Cristina Dapeña

Arsenic and associated trace-elements in groundwater from the Chaco-Pampean plain, Argentina: results from 100 years of research.

The Chaco-Pampean plain, Argentina, is a vast geographical unit (1,000,000 km²) affected by high arsenic (As) concentrations in universal oxidizing groundwater. The socio-economic development of the region is restricted by water availability and its low quality caused by high salinity and hardness. In addition, high As and associated trace-elements (F, U, V, B, Se, Sb, Mo) concentrations of geogenic origin turn waters unsuitable for human consumption. Shallow groundwater with high As and F concentrations (ranges: <10-5300 μg As/L; 51-7,340 μg F/L) exceeding the WHO guideline values (As: 10 μg/L; F: 1,500 μg/L) introduces a potential risk of hydroarsenicism disease in the entire region and fluorosis in some areas. The rural population is affected (2-8 million inhabitants). Calcareous loess-type sediments and/or intercalated volcanic ash layers in pedosedimentary sequences hosting the aquifers are the sources of contaminant trace-elements. Large intra and interbasin variabilities of trace-element concentrations, especially between shallow and deep aquifers have been observed. All areas of the Chaco-Pampean plain were affected in different grades: the Chaco-Salteña plain (in the NNE of the region) and the northern La Pampa plain (in the center-south) have been shown the highest concentrations. The ranges of As and F contents in loess-sediments are 6-25 and 534-3340 mg/kg, respectively in the Salí River basin. Three key processes render high As concentrations in shallow aquifers: i) volcanic glass dissolution and/or hydrolysis and leaching of silicates minerals hosted in loess; ii) desorption processes from the surface of Al-, Fe- and Mn-oxi-hydroxides (coating lithic fragments) at high pH and mobilization as complex oxyanions (As and trace elements)in Na-bicarbonate type groundwaters; and iii) evaporative concentration in areas with semiarid and arid climates. Local factors play also an important role in the control of high As concentrations, highly influenced by lithology-mineralogy, soils-geomorphology, actual climate and paleoclimates, hydraulic parameters, and residence time of groundwaters.

The role of evapotranspiration in the groundwater hydrochemistry of an arid coastal wetland (Península Valdés, Argentina)

Coastal wetlands are complex hydrogeological systems, in which saline groundwater usually occurs. Salinity can be attributed to many origins, such as dissolution of minerals in the sediments, marine contribution and evapotranspiration, among others. The aim of this paper is to evaluate the processes that condition the hydrochemistry of an arid marsh, Playa Fracasso, located in Patagonia, Argentina. A study of the dynamics and geochemistry of the groundwater was carried out in each hydrogeomorphological unit, using major ion and isotope ((18)O and (2)H) data, soil profiles descriptions and measurements, and recording of water tables in relation to the tidal flow. Water balances and analytical models based on isotope data were used to quantify the evaporation processes and to define the role of evaporation in the chemical composition of water. The results obtained show that the groundwater salinity of the marsh comes mainly from the tidal inflow, to which the halite and gypsum dissolution is added. These mineral facies are the result of the total evaporation of the marine water flooding that occurs mostly at the spring high tides. The isotope relationships in the fan and bajada samples show the occurrence of evaporation processes. Such processes, however, are not mainly responsible for the saline content of groundwater, which is actually generated by the dissolution of the typical evaporite facies of the arid environment sediments. It is concluded that the evapotranspiration processes condition groundwater quality. This is not only due to the saline enrichment caused by the evapotranspiration of shallow water, but also because such processes are the main drivers of the formation of soluble salts, which are then incorporated into the water by groundwater or tidal flow.

Groundwater salinization in arid coastal wetlands: a study case from Playa Fracasso, Patagonia, Argentina

The origin of the high salinity in the groundwater of a coastal wetland in an arid climate was studied in the Playa Fracasso marsh, located on the northwest coast of the extra-Andean Patagonia. Research was carried out by means of the design of a network of soil pits and short piezometers in the marsh and the surrounding landforms. Continuous fluctuations of the water table, in situ physical and chemical properties, major ions (Ca2+, Mg2+, Na+, K+, Cl−, SO42−, HCO3−) and stable isotopes (18O and 2H) in groundwater, as well as soil salinity, were measured. The combined analysis of the hydrodynamics, the ion ratios rCa2+/rCl− and rMg2+/rCa2+ vs. rCl− and the isotopic composition made it possible to recognize an area within the high marsh in which the origin of groundwater is mainly marine and another in which the contributions are of mixed origin. By means of the analysis of rCl− vs. δ18O, a salinization process with no change in isotopic composition was identified. Its interpretation, together with those of the soil salinity profiles and the records of the fluctuations in electrical conductivity associated with extraordinary tides, was used to define a conceptual model of salinization which could be useful to understand other coastal wetlands under similar arid climatic conditions. It consists in a cyclical mechanism of evapotranspiration, precipitation, dissolution and transport of salts during tides.

Assessing Groundwater Age in Confined Aquifers from the Central Pampean Plain of Cordoba, Argentina

In Cordoba Province, Argentina, the population uses groundwater from confined aquifer systems (CASs) for different activities. Therefore, it is necessary to carry out comprehensive studies in order to plan more sustainable use considering that groundwater renewal times can be of several thousands of years. The objective of this research is to evaluate groundwater age in confined aquifers based on hydraulic and isotopic methods. The CASs present variable extension, are multilayered and formed by thin (4–6 m) sand-pebble lenses, and are linked to Neogene fluvial paleosystems. These layers are situated at different depths (120–400 m) and interbedded with thick clay strata. The interpretations made from 2 H, 18 O, and 3 H results and hydraulic calculations suggest that the groundwater is old. Furthermore, an age gradient was observed that increases with depth and flow direction. The 14 C ages obtained for the CASs labeled A2, C, and D were 3.6–1.1 ka BP, 10.8 ka BP, and 46.0–40.5 ka BP, respectively. These results indicate that A2 and C contain groundwater recharged during Holocene cold periods, between the Little Ice Age and the ending of the Holocene Climatic Optimum and during the last glaciation. The D CAS contains paleowater that was recharged during the Pleistocene.

Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment, southeast of Buenos Aires Province, Argentina

High concentrations of fluoride have negative effects on human health, and it is one of the most widespread contaminants in groundwater, having being found in high concentrations in different countries over the entire world. Fluoride concentrations exceeding the drinking water levels are very frequent in the region known as Pampa Plain in Argentina, associated with loess-like sediments bearing volcanic shards and calcium carbonate concretions. In this study, the behavior of fluoride in the catchment of La Ballenera creek is performed to contribute to the understanding of the processes controlling its distribution at catchment scale. The catchment is around 100xa0km2, mostly in a flat landscape, outflowing into the Atlantic Ocean. The concentration of major ions, silica and fluoride was measured on 34 groundwater and 9 surface water samples obtained in October 2013. All the samples, both streamwater and groundwater, were sodium bicarbonate type with an average pH of 8 and 7.3, respectively. The fluoride concentrations in groundwater ranged between 1.1 and 2.5xa0mg/L with an average value of 1.9xa0mg/L. Fluoride concentrations in streamwater were close to groundwater concentrations indicating the predominance of baseflow on surface water composition. The variations in the contents of fluoride are due to two main factors, one geological–geomorphological and the other geochemical. The first one is related to the dominance of loess-like sediments formed by minerals bearing fluoride, and the second one is related to the control resulting on calcite precipitation adsorbing fluoride ions.

Relationship between electrical conductivity, 18 O of water and NO 3 content in different streamflow stages

The Ballenera Creek has 160xa0km2 being a small catchment in the Pampa Plain in Argentina. This area has been deeply modified by human action through agricultural activities. From 2013 to 2017, electrical conductivity, stable isotopes of water and nitrate concentration monitoring program were conducted. The sampling included weekly and bimonthly samples in two sites along the stream, several groundwater wells and monthly precipitation. Chemical and isotopic tracers are used to discriminate the streamflow components and to evaluate their incidence in the nitrate concentration. The easiest conceptual model for gaining streams contemplates two main elements: direct runoff and groundwater (baseflow and pre-event water). The direct runoff has the lowest electrical conductivity and 18Ow variable content. The baseflow component is characterized by the highest electrical conductivity and isotope composition quite constant. Finally, pre-event water has an intermediate electrical conductivity and isotopic content close to the rainfall-weighted average composition. The nitrate concentration obtained was in general related to the different stream stages and was a useful indicator to evaluate the fertilization in agricultural zones.