C. Provenzano

Highly efficient liquid crystal based diffraction grating induced by polarization holograms at the aligning surfaces

Low-scattering and highly efficient orientational gratings are obtained, exploiting polarization holography to modulate the in-plane anchoring axis at both surfaces of a planar nematic cell. Polarization-sensitive azo-dye-doped polyimide films are used as aligning layers. For proper values of cell thickness and spatial periodicity of the gratings, the director configuration in the nematic bulk is a perfect replica of the polarization gratings recorded on the aligning layers. High first-order diffraction efficiency, up to 98%, is observed in thin grating regime. External ac voltage allows to adjust the efficiency over the whole range for arbitrary cell thickness.

Electrically tunable two-dimensional liquid crystals gratings induced by polarization holography

Two-dimensional (2D) gratings made up of an array of differently twisted nematic structures are obtained by crossed assembling of 1D polarization holograms recorded at the photoaligning substrates. The rotating linear polarization pattern, produced by the interference of two opposite circularly polarized beams, is recorded on the azo-dye doped polyimide aligning layers. The 2D gratings diffract light in different directions with different polarization states, that can be optically controlled. Orthogonal circularly and linearly polarized diffraction orders are simultaneously obtained irradiating the grating with a linearly polarized beam. An external ac voltage allows to completely control the diffracted energy distribution.

Polarization-dependent optomechanics mediated by chiral microresonators

Chirality is one of the most prominent and intriguing aspects of nature, from spiral galaxies down to aminoacids. Despite the wide range of living and non-living, natural and artificial chiral systems at different scales, the origin of chirality-induced phenomena is often puzzling. Here we assess the onset of chiral optomechanics, exploiting the control of the interaction between chiral entities. We perform an experimental and theoretical investigation of the simultaneous optical trapping and rotation of spherulite-like chiral microparticles. Due to their shell structure (Bragg dielectric resonator), the microparticles function as omnidirectional chiral mirrors yielding highly polarization-dependent optomechanical effects. The coupling of linear and angular momentum, mediated by the optical polarization and the microparticles chiral reflectance, allows for fine tuning of chirality-induced optical forces and torques. This offers tools for optomechanics, optical sorting and sensing and optofluidics.

Photopolarimeter based on two gratings recorded in thin organic films

A photopolarimeter based on two different kinds of diffraction gratings (a two-grating photopolarimeter) has been developed for real-time measurements of the four elements of the Stokes vector. The main elements of the device are a pure polarization grating and an ordinary transmission grating, both recorded by means of holographic techniques in thin films of organic materials. The first one consists of a diffraction grating recorded by two interfering opposite circularly polarized beams in a Langmuir-Blodgett film of an azo-compound material. The second component is a grating recorded by two interfering parallel circularly polarized beams in a thin film of a photosensitive polymer. Both gratings offer long time stability and good diffraction efficiency. Four photodiodes collect the first-order diffracted beams from these gratings, the output signals of which are read through an analog-to-digital converter by a PC. The optical alignment of the device is easy and the calibration is realized in a one-step procedure.

Surface relief gratings on polymer dispersed liquid crystalsby polarization holography

We report the observation of surface relief gratings (SRGs) on polymer dispersed liquid crystal films after polarization holographic recording, demonstrating the formation of SRGs in systems without azo compounds, where photoisomerization and chromophore reorientation processes do not occur. Permanent SRGs, several hundred nanometers deep, are recorded on the surface of a polymeric material containing oriented liquid crystal droplets. The results suggest that SRG growth under uniform intensity irradiation is not exclusively related to the photoisomerization, but is a more general phenomenon which can involve different photoinduced chemical and physical mechanisms sensitive to the light polarization state. These effects contribute to the formation of anisotropic structures during the recording process.

Polarization Holographic Recording in Amorphous Polymer with Photoinduced Linear and Circular Birefringence

Polarization grating recording in an amorphous and nonchiral azo copolymer has been investigated. The reported study shows that the amorphous polymeric film undergoes a light-guided inhomogeneous supramolecular modification as a consequence of the illumination with proper polarized light patterns, acquiring new functionalities. Both linear and circular, spatially modulated, photoinduced birefringences occur, attaining their peak values in the linearly and circularly polarized regions of the light pattern, respectively. The photoinduced anisotropic structures strongly affect the polarization state of the light propagating through them, and the characterization of their optical diffraction enables measurement of the amplitude of the linear and circular birefringences. The recorded gratings show long-time stability and full reconfigurability functional to the multiple holographic recording.

Method for artifact-free circular dichroism measurements based on polarization grating.

We propose a simple method to perform real-time measurements of circular dichroism (CD), which suppresses the artifacts introduced by anisotropic samples and nonideal optical elements in conventional spectrometers. A single polarization holographic grating is adopted, whose first orders of diffraction have amplitudes that are proportional to the right and left circular polarization component of the input light. We demonstrate that, exploiting unpolarized white light and the intrinsic spectral selectivity of the grating, the true CD spectrum is evaluated in parallel in the spectral range of interest from the intensities of the two diffraction orders, I(+1) and I(-1).

Highly efficient generation of vector beams through polarization holograms

We report a highly efficient and flexible method to yield vector beams (VBs) with spatially variant amplitude, phase and polarization by means of two polarization holograms (PHs). Left- and right-hand circularly polarized scalar beams, generated by the first hologram, are collinearly recombined by the second one to produce the vector beams. By taking advantage of the diffraction properties, the high efficiency, and the intrinsic achromaticity of the polarization holograms, the method aims to overcome the limitations related to stability and efficiency, making it attractive for applications. Theoretical analysis, based on the Jones formalism, and experimental results are shown.

Electric field controlled polarization grating based on a hybrid structure "photosensitive polymer-liquid crystal"

An investigation was carried out on a hybrid structure consisting of a photosensitive polymer in contact with a nematic liquid crystal (NLC) layer. Before assembling the structure, holographic gratings of different periods were recorded in the photopolymer by two laser beams with opposite circular polarization. Such gratings are known for their unique asymmetric diffraction in case of elliptically polarized light and can be used in optical polarization devices. Due to a spatial modulation of the direction of the local optical axis, the photopolymer modulates the anchoring conditions for NLC in a similar way. As a result, a new grating is induced in NLC with the enhanced diffraction efficiency (in a particular experiment it was four orders of magnitude higher than that of the photopolymer). The NLC grating also shows the characteristic asymmetric diffraction for the reconstructing beams of opposite circular polarizations. The diffraction efficiency is easily controlled by an external electric field.

A Nematic Liquid Crystal as an Amplifying Replica of a Holographic Polarization Grating

ABSTRACT Holographic gratings of different periods were recorded in the photopolymer by two laser beams with opposite circular polarization and a nematic liquid crystal was brought in contact with them. The anchoring conditions for the nematic were modulated in a similar way and an induced, field controlled replica manifested a characteristic asymmetric diffraction for the beams of opposite circular polarizations with dramatically enhanced diffraction efficiency. In fact the situation is more complicated than expected and our modelling of the director distribution for a finite anchoring strength explains the experimental data by considering an additional modulated structure at the polymer-nematic interface.