Xianfang Song

Hydrochemical characteristics and water quality assessment of surface water and groundwater in Songnen plain, Northeast China.

Water quality is the critical factor that influence on human health and quantity and quality of grain production in semi-humid and semi-arid area. Songnen plain is one of the grain bases in China, as well as one of the three major distribution regions of soda saline-alkali soil in the world. To assess the water quality, surface water and groundwater were sampled and analyzed by fuzzy membership analysis and multivariate statistics. The surface water were gather into class I, IV and V, while groundwater were grouped as class I, II, III and V by fuzzy membership analysis. The water samples were grouped into four categories according to irrigation water quality assessment diagrams of USDA. Most water samples distributed in category C1-S1, C2-S2 and C3-S3. Three groups were generated from hierarchical cluster analysis. Four principal components were extracted from principal component analysis. The indicators to water quality assessment were Na, HCO(3), NO(3), Fe, Mn and EC from principal component analysis. We conclude that surface water and shallow groundwater are suitable for irrigation, the reservoir and deep groundwater in upstream are the resources for drinking. The water for drinking should remove of the naturally occurring ions of Fe and Mn. The control of sodium and salinity hazard is required for irrigation. The integrated management of surface water and groundwater for drinking and irrigation is to solve the water issues.

Stable isotopic compositions of precipitation in China

During the mid-1980s, there were 31 stations in China that successfully participated in the Global Network of Isotopes in Precipitation. However, most observations were suspended after the mid-1990s. The discontinuous data hindered the application of precipitation isotopes, which are strongly affected in China by the Asian monsoon and are thus of intrinsic interest for palaeoclimatologists. Therefore, to continuously observe precipitation isotopes nationwide, the Chinese Network of Isotopes in Precipitation was established in 2004. The current study reviewed the major characteristics of the 928 samples that were collected from 2005 to 2010. The ranges of δD and δ18O values generally followed the pattern NE>NW>TP>NC>SC, and the amount-weighted δ-values followed the pattern SC>NW>NC>TP>NE. Temporal variations presented a ‘V’-shaped pattern at the SC region and reverse ‘V’-shaped patterns at the NE and NW regions. Decreasing trends with the advent of the rainy season were found at the NC and TP regions. The Chinese Meteoric Water Line has been established as δD=7.48δ18O+1.01. The distributions of scattering along the line demonstrated different water vapour origins and characteristics. The values of δ18O showed strong temperature dependence at the NE (0.27‰/°C) and NW stations (0.37‰/°C), and this dependent variable switched to water vapour pressure and vapour pressure at the SC stations. The geographical controls of δ18O were −0.22‰/° and −0.13‰/100 m for latitude and altitude, respectively. The δ18O/Latitude gradient increased from south to north at the Eastern Monsoon Region, and the δ18O/Altitude gradient (−0.30‰/100 m) was especially significant for the TP region. The results of this study could provide basic isotopic information for on-going investigations in hydrology, meteorology, palaeoclimatology and ecology at different regions of China.

Stable isotopic compositions in Australian precipitation

Stable deuterium (delta D) and oxygen-18 (delta O-18) isotopes in 1962 to 2002 precipitation from the seven Australian stations of the Global Network of Isotopes in Precipitation (GNIP) were used to investigate isotope characteristics including temporal and spatial distributions across different regions of Australia. On the basis of 1534 samples, the local meteoric water line (LMWL) was established as delta D = 7.10 delta O-18 + 8.21. delta O-18 showed a depletion trend from north and south to central Australia (a continental effect) and from west to east. Precipitation amount effects were generally greater than temperature effects, with quadratic or logarithmic correlations describing delta/T and delta/P better than linear relationships. Nonlinear stepwise regression was used to determine the significant meteorological control factors for each station, explaining about 50% or more of the delta O-18 variations. Geographical control factors for delta O-18 were given by the relationship delta O-18 (parts per thousand) = -0.005 longitude (degrees) - 0.034 latitude (degrees)-0.003 altitude (m) - 4.753. Four different types of d-excess patterns demonstrated particular precipitation formation conditions for four major seasonal rainfall zones. Finally, wavelet coherence (WTC) between delta O-18 and SOI confirmed that the influence of ENSO decreased from east and north to west Australia.

Application of the SWAP model to simulate the field water cycle under deficit irrigation in Beijing, China

The evaluation of the field water cycle under deficit irrigation plays an important role in studying mechanism of field water dynamics, optimization of agricultural water management strategies, and assessment of regional water resources. In this study, the agro-hydrological Soil-Water-Atmosphere-Plant (SWAP) model was used to evaluate the field water cycle for a winter wheat-summer corn double cropping system in Beijing, China under deficit irrigation. A carefully designed field experiment was carried out from 2007 to 2009 with six irrigation treatments. The SWAP model was calibrated with soil water contents of two treatments. The dataset of the main field water balance components including soil water content, profile water storage and water flux through the bottom of the root zone were used to validate the SWAP model. The average root mean square error (RMSE) and the mean relative error (MRE) values of predicted soil water contents were 2.4% and 8.0%, respectively. The dataset of predicted and measured values were close to the 1:1 scale line for both the profile water storage and soil water flux. As an application of the SWAP model, the optimal irrigation management practices for the hydrologic years of 75%, 50% and 25%, respectively, in the Beijing area were obtained. The simulated average amount of water saving and groundwater recharge under the optimal irrigation schedules were about 190 mm and 16.1 mm, respectively. This study indicates that the SWAP model can be used as a powerful tool to simulate the field water cycle and evaluate irrigation practices.

Behavior and fate of alkylphenols in surface water of the Jialu River, Henan Province, China

The behavior and fate of alkylphenols (APs) were studied in surface water from the Jialu River, Henan Province, China. Located at its upper stream, Zhengzhou city is regarded as the major discharge source to this river with its annual effluents containing 726 kg for nonylphenol (NP) and 30.2 kg for octylphenol (OP). The concentrations of NP and OP in surface water ranged from 75.2 to 1520 ngL(-1) and from 20.9 to 63.2 ngL(-1), respectively. To assess the behavior of APs along the river, a mass balance equation based on chloride was adopted, due to its relative conservation. The results showed that dilution effect was prevailing in determining the APs concentrations in surface water along the river. The effect of potential biodegradation was also estimated with an assumption of the optimized biodegradation. The contributions of dilution and biodegradation to the decline of APs concentrations were 38.8%, 23.7% for NP and 57.8%, 24.3% for OP, respectively. The other contribution to the decline of APs concentrations along the river was considered as an integrated effect of adsorption and air-water exchange with the values of 37.5% for NP and 17.9% for OP. The decay half-lives of NP and OP from surface water bodies were 1.6 and 2.4d, respectively. About 70.2% of total NP and 24.1% of total OP were finally eliminated from water phase to surrounding matrix in the downstream. The results suggested that the downstream river channel served as the net sink of APs in the study area.

Hydrogeochemical Indicators of Groundwater Flow Systems in the Yangwu River Alluvial Fan, Xinzhou Basin, Shanxi, China

Based on analysis of groundwater hydrochemical and isotopic indicators, this article aims to identify the groundwater flow systems in the Yangwu River alluvial fan, in the Xinzhou Basin, China. Groundwater δ2H and δ18O values indicate that the origin of groundwater is mainly from precipitation, with local evaporative influence. d-excess values lower than 10% in most groundwaters suggest a cold climate during recharge in the area. Major ion chemistry, including rCa/rMg and rNa/rCl ratios, show that groundwater salinization is probably dominated by water–rock interaction (e.g., silicate mineral weathering, dissolution of calcite and dolomite and cation exchange) in the Yangwu River alluvial fan, and locally by intensive evapotranspiration in the Hutuo River valley. Cl and Sr concentrations follow an increasing trend in shallow groundwater affected by evaporation, and a decreasing trend in deep groundwater. 87Sr/86Sr ratios reflect the variety of lithologies encountered during throughflow. The groundwater flow systems (GFS) of the Yangwu River alluvial fan include local and intermediate flow systems. Hydrogeochemical modeling results, simulated using PHREEQC, reveal water–rock interaction processes along different flow paths. This modeling method is more effective for characterizing flow paths in the intermediate system than in the local system. Artificial exploitation on groundwater in the alluvial fan enhances mixing between different groundwater flow systems.

Characteristics of nitrate in major rivers and aquifers of the Sanjiang Plain, China

The characteristics of nitrate (NO(3)(-)) in major rivers and aquifers of the Sanjiang Plain, China were investigated by hydrogeochemical conditions, nitrogen isotope technique and CFCs trace. An overall understanding on the sources and fate of NO(3)(-) in the surface water and the groundwater was obtained. The NO(3)(-) concentrations in the surface water were low and no samples exceeds the WTO standards. However, 11.4% of the groundwater samples exceeded the WTO standards, indicating local NO(3)(-) pollution in rural areas. Redox condition analysis revealed that most of the surface water had oxic condition, while for the shallow groundwater (mean well depth smaller than 30 m), the redox condition began to change into anoxic zone, and the deep groundwater (mean well depth larger than 50 m) showed strong anoxic condition. The δ(15)N-NO(3) data indicated soil N and fertilizer contributed the major sources in the surface water, and NO(3)(-) in the groundwater mainly showed a manure origin. In the Songhua-Heilong River, dilution effect was dominating, while for the Wusuli River, it showed that mix with water contained excess of NO(3)(-) resulted in the NO(3)(-) concentration increased along the river. Additionally, the NO(3)(-) transportation in the groundwater was analyzed by groundwater ages derived from environmental tracer (CFCs) data. The relation between the groundwater ages and the NO(3)(-) concentrations showed that the young groundwater with the age less than 60 years had higher NO(3)(-) concentrations than the old groundwater over the age of 60 years because anthropogenic activities began to boom from 1950s in the Sanjiang Plain.

Water Infiltration in Layered Soils with Air Entrapment: Modified Green-Ampt Model and Experimental Validation

Air entrapment in soil is common in cases of farmland flood irrigation or intense rain. A simple, physically based model would be more useful than the complex two-phase (gaseous and liquid phase) flow model to describe water infiltration in layered soils with air entrapment. This study proposed a modified Green-Ampt model (MGAM) to simulate water infiltration in layered soils with consideration of entrapped air. A saturation coefficient S(a) was introduced in MGAM to account for the resistance effect of air entrapment on infiltration. S(a) had robust physical meaning, and was approximately equal to one minus the plus of the residual air and residual water saturation degree that could be determined from the soil water retention curve equation. In MGAM, the actual water content and hydraulic conductivity of the wetted zone were determined by multiplying S(a) with the saturated values. Infiltration experiments in a 300-cm-long five-layered soil column and a 280-cm-deep eight-layered field soil profile were conducted to test the applicability of MGAM. For comparison, the infiltration process was also simulated by the traditional Green-Ampt model (TGAM), in which the wetted zone was assumed to be fully saturated, and the Bouwer Green-Ampt model (BGAM), in which the hydraulic conductivity of the wetted zone was half that of the saturated hydraulic conductivity. The estimated S(a) values were very close to the measured saturation degree of soil layers at the termination of the experiment. The simulation results indicated that the TGAM overestimated the infiltration rate and cumulative infiltration, whereas the BGAM underestimated the infiltration rate and cumulative infiltration. Furthermore, the depths of the wetting fronts simulated by TGAM and BGAM were considerably smaller than those measured. The MGAM provided satisfactory simulation results and adequately described the infiltration process in both the laboratory soil column and the field soil profile. DOI:10.1061/(ASCE)HE.1943-5584.0000360

The role of anthropogenic and natural factors in shaping the geochemical evolution of groundwater in the Subei Lake basin, Ordos energy base, Northwestern China

Groundwater resources are increasingly exploited for industrial and agricultural purposes in many arid regions globally, it is urgent to gain the impact of the enhanced anthropogenic pressure on the groundwater chemistry. The aim of this study was to acquire a comprehensive understanding of the evolution of groundwater chemistry and to identify the impact of natural and anthropogenic factors on the groundwater chemistry in the Subei Lake basin, Northwestern China. A total of 153 groundwater samples were collected and major ions were measured during the three campaigns (August and December 2013, May 2014). At present, the major hydrochemical facies in unconfined groundwater are Ca-Mg-HCO3, Ca-Na-HCO3, Na-Ca-HCO3, Na-HCO3, Ca-Mg-SO4 and Na-SO4-Cl types, while the main hydrochemical facies in confined groundwater are Ca-Mg-HCO3, Ca-Na-HCO3, Na-Ca-HCO3, Ca-HCO3 and Na-HCO3 types. Relatively greater seasonal variation can be observed in the chemical constituents of confined groundwater than that of unconfined groundwater. Rock weathering predominates the evolution of groundwater chemistry in conjunction with the cation exchange, and the dissolution/precipitation of gypsum, halite, feldspar, calcite and dolomite are responsible for the chemical constituents of groundwater. Anthropogenic activities can be classified as: (1) groundwater overexploitation; (2) excessive application of fertilizers in agricultural areas. Due to intensive groundwater pumping, the accelerated groundwater mineralization resulted in the local changes in hydrochemical facies of unconfined groundwater, while the strong mixture, especially a large influx of downward leakage from the unconfined aquifer into the confined aquifer, played a vital role in the fundamental variation of hydrochemical facies in confined aquifer. The nitrate contamination is mainly controlled by the local hydrogeological settings coupled with the traditional flood irrigation. The deeper insight into geochemical evolution of groundwater obtained from this study can be beneficial to improving groundwater management for sustainable development in the rapidly industrialized areas.

The impacts of a linear wastewater reservoir on groundwater recharge and geochemical evolution in a semi-arid area of the Lake Baiyangdian watershed, North China Plain

Sewage leakage has become an important source of groundwater recharge in urban areas. Large linear wastewater ponds that lack anti-seepage measures can act as river channels that cause the deterioration of groundwater quality. This study investigated the groundwater recharge by leakage of the Tanghe Wastewater Reservoir, which is the largest industrial wastewater channel on the North China Plain. Additionally, water quality evolution was investigated using a combination of multivariate statistical methods, multi-tracers and geochemical methods. Stable isotopes of hydrogen and oxygen indicated high levels of wastewater evaporation. Based on the assumption that the wastewater was under an open system and fully mixed, an evaporation model was established to estimate the evaporation of the wastewater based on isotope enrichments of the Rayleigh distillation theory using the average isotope values for dry and rainy seasons. Using an average evaporation loss of 26.5% for the input wastewater, the estimated recharge fraction of wastewater leakage and irrigation was 73.5% of the total input of wastewater. The lateral regional groundwater inflow was considered to be another recharge source. Combing the two end-members mix model and cluster analysis revealed that the mixture percentage of the wastewater decreased from the Highly Affected Zone (76%) to the Transition Zone (5%). Ion exchange and redox reaction were the dominant geochemical processes when wastewater entered the aquifer. Carbonate precipitation was also a major process affecting evolution of groundwater quality along groundwater flow paths.