 5.20 t/ha. Highest uptake of Zn by both the crops occurred in Zn-treated plots. Zinc associated with easily reducible manganese, carbonate and iron and aluminum oxides contributed directly towards DTPA-extractable Zn. Sorbed Zn (SORB-Zn) and Zn associated with organic matter (OM-Zn) contributed significantly towards Zn uptake by the 2 crops.

Changes in Fractions of Iron, Manganese, Copper, and Zinc in Soil under Continuous Cropping for More Than Three Decades

The effect of continuous cropping with maize and wheat on soil characteristics and various forms of micronutrient cations in an Incetisol over the years was studied in an ongoing long‐term experiment in New Delhi, India. The soil samples collected in the years of 1993, 1995, 1997, 1999, 2001, 2003, and 2004 were analyzed for different fractions of iron (Fe), manganese (Mn), copper (Cu), and zinc (Zn) by following a sequential extraction procedure. The pH, electrical conductivity (EC), and calcium carbonate (CaCO3) content of the soil varied from 8.28 to 8.53, 0.40 to 0.43 dSm−1, and 0.92 to 1.05%, respectively. Organic carbon content ranged from 0.38 in the control to 0.67% in 100% NPK + farmyard manure (FYM). Diethylenetriaminepentaacetic acid (DTPA)–extractable Fe and Mn (but not Zn and Cu) in soil declined from their respective initial (1971) values as a result of intensive cropping for more than three decades. It also resulted in a decrease in the concentrations of all the four metallic cations bound to organic matter, in addition to Fe and Zn, associated with carbonates in all the treatments in surface soil.

Soil boron status: impact of lime and fertilizers in an Indian long-term field experiment on a Typic Paleustalf

In Indian agriculture, nitrogen (N) and phosphorus (P) fertilizers are predominantly used by the farmers, often ignoring secondary and micronutrients. Significance of boron (B) in nutrient management studies has been increasingly underlined under intensive cropping systems particularly in acid soils. In order to understand the distribution of soil native B in different fractions and their contribution to plant B uptake as influenced by nutrient management, soil samples collected after wheat (2009–2010) from a long-term experiment (LTE) continuing since 1972–1973 on Typic Paleustalf of Ranchi were subjected to sequential fractionation of soil B. Treatments included N alone, NP, NPK, 150% of recommended NPK, NPK + farmyard manure (FYM), NPK + lime, and an unfertilized-control. Five soil B fractions were determined along with hot CaCl2-extractable (available) B. Averaged across the treatments, the soil had low organic carbon (C), pH and cation exchange capacity (CEC), and high free sesquioxides. Total B content was 21.7 mg kg−1. Among different B fractions, residual B was the major contributor to total B and other fractions collectively shared 7% of total B only. Application of N alone depleted readily soluble, specifically adsorbed and organically bound B bringing the contents even below unfertilized-control. Conjoint use of lime or FYM with NPK increased significantly these fractions, whereas a decrease in oxide bound B was noticed under these treatments. Available B was positively correlated with these fractions indicating their significance in controlling B availability in the soil. The study revealed that use of lime or FYM helped modifying the distribution of soil B in different fractions by way of changing soil pH and organic C content, resulting in enrichment of plant available pool. A drastically low available B content in different treatments receiving fertilizers alone, however, suggested the necessity of B fertilization at prescribed rates for maintaining soil B fertility as also high crop yields.

Zincated Nanoclay Polymer Composites (ZNCPCs): Synthesis, Characterization, Biodegradation and Controlled Release Behaviour in Soil

ABSTRACT Novel zincated nanoclay polymer composites (ZNCPCs) with variable percentage of commercial bentonite and nanobentonite (8%, 10% and 12% of monomer for each case) were synthesized. Polyacrylic acid-Polyacrylamide copolymer was synthesized using N, N-Methylene bisacrylamide as crosslinker and ammonium persulfate as initiator. Clays as well as ZNCPCs were characterized by XRD, SEM, TEM and FTIR. 12% nanoclay containing formulation showed slowest release rate. ZNCPCs containing 8% clay recorded highest Zn content as well as highest equilibrium water absorbency. Biodegradation study revealed that Aspergillus spp was more effective as compared with Trichoderma spp in degradation of ZNCPCs. GRAPHICAL ABSTRACT

Long-term effects of fertilisers and organic sources on soil organic carbon fractions under a rice–wheat system in the Indo-Gangetic Plains of north-west India

Decline in soil organic carbon (SOC) content is considered a key constraint for sustenance of rice–wheat system (RWS) productivity in the Indo-Gangetic Plain region. We, therefore, studied the effects of fertilisers and manures on SOC pools, and their relationships with crop yields after 18 years of continuous RWS. Total organic C increased significantly with the integrated use of fertilisers and organic sources (from 13 to 16.03gkg–1) compared with unfertilised control (11.5gkg–1) or sole fertiliser (NPKZn; 12.17gkg–1) treatment at 0–7.5cm soil depth. Averaged across soil depths, labile fractions like microbial biomass C (MBC) and permanganate-oxidisable C (PmOC) were generally higher in treatments that received farmyard manure (FYM), sulfitation pressmud (SPM) or green gram residue (GR) along with NPK fertiliser, ranging from 192 to 276mgkg–1 and from 0.60 to 0.75gkg–1 respectively compared with NPKZn and NPK+cereal residue (CR) treatments, in which MBC and PmOC ranged from 118 to 170mgkg–1 and from 0.43 to 0.57gkg–1 respectively. Oxidisable organic C fractions revealed that very labile C and labile C fractions were much larger in the NPK+FYM or NPK+GR+FYM treatments, whereas the less-labile C and non-labile C fractions were larger under control and NPK+CR treatments. On average, Walkley–Black C, PmOC and MBC contributed 29–46%, 4.7–6.6% and 1.16–2.40% towards TOC respectively. Integrated plant nutrient supply options, except NPK+CR, also produced sustainable high yields of RWS.

Fractions of Copper in Soil under a Long-Term Experiment and Their Contribution to Copper Availability and Uptake by Maize―Wheat Cropping Sequence

ABSTRACT Soil and plant samples were collected from on-going long-term experiment at Indian Agricultural Research Institute, New Delhi farm to study the distribution of various forms of copper (Cu) and their contribution to availability and plant uptake in maize (Zea mays L.)—wheat (Triticum aestivum L.) sequence. The optimum dose-based treatments selected for the study were nitrogen-phosphorus-potassium (NPK), NPK + Farmyard manure (FYM), NPK+ zinc (Zn) and control (no fertilizer or manure). Uptake of Cu by maize and wheat varied from 17.0 to 37.5 and 60.8 to 149.3 g ha−1, respectively, under different treatments. Copper uptake by wheat was significantly higher under 100% NPK + FYM than that with 100% NPK. There was no significant difference among the treatments with respect to diethylenetriaminepentaacetic acid (DTPA)-extractable Cu in 0–15, 15–30, 30–45, and 45–60 cm soil layers. However, with increasing depth of soil, it showed declining trend under all the treatments. Mean value of total Cu was 28, 32, 25, and 21 mg kg−1 in 0–15, 15–30, 30–45, and 45–60 cm depths, respectively. Major part of the total Cu was present as residual form. Sorbed copper (SORB–Cu) contributed directly towards its availability both in pre-sowing maize and post-harvest wheat soil samples. SORB–Cu and organic matter bound Cu (OM–Cu) contributed directly towards the uptake by the component crops. Copper associated with easily reducible manganese, carbonate, and iron and aluminum oxides were most recalcitrant forms present in soil and their effects on availability and crop uptake were adverse.

Depth dynamics of soil N contents and natural abundances of 15N after 43 years of long-term fertilization and liming in sub-tropical Alfisol

ABSTRACT The aim of this study was to understand impacts of long-term (43 years) fertilization on soil aggregation, N accumulation rates and δ15N in surface and deep layers in an Alfisol. Soil samples from seven treatments were analysed for N stocks, aggregate-associated N in 0–30 cm and the changes in δ15N in 0–90 cm depths. The treatments were: unfertilized control (control); recommended N dose (N); recommended N and phosphorus doses (NP); recommended N, P and potassium doses (NPK); 150% of recommended N, P and K doses (150% NPK); NPK + 10 Mg FYM ha−1 (NPK + FYM) and NPK + 0.4 Mg lime ha−1 (NPK + L). Results revealed that plots under NPK + FYM had ~39% higher total N concentrations than NPK + L in 0–30 cm soil layers. In NPK + L, macro-aggregates had 35 and 11% and microaggregates had 20 and 9% lower δ15N values than NPK + FYM in 0–15 and 15–30 cm soil layers, respectively. However, plots receiving NPK + FYM had ~39% greater deep soil (30–90 cm) N accumulation than NPK + L. These results would help understanding N supplying capacity by long-term fertilization and assist devising N management strategies in sub-tropical acidic Alfisols.