Daniel Albrecht

The impact of diagenetic fluid–rock reactions on Rotliegend sandstone composition and petrophysical properties (Altmark area, central Germany)

In the framework of the German R&D joint project CLEAN (CO2 large-scale enhanced gas recovery in the Altmark natural gas field), Rotliegend reservoir sandstones of the Altensalzwedel block in the Altmark area (Saxony-Anhalt, central Germany) have been studied to characterise litho- and diagenetic facies, mineral content, geochemical composition, and petrophysical properties. These sands have been deposited in a playa environment dominated by aeolian dunes, dry to wet sand flats and fluvial channel fills. The sediments exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. In sandstones of the damp to wet sandflats, their pristine red colours are preserved and porosity and permeability are only low. Rocks of the aeolian environment and most of the channel fill deposits are preferentially bleached and exhibit moderate to high porosity and permeability. Although geochemical element whole rock content in these rocks is very similar, element correlations are different. Variations in porosity and permeability are mainly due to calcite and anhydrite dissolution and differences in clay coatings with Fe-bearing illitic-chloritic composition exposed to the pore space. Moreover, mineral dissolution patterns as well as compositions (of clays and carbonate) and morphotypes of authigenic minerals (chlorite, illite) are different in red and bleached rocks. Comparison of the geochemical composition and mineralogical features of diagenetically altered sandstones and samples exposed to CO2-bearing fluids in laboratory batch experiments exhibit similar character. Experiments prove an increase in wettability and water binding capacity during CO2 impact.

Influence of added hydrogen on underground gas storage: a review of key issues

The existing infrastructure of the natural gas transportation pipeline network and underground gas storage (UGS) facilities in Germany provides an opportunity and huge capacity to feed, transport and store hydrogen and synthetic fuel gases containing hydrogen, produced from renewable sources. At low hydrogen concentrations, only minor changes to gas transportation equipment will be required. In contrast, the UGS designed in converted gas fields and aquifers are particularly susceptible to the effect of hydrogen. Due to a lack of adequate knowledge about the hydrogen concentration in natural gas, which can be tolerated by the downhole equipment, reservoir and caprocks, the injection of natural gas containing hydrogen in the existing porous UGS is strongly limited. Key issues addressed in this paper are the change in capacity and efficiency of UGS associated with the blending of hydrogen in the stored natural gas, the geological integrity of the reservoir and caprocks, the technical integrity of gas storage wells, durability of the materials used for well completions, corrosion and environmental risks associated with the products of microbial metabolism.

The chemical dissolution and physical migration of minerals induced during CO2 laboratory experiments: their relevance for reservoir quality

The characterization of the quality and storage capacity of geological underground reservoirs is one of the most important and challenging tasks for the realization of carbon capture and storage (CCS) projects. One approach for such an evaluation is the upscaling of data sets achieved by laboratory CO2 batch experiments to field scale. (Sub)-microscopic, petrophysical, tomographic, and chemical analytical methods were applied to reservoir sandstone samples from the Altmark gas field before and after static autoclave batch experiments at reservoir-specific conditions to study the relevance of injected CO2 on reservoir quality. These investigations confirmed that the chemical dissolution of pore-filling mineral phases (carbonate, anhydrite), associated with an increased exposure of clay mineral surfaces and the physical detachment and mobilization of such clay fines (illite, chlorite) are most appropriate to modify the quality of storage sites. Thereby the complex interplay of both processes will affect the porosity and permeability in opposite ways—mineral dissolution will enhance the rock porosity (and permeability), but fine migration can deteriorate the permeability. These reactions are realized down to ~µm scale and will affect the fluid–rock reactivity of the reservoirs, their injectivity and recovery rates during CO2 storage operations.

Investigations on fluid transport properties in the North-German Rotliegend tight gas sandstones and applications

Tight gas reservoirs are an important part of the world gas resources. Such reservoirs have very low permeability (usually below 0.1 mD) and show a strong stress sensitivity to fluid transport properties and a considerable productivity decline during the production process due to increasing effective stress. In an experimental study, several measurement series were performed on plugs from the North-German Rotliegend tight gas reservoirs to improve knowledge and understanding of the effects of changing stress and pore pressure conditions on reservoir rocks, during gas production. In addition to the experimental study, an Interactive Rock Data Catalog (IRDC) has been developed, which contains a database coupled with a correlation module. The database contains metadata of the fields and wellbores included in the IRDC, the corresponding log data and petrophysical data. The correlation module contains correlations derived both from the study measurements and from literature. The results of this study will enable reservoir engineers to select specific data from the database and process it in the correlation module to generate secondary sets of data, which can then be used for modeling and simulation of tight gas reservoirs.

The H2STORE Project: Hydrogen Underground Storage – A Feasible Way in Storing Electrical Power in Geological Media?

The large scale storage of energy is a great challenge arising from the planned transition from nuclear and CO2-emitting power generation to renewable energy production, by e.g. wind, solar, and biomass in Germany. The most promising option for storing large volumes of excess energy produced by such renewable sources is the usage of underground porous rock formations as energy reservoirs. Some new technologies are able to convert large amounts of electrical energy into a chemical form, for example into hydrogen by means of water electrolysis. Porous formations can potentially provide very high hydrogen storage capacities. Several methods have to be studied including high hydrogen diffusivity, the potential reactions of injected hydrogen, formation fluids, rock composition, and the storage complex.

Evaluation of Geo-processes

A holistic understanding of the physicochemical processes induced by CO2 injection and storage in a reservoir is based on a geoscientific characterisation of the overall geological system consisting of reservoir rocks and cap rocks. It requires in a first step a comprehensive baseline characterisation (sedimentological, mineralogical, geochemical, mechanical, etc.) of pertinent parameters and conditions. To properly handle the large amount of different geoscientific information a Data Management System (DMS) was developed, which proved indispensable to conduct such a multi-disciplinary project. The DMS provides a tool for scientific process management, data analysis, integration and visualisation, data transfer and scheduling through specialised database systems and retrieval techniques, storage technology, and efficient data access.

Thin-film calorimetry: In-situ characterization of materials for lithium-ion batteries

Abstract Thin-film calorimetry allows for qualitative and quantitative in-situ analysis of thermodynamic properties of thin films and thin-film systems from room temperature up to 1000 °C. It is based on highly sensitive piezoelectric langasite resonators which serve simultaneously as planar temperature sensors and substrates for the films of interest. Generation or consumption of heat during phase transformations of the films cause deviations from the regular course of the resonance frequency. Thermodynamic data such as phase transformation temperatures and enthalpies are extracted from these deviations. Thin-film calorimetry on Sn and Al thin films is performed to prove the concept. The results demonstrate high reproducibility of the measurement approach and are in agreement with literature data obtained by established calorimetric techniques. The calibration of the system is done in different atmospheres by application of defined heat pulses via heating structures. The latter replace the films of interest and simulate phase transformations to provide detailed analysis of the heat transfer mechanisms occurring in the measurement system. Based on this analysis, a data evaluation concept is developed. Application-relevant studies are performed on thin films of the lithium-ion battery materials NMC(A), NCA, LMO, and MoS2. Their phase transformation temperatures and enthalpies are evaluated in oxidizing and reducing atmospheres. Furthermore, their thermodynamic stability ranges are presented. Finally, measurements on all-solid-state thin-film batteries during electrochemical cycling are performed. They demonstrate the suitability of the system for in-situ investigations.