Benjamin Wade

Evidence for Early Mesoproterozoic Arc Magmatism in the Musgrave Block, Central Australia: Implications for Proterozoic Crustal Growth and Tectonic Reconstructions of Australia

The Musgrave Block in central southern Australia separates the dominantly Paleoproterozoic North Australian Craton from the Late Archean to early Mesoproterozoic Gawler Craton in southern Australia. Geochemical and Nd isotopic data from ∼1.59–1.55‐Ga felsic rocks in the Mann Ranges suggest that the early history of the Musgrave Block was linked to the development of subduction along the northern margin of the Gawler Craton. Characteristic geochemical patterns of these felsic rocks include negative anomalies in Nb, Ti, and Y and are accompanied by steep light rare earth element patterns and comparatively juvenile Nd isotopic compositions (ϵNd(1550) values from −1.2 to 0.9). The geochemical and isotopic signatures of these early Mesoproterozoic felsic rocks have similarities with island arc systems involving residual Ti‐bearing minerals and garnet. We propose that the 1.59–1.55‐Ga arclike rocks in the Musgrave Block indicate the presence of an active margin between the North Australian Craton and the South Australian Craton, with subsequent suturing of the Australian continent during the early Mesoproterozoic. The existence of arclike magmatism in the Musgrave Block during the early Mesoproterozoic suggests a period of major crustal growth in the Australian Proterozoic that has important implications for current Proterozoic reconstructions of Australia and Australias fit within the supercontinent Rodinia.

Temporal constraints on the timing of high-grade metamorphism in the northern Gawler Craton: implications for assembly of the Australian Proterozoic

LA-ICPMS U–Pb data from metamorphic monazite in upper amphibolite and granulite-grade metasedimentary rocks indicate that the Nawa Domain of the northern Gawler Craton in southern Australia underwent multiple high-grade metamorphic events in the Late Paleoproterozoic and Early Mesoproterozoic. Five of the six samples investigated here record metamorphic monazite growth during the period 1730–1690 Ma, coincident with the Kimban Orogeny, which shaped the crustal architecture of the southeastern Gawler Craton. Combined with existing detrital zircon U–Pb data, the metamorphic monazite ages constrain deposition of the northern Gawler metasedimentary protoliths to the interval ca 1750–1720 Ma. The new age data highlight the craton-wide nature of the 1730–1690 Ma Kimban Orogeny in the Gawler Craton. In the Mabel Creek Ridge region of the Nawa Domain, rocks metamorphosed during the Kimban Orogeny were reworked during the Kararan Orogeny (1570–1555 Ma). The obtained Kararan Orogeny monazite ages are within uncertainty of ca 1590–1575 Ma zircon U–Pb metamorphic ages from the Mt Woods Domain in the central-eastern Gawler Craton, which indicate that high-grade metamorphism and associated deformation were coeval with the craton-scale Hiltaba magmatic event. The timing of this deformation, and the implied compressional vector, is similar to the latter stages of the Olarian Orogeny in the adjacent Curnamona Province and appears to be part of a westward migration in the timing of deformation and metamorphism in the southern Australian Proterozoic over the interval 1600–1545 Ma. This pattern of westward-shifting tectonism is defined by the Olarian Orogeny (1600–1585 Ma, Curnamona Province), Mt Woods deformation (1590–1575 Ma), Mabel Creek Ridge deformation (1570–1555 Ma, Kararan Orogeny) and Fowler Domain deformation (1555–1545 Ma, Kararan Orogeny). This westward migration of deformation suggests the existence of a large evolving tectonic system that encompassed the emplacement of the voluminous Hiltaba Suite and associated volcanic and mineral systems.

Gold-telluride nanoparticles revealed in arsenic-free pyrite

Abstract Pyrite, the most abundant sulfide on Earth and a common component of gold deposits, can be a significant host for refractory gold. This is the first documentation of pore-attached, composite Autelluride nanoparticles in “arsenic-free” pyrite. Trace elements mapping in pyrite from an intrusionhosted Au deposit with orogenic overprint (Dongping, China) shows trails of tellurides overlapping Co-Ni-zonation. Intragranular microfracturing, anomalous anisotropy, and high porosity are all features consistent with devolatilization attributable to the orogenic event. The pyrite-hosted nanoparticles are likely the “frozen,” solid expression of Te-rich, Au-Ag-Pb-bearing vapors discharged at this stage. Nanoparticle formation, as presented here, provides the “smallest-scale” tool to fingerprint Au-trapping during crustal metamorphism

Nd isotopic and geochemical constraints on provenance of sedimentary rocks in the eastern Officer Basin, Australia: implications for the duration of the intracratonic Petermann Orogeny

Sm–Nd isotopic and geochemical data from Neoproterozoic to Cambrian sedimentary rocks in the intracratonic eastern Officer Basin in central Australia highlight the evolving provenance roles of the basement complexes that underlie and bound the basin. Initial εNd values of around −12 for the basal units indicate that both were largely derived from the late Archaean to Mesoproterozoic Gawler Craton, which bounds the basin to the south. At c. 720 Ma an influx of juvenile, glacially derived sediment indicates partial uplift of the Mesoproterozoic Musgrave Block along the basins northern margin, in a regime interpreted to be broadly extensional. At around 600 Ma, synchronous with the development of a foreland architecture, there was a large influx of Musgrave Block-derived sediments. This is interpreted to mark the onset of the intracratonic Petermann Orogeny, which was a long-lived event or series of events, spanning more than 70 Ma. Subsequent to c. 600 Ma, the Nd isotopic composition of sequences within the Officer Basin indicates an increasing contribution from the Gawler Craton despite up to 45 km of denudation of part of the Musgrave Block. This suggests that the majority of sediment derived from the Petermann Orogen bypassed the eastern Officer Basin for much of the history of the Petermann Orogeny.

Trace and minor elements in galena: a reconnaissance LA-ICP-MS study

Abstract Minor and trace elements can substitute into the crystal lattice of galena at various concentrations. In situ LA-ICP-MS analysis and trace element mapping of a range of galena specimens from different deposit types are used to obtain minor/trace element data, aimed at achieving insight into factors that control minor/trace element partitioning. The previously recognized coupled substitution Ag++(Bi,Sb)3+↔ 2Pb2+ is confirmed. However, the poorer correlation between Ag and (Bi+Sb) when the latter elements are present at high concentrations (~>2000 ppm), suggests that site vacancies may come into play: [2(Bi,Sb)3++o ↔ 3Pb2+]. Galena is the primary host of Tl in all mapped mineral assemblages. Along with Cu, Tl is likely incorporated into galena via the coupled substitution: (Ag,Cu,Tl)++(Bi,Sb)3+↔ 2Pb2+. Tin can reach significant concentrations in galena (>500 ppm). Cd and minor Hg can be incorporated into galena; the simple isovalent substitution (Cd,Hg)2+↔ Pb2+ is inferred. This paper shows for the first time, oscillatory and sector compositional zoning of minor/trace elements (Ag, Sb, Bi, Se, Te, Tl) in galena from two epithermal ores. Zoning is attributed to slow crystal growth into open spaces within the vein at relatively low temperatures. The present data show that galena can host a broader range of elements than previously recognized. For many measured elements, the data sets generated display predictable partitioning patterns between galena and coexisting minerals, which may be dependent on temperature or other factors. Trace element concentrations in galena and their grain-scale distributions may also have potential in the identification of spatial and/or temporal trends within individual metallogenic belts, and as markers of ore formation processes in deposits that have undergone superimposed metamorphism and deformation. Galena trace element geochemistry may also display potential to be used as a trace/minor element vector approach in mineral exploration, notably for recognition of proximal-to-distal trends within a given ore system.

Evidence for 930 Ma metamorphism in the Shetland Islands, Scottish Caledonides: Implications for Neoproterozoic tectonics in the Laurentia-Baltica sector of Rodinia

Abstract: Zircon and monazite laser-ablation inductively coupled plasma mass spectrometry U–Pb geochronological data for two metasediment samples from the Westing Group, northern Shetland Islands, Scottish Caledonides yield ages between 938 ± 8 and 925 ± 10 Ma (Tonian) for upper amphibolites-facies metamorphism. Texturally early metamorphism is recorded by a migmatitic garnet + sillimanite + plagioclase + muscovite + biotite assemblage, which formed at c. 650–700 °C and 7 kbar. Subsequent reworking resulted in the growth of a secondary garnet + kyanite + plagioclase + muscovite + biotite assemblage at c. 650 °C and 8–9 kbar. In situ electron probe microanalysis (EPMA) U–Th–Pb chemical dating of monazite hosted within garnet grains and the matrix of one sample also give Tonian ages, apparently indicating that all the metamorphism occurred during the Neoproterozoic. However, the dominant structural fabrics appear to have formed during the Ordovician–Silurian Caledonian orogeny, suggesting that the reworking was substantially younger despite the apparent absence of Caledonian monazite or zircon ages. Detrital zircons are consistent with Laurentia–Baltica provenance. Deposition of the Westing Group is constrained to between c. 1030 and 930 Ma. The timing of Tonian metamorphism suggests possible correlations with sequences elsewhere in the northern Caledonides, including the Krummedal Succession of East Greenland and Laurentian-derived successions in Svalbard and northern Norway. Supplementary material: U–Pb LA-ICPMS and EPMA data are available at http://www.geolsoc.org/SUP18379.

Origin of metasedimentary and igneous rocks from the Entia Dome, eastern Arunta region, central Australia: a U-Pb LA-ICPMS SHRIMP and Sm-Nd isotope study

Analysis of detrital zircon from previously geochronologically unconstrained metasedimentary rocks in the eastern Arunta region, using U – Pb LA-ICPMS and SHRIMP, provides ages reconcilable with Australian sources. Maximum depositional ages of the analysed samples fall into two groups, three samples having maximum depositional ages of ca 1780–1760 Ma and two at ca 2510–2490 Ma. Metamorphic monazite from two pelitic rocks provides bimodal age populations of 1773 ± 9 Ma and 325 ± 8 Ma from one sample, and 1719 ± 9 Ma and 341 ± 5 Ma from the second. The age of 1773 ± 9 Ma is the first direct evidence of monazite growth in the interval ca 1780–1770 Ma, and is attributed to high-grade contact metamorphism associated with the proximal emplacement of granodioritic bodies previously thought to be subduction-related. The metamorphic age of 1719 ± 9 Ma is attributed to the Strangways Orogeny (1730–1710 Ma). The Carboniferous ages of 325 ± 8 Ma and 341 ± 5 Ma in both samples are attributed to partial resetting and new growth of monazite during the Alice Springs Orogeny (ca 400–300 Ma). Sm – Nd isotope systematics of the metasedimentary rocks display a large variation ranging from ϵ Nd(1760) = – 1.4 to – 8.8 and, when coupled with the detrital-zircon age populations, allow for a locally derived (North Australian Craton) source for the metasedimentary rocks. Analysis of igneous zircon from a felsic layer of the Entia Gneiss Complex intimately interlayered with the metasedimentary rocks yielded a 207Pb/206Pb weighted average age of 1771 ± 10 Ma, interpreted as the crystallisation age of the igneous precursor. This age is indistinguishable within error from that of the granodioritic intrusions (Inkamulla Granodiorite 1773 ± 4 Ma), here thought to be responsible for the high-grade metamorphism in the metasedimentary rocks. Given that the granodioritic bodies have previously been characterised as subduction-related intrusions, the approximately coincident ages of metamorphism, deposition of at least some of the metasedimentary rocks, and the intrusion of voluminous felsic and mafic magmas, suggests that the deposition and metamorphism of the precursor to the metasedimentary rocks may be related to active subduction along the southern margin of the Arunta region.

Petrogenesis of ca 1.50 Ga granitic gneiss of the Coompana Block: filling the 'magmatic gap' of Mesoproterozoic Australia

The Coompana Block is an essentially unknown basement province that separates the Gawler Craton of South Australia from the Yilgarn Craton of Western Australia. Previously unstudied granitic gneiss intersected by deep drilling in the Coompana Block represents an important period of within-plate magmatism during a time of relative magmatic quiescence in the Australian Proterozoic. Granitic gneiss intersected at ∼1500 m depth in Mallabie 1 diamond drillhole is metaluminous and dominantly granodioritic in composition. The granodiorites have distinctive A-type chemistry characterised by high contents of Zr, Nb, Y, Ga, LREE with low Mg#, Sr, CaO and HREE. U – Pb LA-ICPMS dating of magmatic zircons provides an age of 1505 ± 7 Ma, interpreted as the crystallisation age of the granite protolith. ϵ Nd values are high with respect to exposed crust of the Musgrave Province and Gawler Craton, and range from +1.2 to +3.3 at 1.5 Ga. The granitic gneiss is interpreted to be a fractionated melt of a mantle-derived parental melt. The tectonic environment into which the precursor granite was emplaced is not clear. One possibility is emplacement within an extensional environment. Regardless, the granitic gneiss intersected in Mallabie 1 represents magmatic activity during the ‘Australian Mesoproterozoic magmatic gap’ of ca 1.50 – 1.35 Ga, and is a possible source for ca 1.50 detrital zircons found in sedimentary rocks of Tasmania and Antarctica, and metasedimentary rocks of the eastern Musgrave Province.

Early Mesoproterozoic metamorphism in the Barossa Complex, South Australia: links with the eastern margin of Proterozoic Australia

LA-ICP-MS U–Pb geochronological data from metamorphic monazite in granulite-facies metapelites in the Barossa Complex, southern Australia, yield ages in the range 1580–1550 Ma. Metapelitic rocks from the Myponga and Houghton Inliers contain early biotite–sillimanite-bearing assemblages that underwent partial melting to produce peak metamorphic garnet–sillimanite-bearing anatectic assemblages. Phase equilibrium modelling suggests a clockwise P–T evolution with peak temperatures between 800 and 870°C and peak pressures of 8–9 kbar, followed by decompression to pressures of ∼6 kbar. In combination with existing age data, the monazite U–Pb ages indicate that the early Mesoproterozoic evolution of the Barossa Complex is contemporaneous with other high geothermal gradient metamorphic terranes in eastern Proterozoic Australia. The areal extent of early Mesoproterozoic metamorphism in eastern Australia suggests that any proposed continental reconstructions involving eastern Proterozoic Australia should share a similar tectonothermal history.

Trace element mapping by LA-ICP-MS: assessing geochemical mobility in garnet

A persistent problem in the study of garnet geochemistry is that the consideration of major elements alone excludes a wealth of information preserved by trace elements, particularly the rare-earth elements (REEs). This is despite the fact that trace elements are generally less vulnerable to diffusive resetting, and are sensitive to a broader spectrum of geochemical interactions involving the entire mineral assemblage, including the growth and/or dissolution of accessory minerals. We outline a technique for the routine acquisition of high-resolution 2D trace element maps by LA-ICP-MS, and introduce an extension of the software package XMapTools for rapid processing of LA-ICP-MS data to visualise and interpret compositional zoning patterns. These methods form the basis for investigating the mechanisms controlling geochemical mobility in garnet, which are argued to be largely dependent on the interplay between element fractionation, mineral reactions and partitioning, and the length scales of intergranular transport. Samples from the Peaked Hill shear zone, Reynolds Range, central Australia, exhibit contrasting trace element distributions that can be linked to a detailed sequence of growth and dissolution events. Trace element mapping is thus employed to place garnet evolution in a specific paragenetic context and derive absolute age information by integration with existing U–Pb monazite and Sm–Nd garnet geochronology. Ultimately, the remarkable preservation of original growth zoning and its subtle modification by subsequent re-equilibration is used to ‘see through’ multiple superimposed events, thereby revealing a previously obscure petrological and temporal record of metamorphism, metasomatism, and deformation.