Changyuan Tang

Hydrochemical characteristics and water quality assessment of surface water and groundwater in Songnen plain, Northeast China.

Water quality is the critical factor that influence on human health and quantity and quality of grain production in semi-humid and semi-arid area. Songnen plain is one of the grain bases in China, as well as one of the three major distribution regions of soda saline-alkali soil in the world. To assess the water quality, surface water and groundwater were sampled and analyzed by fuzzy membership analysis and multivariate statistics. The surface water were gather into class I, IV and V, while groundwater were grouped as class I, II, III and V by fuzzy membership analysis. The water samples were grouped into four categories according to irrigation water quality assessment diagrams of USDA. Most water samples distributed in category C1-S1, C2-S2 and C3-S3. Three groups were generated from hierarchical cluster analysis. Four principal components were extracted from principal component analysis. The indicators to water quality assessment were Na, HCO(3), NO(3), Fe, Mn and EC from principal component analysis. We conclude that surface water and shallow groundwater are suitable for irrigation, the reservoir and deep groundwater in upstream are the resources for drinking. The water for drinking should remove of the naturally occurring ions of Fe and Mn. The control of sodium and salinity hazard is required for irrigation. The integrated management of surface water and groundwater for drinking and irrigation is to solve the water issues.

Behavior and fate of alkylphenols in surface water of the Jialu River, Henan Province, China

The behavior and fate of alkylphenols (APs) were studied in surface water from the Jialu River, Henan Province, China. Located at its upper stream, Zhengzhou city is regarded as the major discharge source to this river with its annual effluents containing 726 kg for nonylphenol (NP) and 30.2 kg for octylphenol (OP). The concentrations of NP and OP in surface water ranged from 75.2 to 1520 ngL(-1) and from 20.9 to 63.2 ngL(-1), respectively. To assess the behavior of APs along the river, a mass balance equation based on chloride was adopted, due to its relative conservation. The results showed that dilution effect was prevailing in determining the APs concentrations in surface water along the river. The effect of potential biodegradation was also estimated with an assumption of the optimized biodegradation. The contributions of dilution and biodegradation to the decline of APs concentrations were 38.8%, 23.7% for NP and 57.8%, 24.3% for OP, respectively. The other contribution to the decline of APs concentrations along the river was considered as an integrated effect of adsorption and air-water exchange with the values of 37.5% for NP and 17.9% for OP. The decay half-lives of NP and OP from surface water bodies were 1.6 and 2.4d, respectively. About 70.2% of total NP and 24.1% of total OP were finally eliminated from water phase to surrounding matrix in the downstream. The results suggested that the downstream river channel served as the net sink of APs in the study area.

Prediction of changes in soil moisture associated with climatic changes and their implications for vegetation changes: Waves model simulation on Taihang Mountain, China

The WAVES model was used to simulate the effect of global warming on soil moisture on the semi-arid Taihang Mountain in China. Parameters of the WAVES model were first adjusted according to soil moisture data from a field global warming experiment. Then, the reliability of WAVES in predicting soil moisture changes induced by climatic change was confirmed by comparing the simulated and observed soil moisture values under different climatic conditions and plant growth rates of another field treatment. Next, 10 climate change scenarios incorporating increases in temperature and changes in precipitation were designed. When a simulation was conducted using the leaf area index (LAI) growth pattern from a field experiment under the present climatic conditions, the results suggested that the combination of temperature increase and precipitation decrease would greatly decrease soil water content throughout the entire simulation period. On the other hand, only when precipitation increased by 20% and temperatureincreased by 2 °C, the effect of precipitation increase on soil moisture was obviously positive. Although soil moisture conditions in the T2P1 (temperature increase by 2 °C and precipitation increase by 10%) and T4P2 (temperature increase by 4 °C and precipitation increase by 20%) scenarios were slightly better during the rainy season and notmuch changed before the rainy season, the positive effect of 10%precipitation increase on soil moisture was totally offset by moisture decrease caused bya 4 °C temperature increase in the T4P1 scenario. At the same time, the trends of soil-moisture change were highly coincident with predicted changes in productivity. Finally, the predicted LAI values from other studies were combined with the climatic change scenarios and used in the simulation. The results showed that changes in LAI alleviated, at least to some extent, the effects of temperature and precipitation changes on soil moisture.

Characteristics of nitrate in major rivers and aquifers of the Sanjiang Plain, China

The characteristics of nitrate (NO(3)(-)) in major rivers and aquifers of the Sanjiang Plain, China were investigated by hydrogeochemical conditions, nitrogen isotope technique and CFCs trace. An overall understanding on the sources and fate of NO(3)(-) in the surface water and the groundwater was obtained. The NO(3)(-) concentrations in the surface water were low and no samples exceeds the WTO standards. However, 11.4% of the groundwater samples exceeded the WTO standards, indicating local NO(3)(-) pollution in rural areas. Redox condition analysis revealed that most of the surface water had oxic condition, while for the shallow groundwater (mean well depth smaller than 30 m), the redox condition began to change into anoxic zone, and the deep groundwater (mean well depth larger than 50 m) showed strong anoxic condition. The δ(15)N-NO(3) data indicated soil N and fertilizer contributed the major sources in the surface water, and NO(3)(-) in the groundwater mainly showed a manure origin. In the Songhua-Heilong River, dilution effect was dominating, while for the Wusuli River, it showed that mix with water contained excess of NO(3)(-) resulted in the NO(3)(-) concentration increased along the river. Additionally, the NO(3)(-) transportation in the groundwater was analyzed by groundwater ages derived from environmental tracer (CFCs) data. The relation between the groundwater ages and the NO(3)(-) concentrations showed that the young groundwater with the age less than 60 years had higher NO(3)(-) concentrations than the old groundwater over the age of 60 years because anthropogenic activities began to boom from 1950s in the Sanjiang Plain.

The impacts of a linear wastewater reservoir on groundwater recharge and geochemical evolution in a semi-arid area of the Lake Baiyangdian watershed, North China Plain

Sewage leakage has become an important source of groundwater recharge in urban areas. Large linear wastewater ponds that lack anti-seepage measures can act as river channels that cause the deterioration of groundwater quality. This study investigated the groundwater recharge by leakage of the Tanghe Wastewater Reservoir, which is the largest industrial wastewater channel on the North China Plain. Additionally, water quality evolution was investigated using a combination of multivariate statistical methods, multi-tracers and geochemical methods. Stable isotopes of hydrogen and oxygen indicated high levels of wastewater evaporation. Based on the assumption that the wastewater was under an open system and fully mixed, an evaporation model was established to estimate the evaporation of the wastewater based on isotope enrichments of the Rayleigh distillation theory using the average isotope values for dry and rainy seasons. Using an average evaporation loss of 26.5% for the input wastewater, the estimated recharge fraction of wastewater leakage and irrigation was 73.5% of the total input of wastewater. The lateral regional groundwater inflow was considered to be another recharge source. Combing the two end-members mix model and cluster analysis revealed that the mixture percentage of the wastewater decreased from the Highly Affected Zone (76%) to the Transition Zone (5%). Ion exchange and redox reaction were the dominant geochemical processes when wastewater entered the aquifer. Carbonate precipitation was also a major process affecting evolution of groundwater quality along groundwater flow paths.

Interception and recharge processes beneath a Pinus elliotii forest

Interception and recharge processes beneath a Pinus elliotii forest were considered in an integrated study. In the study area, annual rainfall was divided into throughfall (74.45%), stemflow (9.37%) and interception (16.28%). Throughfall and stemflow infiltrate into the soil in different ways. The results show that trees can affect the recharge characteristics by providing throughfall as a non-point source and stemflow as a point source, and also through their influence on infiltration processes by making the hydraulic conductivity of soil heterogeneous. In the root zone there was a divergent zero flux plane recharged by macropore flow during heavy rain and a convergent zero flux plane caused by transpiration during dry periods.

Assessment of major ions and heavy metals in groundwater: a case study from Guangzhou and Zhuhai of the Pearl River Delta, China

Anthropogenic activities in the Pearl River Delta (PRD) have caused a deterioration of groundwater quality over the past twenty years as a result of rapid urbanization and industrial development. In this study, the hydrochemical characteristics, quality, and sources of heavy metals in the groundwater of the PRD were investigated. Twenty-five groundwater samples were collected and analyzed for pH, electrical conductivity (EC), total dissolved solids (TDS), δ18O, δ2H, major ions, and heavy metals. The groundwater was slightly acidic and presented TDS values that ranged from 35.5 to 8,779.3 mg·L−1. The concentrations of the major ions followed the order Cl−>HCO3−>Na+>SO42−>NO3−>NH4+>Ca2+>K+>Mg2+>Fe2+/3+>Al3+. Ca-Mg-HCO3 and Na-K-HCO3 were the predominant types of facies, and the chemical composition of the groundwater was primarily controlled by chemical weathering of the basement rocks, by mixing of freshwater and seawater and by anthropogenic activities. The heavy metal pollution index (HPI) indicated that 64% of the samples were in the low category, 16% were in the medium category and 20% were in the high category, providing further evidence that this groundwater is unsuitable for drinking. Lead, arsenic, and manganese were mainly sourced from landfill leachate; cadmium from landfill leachate and agricultural wastes; mercury from the discharge of leachate associated with mining activities and agricultural wastes; and chromium primarily from industrial wastes. According to the irrigation water quality indicators, the groundwater in the PRD can be used for irrigation in most farmland without strong negative impacts. However, approximately 9 million people in the Guangdong Province are at risk due to the consumption of untreated water. Therefore, we suggest that treating the groundwater to achieve safer levels is necessary.

Topographical effects on the distributions of rainfall and 18O distributions: a case in Miyake Island, Japan

In this paper, we try to calculate precipitation in Miyake Island, Japan. In order to know the temporal and spatial variations of precipitation, we have set 15 rain gauges randomly in the island to collect the monthly precipitation data since June 1994. It is found that the precipitation is very different from point to point. First, we used statistical methods to get the correlations between the monthly precipitation at our survey points and that at the weather station. Next, regression analyses were used to establish formulae to calculate precipitation as a function of altitude, aspect of the geomorphological surface and wind direction. Based on these results, distributions of monthly and yearly precipitation and δ18O over the island were assessed. The results show that landscape patterns strongly influence precipitation distribution over the island, with the highest precipitation being found on the windward side, about 400–600 m above sea level. Even at places at the same altitude, the precipitation was different because of the aspect of the landscape. At the same time, altitude effects for δ18O on both the windward and leeward sides were −0·10‰/100 m and −0·15‰/100 m, respectively. Comparing with the distribution of precipitation distribution, it was also found that δ18O for the windward and leeward sides was different from that for precipitation, which means that both topographical effects must be considered separately.

The relationship between and evolution of surface water and groundwater in Songnen Plain, Northeast China

To improve water management, the relation and the hydrochemical evolution of surface water and groundwater were studied in the Songnen Plain. The surface water and groundwater samples were evaluated for stable isotopes and hydrochemistry analyses. The stable isotopic compositions (δ18O, δ D) indicate the groundwater recharges from the precipitation. However, the connectivity between surface water and groundwater is weak, because of the clay layer and the interrupted aquifer. The water evolution is from Ca–Mg–HCO3 to Na–HCO3 by the evaporation, water–rock interaction, and ion exchange processes. The water evaporation and leaching of saline–alkaline soil are the main reasons for water salinity. Further, the leaching of salts in the soil during recharging from backwater and irrigation water intensifies the salinization. The relationship between and evolution of surface water and groundwater provide important guidance for water management not only in the arid and semi-arid area, but also in the soda saline–alkali soil regions of the world.

The renewability and quality of shallow groundwater in Sanjiang and Songnen Plain, Northeast China

Abstract Groundwater is a key component for water resources in Sanjiang and Songnen Plain, an important agriculture basement in China. The quality and the renewability of irrigation groundwater are essential for the stock raising and agricultural production. Shallow groundwater was sampled and analyzed for various variables. The salinity sodium concentration and bicarbonate hazard, were examined with regard to the United States Department of Agriculture (USDA) irrigation water standards. The concentration of chlorofluorocarbons (CFCs) was determined to analyze the age of groundwater. Most groundwater samples labeled as excellent to good for irrigation with low salinity hazard or medium salinity hazard. Four groundwater samples were good and suspected for irrigation with high salinity hazard. Generally groundwater in Sanjiang Plain was younger than the groundwater in Songnen Plain. Meanwhile, groundwater nearby river is younger than the groundwater further away inside the watershed. The mean age of groundwater in Sanjiang Plain is in average of 44.1, 47.9 and 32.8 years by CFC-11 (CCl3F), CFC-12 (CCl2F2) and CFC-113 (C2Cl3F3), respectively. The mean ages of groundwater in Songnen Plain is in average of 46.1, 53.4, and 40.7 years by CFC-11, CFC-12 and CFC-113, respectively. Thus, groundwater nearby rivers could be directly exploited as irrigation water. Partial groundwater has to be processed to lower the salt concentration rather than directly utilized as irrigation water in Songnen Plain. Both water quality and renewability should be put in mind for sustainable agricultural development and water resources management.