Bediha Beser

Experimental investigation of the Rb-85(2) a (3)Sigma(+)(u) triplet ground state: Multiparameter Morse long range potential analysis

Using perturbation facilitated infrared-infrared double resonance excitation of the (85)Rb(2) molecule, we have observed spectrally resolved fluorescence to the a (3)Sigma(u)(+) state. We have analyzed the rovibrational energy level structure of the (85)Rb(2) a (3)Sigma(u)(+) state and derived a multiparameter Morse Long Range (MLR) potential and molecular constants for this state, which can be used to predict term values without needing to solve the radial Schrödinger equation.

Electronic transition dipole moment and radiative lifetime calculations of sodium dimer ion-pair states

We report here ab initio calculated electronic transition dipole moments for the sodium dimer ion pair states of (1)Σg (+) symmetry. They vary strongly as a function of internuclear distance because of the effect of the Na(+) + Na(-) ion pair potential, which also causes the formation of additional wells and shoulders in the molecular potential energy curves. We also present a computational study of the transition dipole moment matrix elements and lifetimes for these ion-pair states.

Global analysis of data on the spin-orbit-coupled A {sup 1{Sigma}}{sub u}{sup +} and b {sup 3{Pi}}{sub u} states of Cs{sub 2}

We present experimentally derived potential curves and spin-orbit interaction functions for the strongly perturbed A {sup 1{Sigma}}{sub u}{sup +} and b {sup 3{Pi}}{sub u} states of the cesium dimer. The results are based on data from several sources. Laser-induced fluorescence Fourier transform spectroscopy (LIF FTS) was used some time ago in the Laboratoire Aime Cotton primarily to study the X {sup 1{Sigma}}{sub g}{sup +} state. More recent work at Tsinghua University provides information from moderate resolution spectroscopy on the lowest levels of the b {sup 3{Pi}}{sub 0u}{sup {+-}} state as well as additional high-resolution data. From Innsbruck University, we have precision data obtained with cold Cs{sub 2} molecules. Recent data from Temple University was obtained using the optical-optical double resonance polarization spectroscopy technique, and finally, a group at the University of Latvia has added additional LIF FTS data. In the Hamiltonian matrix, we have used analytic potentials (the expanded Morse oscillator form) with both finite-difference (FD) coupled-channel and discrete variable representation (DVR) calculations of the term values. Fitted diagonal and off-diagonal spin-orbit functions are obtained and compared with ab initio results from Temple and Moscow State universities.