Daniel Charles Ziskin

Satellite-observed pollution from Southern Hemisphere biomass burning.

Biomass burning is a major source of pollution in the tropical Southern Hemisphere, and fine mode carbonaceous particles are produced by the same combustion processes that emit carbon monoxide (CO). In this paper we examine these emissions with data from the Terra satellite, CO profiles from the Measurement of Pollution in the Troposphere (MOPITT) instrument, and fine-mode aerosol optical depth (AOD) from the Moderate-Resolution Imaging Spectroradiometer (MODIS). The satellite measurements are used in conjunction with calculations from the MOZART chemical transport model to examine the 2003 Southern Hemisphere burning season with particular emphasis on the months of peak fire activity in September and October. Pollutant emissions follow the occurrence of dry season fires, and the temporal variation and spatial distributions of MOPITT CO and MODIS AOD are similar. We examine the outflow from Africa and South America with emphasis on the impact of these emissions on clean remote regions. We present comparisons of MOPITT observations and ground-based interferometer data from Lauder, New Zealand, which indicate that intercontinental transport of biomass burning pollution from Africa often determines the local air quality. The correlation between enhancements of AOD and CO column for distinct biomass burning plumes is very good with correlation coefficients greater than 0.8. We present a method using MOPITT and MODIS data for estimating the emission ratio of aerosol number density to CO concentration which could prove useful as input to modeling studies. We also investigate decay of plumes from African fires following export into the Indian Ocean and compare the MOPITT and MODIS measurements as a way of estimating the regional aerosol lifetime. Vertical transport of biomass burning emissions is also examined using CO profile information. Low-altitude concentrations are very high close to source regions, but further downwind of the continents, vertical mixing takes place and results in more even CO vertical distributions. In regions of significant convection, particularly in the equatorial Indian Ocean, the CO mixing ratio is greater at higher altitudes, indicating vertical transport of biomass burning emissions to the upper troposphere.

Cloud detection and clearing for the Earth Observing System Terra satellite Measurements of Pollution in the Troposphere (MOPITT) experiment

The Measurements of Pollution in the Troposphere (MOPITT) instrument, which was launched aboard the Earth Observing System (EOS) Terra spacecraft on 18 December 1999, is designed to measure tropospheric CO and CH(4) by use of a nadir-viewing geometry. The measurements are taken at 4.7 mum in the thermal emission and absorption for the CO mixing ratio profile retrieval and at 2.3 and 2.2 mum in the reflected solar region for the total CO column amount and CH(4) column amount retrieval, respectively. To achieve the required measurement accuracy, it is critical to identify and remove cloud contamination in the radiometric signals. We describe an algorithm to detect cloudy pixels, to reconstruct clear column radiance for pixels with partial cloud covers, and to estimate equivalent cloud top height for overcast conditions to allow CO profile retrievals above clouds. The MOPITT channel radiances, as well as the first-guess calculations, are simulated with a fast forward model with input atmospheric profiles from ancillary data sets. The precision of the retrieved CO profiles and total column amounts in cloudy atmospheres is within the expected ?10% range. Validations of the cloud-detecting thresholds with the moderate-resolution imaging spectroradiometer airborne simulator data and MOPITT airborne test radiometer measurements were performed. The validation results showed that the MOPITT cloud detection thresholds work well for scenes covered with more than 5-10% cloud cover if the uncertainties in the model input profiles are less than 2 K for temperature, 10% for water vapor, and 5% for CO and CH(4).

Effects of a Spectral Surface Reflectance on Measurements of Backscattered Solar Radiation: Application to the MOPITT Methane Retrieval

Abstract The amount of solar radiation emerging from the top of the atmosphere is strongly influenced by the reflectance of the underlying surface. For this reason, some information about the magnitude and the spectral variability of the surface reflectance typically has to be included in the retrieval of atmospheric parameters from reflected solar radiation measurements. Sufficient information about the surface reflectance properties is rarely available, and the integration of this effect in the retrieval might turn out to be a challenge, especially for broadband instruments. In this paper the focus is on the Measurements of Pollution in the Troposphere (MOPITT) remote sensing instrument. Theoretical studies are performed to investigate how a spectrally varying surface reflectance might impact the retrieval of the total column amount of methane from MOPITT radiance measurements, and the current findings are compared to observed biases. However, the findings present herein might be valuable and applicable...

Validation of MOPITT retrievals of carbon monoxide

Validation of the MOPITT retrievals of carbon monoxide (CO) has been performed with a varied set of correlative data. These include in situ observations from a regular program of aircraft observations at five sites. Additional in situ profiles are available from several short-term research campaigns. These in situ profiles are critical for the validation of the retrieved CO mixing ratio profiles from MOPITT. Ground-based spectroscopic measurements are compared to MOPITT CO total column densities to validate the observed seasonal cycles. The current validation results indicate good quantitative agreement between MOPITT and in situ profiles, with an average bias less than 20 ppbv. The same seasonal cycles are see in MOPITT and the ground-based spectroscopic data. These validation comparisons provide critical assessments of the retrievals, and continuing improvements to the retrieval algorithms are reducing the validation biases.

EOS MOPITT experiment: extracting the information from the measurements

This paper will serve as an overview of the challenges to the recovery of information on atmospheric CO and CH4 from the measurements made by the MOPITT instrument that has been described by Drummond et al. It will also provide a context and introduction to several of the following papers that go into greater detail on particular topics, and outline plans for the data processing. Here we briefly outline the principles of correlation radiometry as used by MOPITT, and introduce the principles behind the retrievals. After noting plans for data processing, we discuss our approach to data validation, and the ability to see global distributions of CO in the MOPITT data.

Improvement of the global surface emissivity from MOPITT measurements and its impacts on the retrievals of tropospheric carbon monoxide profiles

Carbon monoxide (CO) is an important tropospheric trace species and can serve as a useful tracer of atmospheric transport. The Measurements of Pollution In The Troposphere (MOPITT) instrument uses the 4.7 μm CO band to measure the spatial and temporal variation of the CO profile and total column amount in the troposphere from space. Launched in 1999 on board the NASA Terra satellite, the MOPITT views the earth with a pixel size 22 km by 22 km and a cross-track swath that measures a near-global distribution of CO every 3 days. In the operational MOPITT CO retrieval algorithm (V3; Version 3), surface skin temperature (Ts) and emissivity (E) are retrieved simultaneously with the CO profile. The accuracy of E and Ts is crucial for obtaining the CO retrieval within the 10% accuracy from the MOPITT measurements. However, because both Ts and E are retrieved from the same piece of information from the MOPITT measurements, the accuracy of both valuables may be limited. Extra surface skin temperature information is needed to determine surface emissivity, and vice versa. In this study, we use MODIS Ts within the MOPITT FOVs, in conjunction with those MOPITT signals most sensitive to the background scene, to compute the surface emissivity through an iterative retrieval algorithm. A monthly 1degree grid averaged 4.7 μm surface emissivity map is generated. The evaluation of the accuracy of this monthly 1 degree grid averaged 4.7 μm surface emissivity map is presented and its impacts on the retrievals of tropospheric CO profiles from the MOPITT measurements are also discussed.

Carbon monoxide total column retrievals by use of the measurements of pollution in the troposphere airborne test radiometer

The Measurements of Pollution in the Troposphere (MOPITT) Airborne Test Radiometer (MATR) uses gas correlation filter radiometry from high-altitude aircraft to measure tropospheric carbon monoxide. This radiometer is used in support of the ongoing validation campaign for the MOPITT instrument aboard the Earth Observation System Terra satellite. A recent study of MATR CO retrievals that used data from the autumn of 2001 in the western United States is presented. Retrievals of the CO total column were performed and compared to in situ sampling with less than 10% retrieval error. Effects that influence retrieval, such as instrument sensitivity, retrieval sensitivity, and the bias between observations and the radiative transfer model, are discussed. Comparisons of MATR and MOPITT retrievals show promising consistency. A preliminary interpretation of MATR results is also presented.

Retrieval of surface skin temperature from MOPITT measurements: validation and impacts to the retrievals of tropospheric carbon monoxide profiles

The Measurements Of Pollution In The Troposphere (MOPITT) instrument is designed to measure the spatial and temporal variation of the carbon monoxide (CO) profile and total column amount in the troposphere from space. MOPITT channels are sensitive to both thermal emission from the surface and target gas absorption and emission. Surface temperature and emissivity are retrieved simultaneously with the CO profile. To obtain the desired precision for the retrieved CO profiles, it is important to retrieve the surface skin temperature accurately and understand the effects of any errors in retrieved skin temperature on retrieved CO. To demonstrate the impacts of surface skin temperature on the retrieval of the tropospheric CO profile, a simulation study is performed. The collocated Moderate Resolution Imaging Spectroradiometer (MODIS) surface temperatures are used to validate the accuracy of the retrieved MOPITT surface temperatures.

Validation of the retrieval of surface skin temperature and surface emissivity from MOPITT measurements and their impacts on the retrieval of tropospheric carbon monoxide profiles

The Measurements of Pollution In The Troposphere (MOPITT) instrument is designed to measure the spatial and temporal variation of the carbon monoxide (CO) profile and total column amount in the troposphere from the space. MOPITT channels are sensitive to both thermal emission from the surface and target gas absorption and emission. Surface temperature and emissivity are retrieved simultaneously with the CO profile. To obtain the desired 10% precision for the retrieved CO from MOPITT measurements, it is important to understand MOPITT CO channel sensitivity to surface temperature and emissivity and the impacts of the effects of any errors in retrieved skin temperature and emissivity on retrieved CO for various underlying surfaces. To demonstrate the impacts of the surface temperature and emissivity on the retrieval of the tropospheric CO profile, simulation studies are performed. The collocated Moderate Resolution Imaging Spectroradiometer (MODIS) surface products are used to assess the accuracy of the retrieved MOPITT surface temperature and emissivity.

MATR thermal channel analysis and results for autumn 2001 campaign

The MOPITT (Measurements of Pollution in the Troposphere) Airborne Test Radiometer (MATR) uses gas filter correlation radiometry from high altitude aircraft to measure tropospheric carbon monoxide. This is in support of the ongoing validation campaign for the MOPITT instrument on board the Tera Satellite. This paper reports on a recent study of MATR CO retrievals using observations of thermal radiation during the autumn of 2001 in western United States. Retrievals of CO were performed and compared to in-situ sampling with less than 7% retrieval error relative to the in-situ total column amount. The effects that influence the retrieval such as the instrument sensitivity, the retrieval sensitivity, and bias between observations and the radiation model are discussed.