Bo Ren

Preparation and characterization of Ti supported bimodal mesoporous catalysts using a self-assembly route combined with a ship-in-a-bottle method

Ti/BMM (bimodal mesoporous silica) catalysts have been prepared via a self-assembly route combined with a ship-in-a-bottle technique. Four different methods were carried out to investigate the effects of adding ionic liquid [spmim][Cl−] (1-methyl-3-(3-trimethoxysilane) propylimidazole chloride) and triethanolamine (TEAOH) or triethylamine (TEA) to the coordination environment of the titanium species in the mesopores. The structural characteristics and textural properties of resultant samples were characterized by XRD, FT-IR spectroscopy, N2 adsorption–desorption isotherms, TGA, and UV-Vis spectroscopy. The results showed that the bimodal mesoporous structure of Ti/BMMs could be preserved after grafting Ti species via four preparation methods. On the other hand, the presence of [spmim][Cl−] and TEAOH or TEA could not only prevent titanium species existing on the mesoporous surface from aggregating, but also promote loading of tetrahedrally-coordinated titanium species with a high dispersion. Finally, their catalytic activities in the epoxidation of cyclohexene preliminarily indicated that the influence of Ti loading methods on the conversion of cyclohexene was remarkable.

Controllable synthesis of obvious core–shell structured Y/Beta composite zeolite by a stepwise-induced method

A stepwise-induced method with easy and simple preparations is proposed, which is used to successfully prepare the obvious core–shell structured Y/Beta composite zeolite using the pre-synthesized NaY-zeolite as a starting material. The composite zeolites with adjustable FAU/BEA features preliminarily present a good catalytic performance for cumene cracking, showing a strong potential application in petroleum processing.