Claudine Scolaro
École Polytechnique Fédérale de Lausanne
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Publication
Featured researches published by Claudine Scolaro.
Journal of Inorganic Biochemistry | 2008
Claudine Scolaro; Christian G. Hartinger; Claire S. Allardyce; Bernhard K. Keppler; Paul J. Dyson
The hydrolysis of [Ru(eta(6)-p-cymene)Cl(2)(PTA)] (PTA=1,3,5-triaza-7-phosphatricyclo-[3.3.1.1]decanephosphine; RAPTA-C) was studied using UV-visible (UV-vis) spectrophotometry and NMR spectroscopy. In analogy to in silico studies, [Ru(eta(6)-p-cymene)Cl(H(2)O)(PTA)](+) was found to be the most abundant hydrolysis product, although the dihydrolysed species [Ru(eta(6)-p-cymene)(OH)(H(2)O)(PTA)](+) and the dichloro compound are present. Rate constants for the different aquation and anation steps and the equilibrium constants were determined. Hydrolysis is suppressed at high chloride concentrations. These results have important implications on the mode of action of the RAPTA drug candidates.
Journal of Medicinal Chemistry | 2005
Claudine Scolaro; Alberta Bergamo; Laura Brescacin; Riccarda Delfino; Moreno Cocchietto; Gábor Laurenczy; Tilmann J. Geldbach; Gianni Sava; Paul J. Dyson
Applied Organometallic Chemistry | 2005
Claire S. Allardyce; Antoine Dorcier; Claudine Scolaro; Paul J. Dyson
Inorganic Chemistry | 2006
Wee Han Ang; Elisa Daldini; Claudine Scolaro; Rosario Scopelliti; Lucienne Juillerat-Jeannerat; Paul J. Dyson
Journal of Medicinal Chemistry | 2007
Carsten A. Vock; Wee Han Ang; Claudine Scolaro; Andrew D. Phillips; Lucienne Lagopoulos; Lucienne Juillerat-Jeanneret; Gianni Sava; Rosario Scopelliti; Paul J. Dyson
Organometallics | 2006
Claudine Scolaro; Tilmann J. Geldbach; Sébastien Rochat; Antoine Dorcier; Christian Gossens; Alberta Bergamo; Moreno Cocchietto; Ivano Tavernelli; Gianni Sava; Ursula Rothlisberger; Paul J. Dyson
Journal of Medicinal Chemistry | 2006
Carsten A. Vock; Claudine Scolaro; Andrew D. Phillips; Rosario Scopelliti; Gianni Sava; Paul J. Dyson
Dalton Transactions | 2007
Claudine Scolaro; Adrian B. Chaplin; Christian G. Hartinger; Alberta Bergamo; Moreno Cocchietto; Bernhard K. Keppler; Gianni Sava; Paul J. Dyson
European Journal of Inorganic Chemistry | 2005
Barbara Serli; Ennio Zangrando; Teresa Gianferrara; Claudine Scolaro; Paul J. Dyson; Alberta Bergamo; Enzo Alessio
Organometallics | 2008
Barnali Dutta; Claudine Scolaro; Rosario Scopelliti; Paul J. Dyson; Kay Severin