Christian Van Haesendonck
Katholieke Universiteit Leuven
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Featured researches published by Christian Van Haesendonck.
Nanotechnology | 2008
Alexander Malesevic; Roumen Vitchev; Koen Schouteden; A. Volodin; Liang Zhang; Gustaaf Van Tendeloo; Annick Vanhulsel; Christian Van Haesendonck
If graphene is ever going to live up to the promises of future nanoelectronic devices, an easy and cheap route for mass production is an essential requirement. A way to extend the capabilities of plasma-enhanced chemical vapour deposition to the synthesis of freestanding few-layer graphene is presented. Micrometre-wide flakes consisting of four to six atomic layers of stacked graphene sheets have been synthesized by controlled recombination of carbon radicals in a microwave plasma. A simple and highly reproducible technique is essential, since the resulting flakes can be synthesized without the need for a catalyst on the surface of any substrate that withstands elevated temperatures up to 700 °C. A thorough structural analysis of the flakes is performed with electron microscopy, x-ray diffraction, Raman spectroscopy and scanning tunnelling microscopy. The resulting graphene flakes are aligned vertically to the substrate surface and grow according to a three-step process, as revealed by the combined analysis of electron microscopy and x-ray photoelectron spectroscopy.
Langmuir | 2008
Tom Hauffman; Orlin Blajiev; Johan Snauwaert; Christian Van Haesendonck; Annick Hubin; H. Terryn
The deposition of n-octylphosphonic acid on aluminum oxide was studied. The substrate was pretreated in order to achieve a root-mean-square roughness of <1 nm, a hydroxyl fraction of 30%, and a thickness of approximately 170 nm. It was proven using X-ray photoelectron spectroscopy (XPS) and atomic force microscopy (AFM) that, rather than a monolayer, an organic multilayer was formed. The growth mechanism was identified as a Stranski-Krastanov one. It was also shown that the use of AFM, probing the surface topography, is essential for a reliable quantification and interpretation of data obtained with XPS.
Ultramicroscopy | 1995
Anja Vinckier; I. Heyvaert; An D'hoore; Tim McKittrick; Christian Van Haesendonck; Yves Engelborghs; Louis Hellemans
Microtubules isolated from pig brains have been immobilized on an inorganic substrate for use in AFM studies. The method employs 4-aminobutyldimethylmethoxysilane and glutaraldehyde to activate a silicon wafer for binding the biopolymer. The covalent bond ensures the positional stability of the tubules on the substrate, and allows reproducible scanning probe experiments. Microtubules have been imaged both by atomic force and scanning tunneling microscopy, yielding results very similar to electron microscopy. The average apparent height of the tubules is smaller than observed with transmission electron microscopy (25 nm) and is smaller in buffer solution (10 nm) than in air (15 nm). The biopolymer surface is softer under buffer than in air. The highest resolution was obtained with the tapping mode where surface features as small as 10 nm in X and Y have been resolved. Gold-coated tubules bound on silicon have been successfully imaged by STM, while images of uncertain origin were generated for tubules deposited on graphite. It is shown that artefacts imaged on a blank graphite surface can easily be confounded with collapsed tubules.
Advanced Materials | 2010
Frederic Leroux; Maarten Gysemans; Sara Bals; Kees Joost Batenburg; Johan Snauwaert; Thierry Verbiest; Christian Van Haesendonck; Gustaaf Van Tendeloo
[*] Dr. M. Gysemans, Prof. J. Snauwaert, Prof. C. Van Haesendonck Laboratory of Solid-State Physics and Magnetism Katholieke Universiteit Leuven Celestijnenlaan 200 D, BE-3001 Leuven (Belgium) E-mail: [email protected] F. Leroux, Prof. S. Bals, Prof. G. Van Tendeloo EMAT, University of Antwerp Groenenborgerlaan 171, BE-2020 Antwerp (Belgium) E-mail: [email protected] Dr. K. J. Batenburg Vision Lab, University of Antwerp Universiteitsplein 1, BE-2020 Wilrijk (Belgium)
Journal of Biological Chemistry | 2006
T. Vandebroek; Dick Terwel; Thomas Vanhelmont; Maarten Gysemans; Christian Van Haesendonck; Yves Engelborghs; Joris Winderickx; Fred Van Leuven
Phosphorylation of Tau protein and binding to microtubules is complex in neurons and was therefore studied in the less complicated model of humanized yeast. Human Tau was readily phosphorylated at pathological epitopes, but in opposite directions regulated by kinases Mds1 and Pho85, orthologues of glycogen synthase kinase-3β and cdk5, respectively (1). We isolated recombinant Tau-4R and mutant Tau-P301L from wild type, Δmds1 and Δpho85 yeast strains and measured binding to Taxol-stabilized mammalian microtubules in relation to their phosphorylation patterns. Tau-4R isolated from yeast lacking mds1 was less phosphorylated and bound more to microtubules than Tau-4R isolated from wild type yeast. Paradoxically, phosphorylation of Tau-4R isolated from kinase Pho85-deficient yeast was dramatically increased resulting in very poor binding to microtubules. Dephosphorylation promoted binding to microtubules to uniform high levels, excluding other modifications. Isolated hyperphosphorylated, conformationally altered Tau-4R completely failed to bind microtubules. In parallel to Tau-4R, we expressed, isolated, and analyzed mutant Tau-P301L. Total dephosphorylated Tau-4R and Tau-P301L bound to microtubules very similarly. Surprisingly, Tau-P301L isolated from all yeast strains bound to microtubules more extensively than Tau-4R. Atomic force microscopy demonstrated, however, that the high apparent binding of Tau-P301L was due to aggregation on the microtubules, causing their deformation and bundling. Our data explain the pathological presence of granular Tau aggregates in neuronal processes in tauopathies.
Nanotechnology | 2010
Roumen Vitchev; Alexander Malesevic; Roumen Petrov; Raymond Kemps; Myrjam Mertens; Annick Vanhulsel; Christian Van Haesendonck
A promising method for the production of few-layer graphene (FLG) is microwave plasma-enhanced chemical vapour deposition (MW PECVD). However, the growth mechanism of PECVD-synthesized FLG is not completely understood. The aim of this work was to investigate the initial stages of the growth process of FLG deposited by MW PECVD on several substrates (quartz, silicon, platinum). The deposited thin films were characterized by angle-resolved x-ray photoelectron spectroscopy (ARXPS), electron backscattered diffraction (EBSD), scanning electron microscopy (SEM) and x-ray diffraction (XRD). It was found that the initial stages of the deposition were different for the three chosen substrate materials. However, the fully grown FLG layers were similar for all substrates.
New Journal of Physics | 2009
Qingfeng Zhan; Stijn Vandezande; Kristiaan Temst; Christian Van Haesendonck
Fe films with thickness varying between 5 and 100 nm were grown on flat MgO(001) substrates while rotating the substrates. Hysteresis loops with one step and two steps were observed and interpreted in terms of a magnetization reversal mechanism with either two successive or two separate 90° domain wall (DW) nucleations, respectively. This recently introduced, novel mechanism for 180° magnetic transitions was used to quantitatively evaluate both the uniaxial magnetic anisotropy (UMA), which accompanies the intrinsic fourfold in-plane magnetic anisotropy, and the DW nucleation energy. The strength of both the UMA and the DW nucleation energy turns out to be inversely proportional to the thickness of the Fe layers for Fe/MgO(001). This suggests that the extra UMA and the DW nucleation/propagation for Fe layers are pure interface related effects. By comparing six 15 nm thick Fe/MgO(001) films deposited under different conditions, it is found that these interface related effects originate from the presence of atomic steps due to the substrate miscut and from the presence of strain relaxation resulting from lattice mismatch.
Physical Review B | 2009
Qingfeng Zhan; Stijn Vandezande; Kristiaan Temst; Christian Van Haesendonck
We investigate the magnetization reversal in Fe/MgO(001) films with fourfold in-plane magnetic anisotropy and an additional uniaxial anisotropy whose orientation and strength are tuned using different growth geometries and post growth treatments. The previously adopted mechanism of 180^{o} domain wall nucleation clearly fails to explain the observed 180^{o} magnetization reversal. A new reversal mechanism with two successive domain wall nucleations consistently predicts the switching fields for all field orientations. Our results are relevant for a correct interpretation of magnetization reversal in many other epitaxial metallic and semiconducting thin films.
Applied Physics Letters | 2009
Qingfeng Zhan; Christian Van Haesendonck; Stijn Vandezande; Kristiaan Temst
We studied surface morphology and magnetic properties of Fe/MgO(001) films deposited at an angle varying between 0° and 60° with respect to the surface normal and with azimuth along the Fe[010] or the Fe[110] direction. Due to shadowing, elongated grains appear on the film surface for deposition at sufficiently large angle. X-ray reflectivity reveals that, depending on the azimuthal direction, films become either rougher or smoother for oblique deposition. For deposition along Fe[010] the pronounced uniaxial magnetic anisotropy (UMA) results in the occurrence of “reversed” two-step and of three-step hysteresis loops. For deposition along Fe[110] the growth-induced UMA is much weaker, causing a small rotation of the easy axes.We studied surface morphology and magnetic properties of Fe/MgO(001) films deposited at an angle varying between 0° and 60° with respect to the surface normal and with azimuth along the Fe[010] or the Fe[110] direction. Due to shadowing, elongated grains appear on the film surface for deposition at sufficiently large angle. X-ray reflectivity reveals that, depending on the azimuthal direction, films become either rougher or smoother for oblique deposition. For deposition along Fe[010] the pronounced uniaxial magnetic anisotropy (UMA) results in the occurrence of “reversed” two-step and of three-step hysteresis loops. For deposition along Fe[110] the growth-induced UMA is much weaker, causing a small rotation of the easy axes.
Journal of the American Chemical Society | 2009
Núria Crivillers; Andrea Minoia; An Ver Heyen; Marta Mas-Torrent; Christian Sporer; A. Volodin; Christian Van Haesendonck; Mark Van der Auweraer; Roberto Lazzaroni; Steven De Feyter; Jaume Veciana; Concepció Rovira
The supramolecular organization of a new polychlorotriphenyl (PTM) radical bearing three long alkyl chains has been studied by scanning tunneling microscopy (STM) at the liquid-solid interface. This radical hierarchically self-assembles on graphite forming head-to-head dimers that organize in rows following an interesting spin-containing two-leg molecular ladder topology, in which the alkyl chains determine the space between the radical rows and act as diamagnetic barriers. In addition, these double-rows also self-assemble three-dimensionally, leading to a multilayer organization which is still influenced by the HOPG substrate symmetry. The observed nanostructures are sustained by different intermolecular interactions such as Cl...Cl, Cl...Ph, pi-pi, van der Waals, and CH...pi interactions. Theoretical calculations were used to model the observed assemblies, and the results were in complete agreement with the experimental data. Remarkably, atomic force microscopy (AFM) studies confirmed that this tendency to form double rows composed by the PTM magnetic heads surrounded by the alkyl chains is maintained after the complete evaporation of the solvent. The electrochemical and magnetic properties of these PTM nanostructures were also demonstrated.