B Waliszewska

Biological diversity of Salix taxa in Cu, Pb and Zn phytoextraction from soil

ABSTRACT The aim of the study was to estimate the efficiency of copper (Cu), lead (Pb) and zinc (Zn) phytoextraction by 145 Salix taxa cultivated in an area affected by industrial activity. Survivability and biomass of plants were also analyzed. The highest Cu, Pb and Zn content in shoots was 33.38 ± 2.91 (S. purpurea × viminalis 8), 24.64 ± 1.97 (S. fragilis 1) and 58.99 ± 4.30 (S. eriocephala 7) mg kg−1 dry weight, respectively. In the case of unwashed leaves, the highest content of these metals was 135.06 ± 8.14 (S. purpurea 26), 67.98 ± 5.27 (S. purpurea 45) and 142.56 ± 12.69 (S. alba × triandra 2) mg kg−1 dw, while in washed leaves it was 106.02 ± 11.12 (S. purpurea 45), 55.06 ± 5.75 (S. purpurea 45) and 122.87 ± 12.33 (S. alba × triandra 2) mg kg−1 dw, respectively. The differences between the highest and lowest values for Cu, Pb and Zn were 545%, 20500% and 535% in shoots; 2692%, 2560% and 7500% in unwashed leaves; and 3286%, 2221% and 6950% in washed leaves, respectively. S. acutifolia was able to effectively accumulate all three metals jointly, producing shoots that were well developed in both length and diameter when compared with the other tested willows—an ability that would suggest its high suitability for practical application.

Treatment of dairy waste by anaerobic co-digestion with sewage sludge

Abstract The results of anaerobic digestion (AD) of buttermilk (BM) and cheese whey (CW) with a digested sewage sludge as inoculum is described. The substrate/inoculum mixtures were prepared using 10% buttermilk and 15% cheese whey. The essential parameters of the materials were described, including: total solids (TS), volatile solids (VS), pH, conductivity, C/N ratio (the quantitative ratio of organic carbon (C) to nitrogen (N)), alkalinity, chemical oxygen demand (COD). The potential directions of biodegradation of the organic waste types, as used in this study, are also presented. Appropriate chemical reactions illustrate the substrates and products in each phase of anaerobic decomposition of the compounds that are present in buttermilk and cheese whey: lactic acid, lactose, fat, and casein. Moreover, the biogas and biomethane production rates are compared for the substrates used in the experiment. The results have shown that buttermilk in AD generates more biogas (743 m3/Mg VS), including methane (527 m3/Mg VS), when compared with cheese whey (600 m3/Mg VS, 338 m3/Mg VS for biogas and methane, respectively).

Characteristics of Thermophysical Parameters of Selected Salix Taxa with Elemental Analysis

In an experiment conducted in the spring of 2011, 3600 cuttings of 145 Salix taxa were cultivated, which were subsequently harvested after 1 year and analyzed for thermophysical and chemical properties. Statistical analysis followed by grouping of the objects enabled us to find significant differences between the Salix genotypes. Two different groups (of 35 and 110 varieties each) were found with average values of higher heating value of 19.75 and 19.27 MJ kg−1 d.w., respectively, while in terms of lower heating value three groups were identified (consisting of 39, 102, and 4 taxa), represented by average values of 18.27, 17.06, and 16.52 MJ kg−1 d.w., respectively. In our opinion, moisture content of fresh material (three groups with average moisture contents of 9.14%, 7.29%, and 4.47% d.w., respectively) is the main indicator distinguishing the above findings. The tested varieties were also divided into three groups according to their volatile matter contents (14, 121, and 10 genotypes with average values of 76.47%, 74.80%, and 72.97% d.w., respectively) as well as fixed carbon content (with 21.3%, 20.23%, and 19.08% d.w., respectively, for groups of 23, 110, and 12 taxa). Also three groups of varieties (11, 121, and 13 taxa) were distinguished in terms of the level of ash (4.16%, 2.77%, and 1.84% d.w., respectively). Differences in the elemental levels of C, H, and S in tested Salix taxa were found as well.

Transformation of Miscanthus and Sorghum cellulose during methane fermentation

The purpose of the paper is designation of the changes in the structure of cellulose after the methane fermentation process of Miscanthus and Sorghum harvested during the growing season and afterwards. The percentage and structure of cellulose before and after fermentation were studied. Investigations into changes of the cellulose structure were conducted by the SEC, FT-IR and XRD methods. The average percentage of cellulose after the growing season for Miscanthus varieties was higher and for Sorghum varieties was lower. As a result of the fermentation, the percentage of cellulose for both investigated species harvested in two growth seasons was lower. The degree of polymerisation for the plants harvested after the growing season was lower for the most feedstock. As a result of the fermentation process, the degree of polymerization increased for each of the investigated feedstock. However, crystallinity of cellulose remained at the same level for Miscanthus and decreased for Sorghum. It was shown that changes were different in the cellulose structure of the compared species.