Viktor Reitenbach

Modelling CO2-induced fluid–rock interactions in the Altensalzwedel gas reservoir. Part I: from experimental data to a reference geochemical model

Modelling fluid–rock interactions induced by CO2 is a key issue when evaluating the technical feasibility and long-term safety assessment of CO2 storage projects in deep formations. The German R&D programme CLEAN (CO2 Large-Scale Enhanced Gas Recovery in the Altmark Natural Gas Field) investigated the almost depleted onshore gas reservoir located in the Rotliegend sandstone at over 3,000-m depth. The high salinity of the formation fluids and the elevated temperature in the reservoir exceed the validity limits of commonly available thermodynamic databases needed for predictive geochemical modelling. In particular, it is shown that the activity model of Pitzer has to be applied, even if necessary input data for this model are incomplete or inconsistent for complex systems and for the considered temperatures. Simulations based on Debye-Hückel activity model lead to severe, systematic discrepancies already in the simple proposed reference case where experimental data could be used for comparison. A simplified geochemical model, consistent with the average measured composition of formation fluids and the prevailing mineralogical assemblage of the host rock, identifies the mineral phases most likely to be considered at equilibrium with the formation fluid. The simulated reactions due to CO2 injection, under the hypothesis of local thermodynamical equilibrium, result in a moderate reactivity of the system, with the dissolution of anhydrite cementation and haematite being the most relevant expected mineral reactions. This is compensated, at equilibrium, by the precipitation of new carbonates, like calcite and siderite, for an overall very small loss of porous space. The simulated rather small effect of mineral alteration is also due to the scarce amount of water available for reactions in the reservoir. The results of the model are qualitatively in line with observations from batch experiments and from natural analogues.

The impact of diagenetic fluid–rock reactions on Rotliegend sandstone composition and petrophysical properties (Altmark area, central Germany)

In the framework of the German R&D joint project CLEAN (CO2 large-scale enhanced gas recovery in the Altmark natural gas field), Rotliegend reservoir sandstones of the Altensalzwedel block in the Altmark area (Saxony-Anhalt, central Germany) have been studied to characterise litho- and diagenetic facies, mineral content, geochemical composition, and petrophysical properties. These sands have been deposited in a playa environment dominated by aeolian dunes, dry to wet sand flats and fluvial channel fills. The sediments exhibit distinct mineralogical, geochemical, and petrophysical features related to litho- and diagenetic facies types. In sandstones of the damp to wet sandflats, their pristine red colours are preserved and porosity and permeability are only low. Rocks of the aeolian environment and most of the channel fill deposits are preferentially bleached and exhibit moderate to high porosity and permeability. Although geochemical element whole rock content in these rocks is very similar, element correlations are different. Variations in porosity and permeability are mainly due to calcite and anhydrite dissolution and differences in clay coatings with Fe-bearing illitic-chloritic composition exposed to the pore space. Moreover, mineral dissolution patterns as well as compositions (of clays and carbonate) and morphotypes of authigenic minerals (chlorite, illite) are different in red and bleached rocks. Comparison of the geochemical composition and mineralogical features of diagenetically altered sandstones and samples exposed to CO2-bearing fluids in laboratory batch experiments exhibit similar character. Experiments prove an increase in wettability and water binding capacity during CO2 impact.

Influence of added hydrogen on underground gas storage: a review of key issues

The existing infrastructure of the natural gas transportation pipeline network and underground gas storage (UGS) facilities in Germany provides an opportunity and huge capacity to feed, transport and store hydrogen and synthetic fuel gases containing hydrogen, produced from renewable sources. At low hydrogen concentrations, only minor changes to gas transportation equipment will be required. In contrast, the UGS designed in converted gas fields and aquifers are particularly susceptible to the effect of hydrogen. Due to a lack of adequate knowledge about the hydrogen concentration in natural gas, which can be tolerated by the downhole equipment, reservoir and caprocks, the injection of natural gas containing hydrogen in the existing porous UGS is strongly limited. Key issues addressed in this paper are the change in capacity and efficiency of UGS associated with the blending of hydrogen in the stored natural gas, the geological integrity of the reservoir and caprocks, the technical integrity of gas storage wells, durability of the materials used for well completions, corrosion and environmental risks associated with the products of microbial metabolism.

The chemical dissolution and physical migration of minerals induced during CO2 laboratory experiments: their relevance for reservoir quality

The characterization of the quality and storage capacity of geological underground reservoirs is one of the most important and challenging tasks for the realization of carbon capture and storage (CCS) projects. One approach for such an evaluation is the upscaling of data sets achieved by laboratory CO2 batch experiments to field scale. (Sub)-microscopic, petrophysical, tomographic, and chemical analytical methods were applied to reservoir sandstone samples from the Altmark gas field before and after static autoclave batch experiments at reservoir-specific conditions to study the relevance of injected CO2 on reservoir quality. These investigations confirmed that the chemical dissolution of pore-filling mineral phases (carbonate, anhydrite), associated with an increased exposure of clay mineral surfaces and the physical detachment and mobilization of such clay fines (illite, chlorite) are most appropriate to modify the quality of storage sites. Thereby the complex interplay of both processes will affect the porosity and permeability in opposite ways—mineral dissolution will enhance the rock porosity (and permeability), but fine migration can deteriorate the permeability. These reactions are realized down to ~µm scale and will affect the fluid–rock reactivity of the reservoirs, their injectivity and recovery rates during CO2 storage operations.

Hydrogenization of underground storage of natural gas

The intermittent production of the renewable energy imposes the necessity to temporarily store it. Large amounts of exceeding electricity can be stored in geological strata in the form of hydrogen. The conversion of hydrogen to electricity and vice versa can be performed in electrolyzers and fuel elements by chemical methods. The nowadays technical solution accepted by the European industry consists of injecting small concentrations of hydrogen in the existing storages of natural gas. The progressive development of this technology will finally lead to the creation of underground storages of pure hydrogen. Due to the low viscosity and low density of hydrogen, it is expected that the problem of an unstable displacement, including viscous fingering and gravity overriding, will be more pronounced. Additionally, the injection of hydrogen in geological strata could encounter chemical reactivity induced by various species of microorganisms that consume hydrogen for their metabolism. One of the products of such reactions is methane, produced from Sabatier reaction between H2 and CO2. Other hydrogenotrophic reactions could be caused by acetogenic archaea, sulfate-reducing bacteria and iron-reducing bacteria. In the present paper, a mathematical model is presented which is capable to reflect the coupled hydrodynamic and bio-chemical processes in UHS. The model has been numerically implemented by using the open source code DuMuX developed by the University of Stuttgart. The obtained bio-chemical version of DuMuX was used to model the evolution of a hypothetical underground storage of hydrogen. We have revealed that the behavior of an underground hydrogen storage is different than that of a natural gas storage. Both, the hydrodynamic and the bio-chemical effects, contribute to the different characteristics.

Investigations on fluid transport properties in the North-German Rotliegend tight gas sandstones and applications

Tight gas reservoirs are an important part of the world gas resources. Such reservoirs have very low permeability (usually below 0.1 mD) and show a strong stress sensitivity to fluid transport properties and a considerable productivity decline during the production process due to increasing effective stress. In an experimental study, several measurement series were performed on plugs from the North-German Rotliegend tight gas reservoirs to improve knowledge and understanding of the effects of changing stress and pore pressure conditions on reservoir rocks, during gas production. In addition to the experimental study, an Interactive Rock Data Catalog (IRDC) has been developed, which contains a database coupled with a correlation module. The database contains metadata of the fields and wellbores included in the IRDC, the corresponding log data and petrophysical data. The correlation module contains correlations derived both from the study measurements and from literature. The results of this study will enable reservoir engineers to select specific data from the database and process it in the correlation module to generate secondary sets of data, which can then be used for modeling and simulation of tight gas reservoirs.

The H2STORE Project: Hydrogen Underground Storage – A Feasible Way in Storing Electrical Power in Geological Media?

The large scale storage of energy is a great challenge arising from the planned transition from nuclear and CO2-emitting power generation to renewable energy production, by e.g. wind, solar, and biomass in Germany. The most promising option for storing large volumes of excess energy produced by such renewable sources is the usage of underground porous rock formations as energy reservoirs. Some new technologies are able to convert large amounts of electrical energy into a chemical form, for example into hydrogen by means of water electrolysis. Porous formations can potentially provide very high hydrogen storage capacities. Several methods have to be studied including high hydrogen diffusivity, the potential reactions of injected hydrogen, formation fluids, rock composition, and the storage complex.

Evaluation of Geo-processes

A holistic understanding of the physicochemical processes induced by CO2 injection and storage in a reservoir is based on a geoscientific characterisation of the overall geological system consisting of reservoir rocks and cap rocks. It requires in a first step a comprehensive baseline characterisation (sedimentological, mineralogical, geochemical, mechanical, etc.) of pertinent parameters and conditions. To properly handle the large amount of different geoscientific information a Data Management System (DMS) was developed, which proved indispensable to conduct such a multi-disciplinary project. The DMS provides a tool for scientific process management, data analysis, integration and visualisation, data transfer and scheduling through specialised database systems and retrieval techniques, storage technology, and efficient data access.