Daniel Janczak

A Broadband Absorber With a Resistive Pattern Made of Ink With Graphene Nano-Platelets

A novel type of a broadband flexible electromagnetic absorbing panel made of a resistive pattern printed on a dielectric spacer backed by a conducting surface is investigated in this paper. It is shown that an appropriate choice of the shape and sheet resistance of the pattern allows extending an absorption spectrum up to an octave and beyond, which is very competitive over alternative solutions. The pattern is made of ink with graphene nano-platelets, which allows achieving expected sheet resistance with decent repeatability, what is confirmed with measurements undertaken with the DC point probe and microwave dielectric resonator techniques. An exemplary sample of the proposed absorber is manufactured and characterized, indicating a very good agreement between theoretical study and experiments.

Electroluminescent structures printed on paper and textile elastic substrates

Purpose – New types of substrates were used for fabrication of printed electroluminescent structures. Polymer foils mainly used as substrates for such optoelectronic elements were replaced with paper and textiles. Printing on non-transparent substrate requires elaboration of printed transparent electrode, while usually polyester foils with sputtered ITO transparent electrodes are used. The paper aims to discuss these issues. Design/methodology/approach – Electroluminescent structures were fabricated with elaborated polymer compositions filled with nanomaterials, such as carbon nanotubes and graphene platelets, dielectric and luminophore nanopowders. Structures were printed as “reverse stack”, where transparent electrode is printed on top of the last luminophore layer. For that carbon nanotubes and graphene platelets filled composition was used, deposited with spray-coating technique. Findings – Main issue with new substrates is proper wetting with the use of screen-printing pastes, and much higher roughne...

Transparent electrodes with nanotubes and graphene for printed optoelectronic applications

We report here on printed electroluminescent structures containing transparent electrodes made of carbon nanotubes and graphene nanoplatelets. Screen-printing and spray-coating techniques were employed. Electrodes and structures were examined towards optical parameters using spectrophotometer and irradiation meter. Electromechanical properties of transparent electrodes are exterminated with cyclical bending test. Accelerated aging process was conducted according to EN 62137 standard for reliability tests of electronics. We observed significant negative influence of mechanical bending on sheet resistivity of ITO, while resistivity of nanotube and graphene based electrodes remained stable. Aging process has also negative influence on ITO based structures resulting in delamination of printed layers, while those based on carbon nanomaterials remained intact. We observe negligible changes in irradiation for structures with carbon nanotube electrodes after accelerated aging process. Such materials demonstrate a high application potential in general purpose electroluminescent devices.

Graphene-Based Dipole Antenna for a UHF RFID Tag

This paper describes design and measurements of RFID tag built of a graphene-based dipole antenna and a chip operating in the UHF band in accordance with the EPC Global Class 1 Gen. 2 standard. Several tags have been constructed and tested with a standard RFID reader to reveal that each one is fully operational, but the interrogation range for the graphene-based circuits has been limited in comparison to copper antennae. This can be attributed to increased sheet resistance of a graphene layer. However, it seems that for applications were the read range is not crucial the novel antenna can be an alternative to more expensive circuits printed with silver-based inks.

Thick Film Polymer Composites with Graphene Nanoplatelets for Use in Printed Electronics

The paper presents the results of the investigation into layers based on graphene nanoplatelets in polymer resin. Several types of polymer composition with different amount of GNP’s were prepared by modified mixing process used in thick film material preparation. The composite structure was observed under a scanning electron microscope and atomic force microscope. Electoral and mechanical properties of screen printed layers on flexible PET foil were checked. Banding tests show good adhesion to polymer substrate and proved that GNP’s are good for reinforcing or as a conductive additive in composite materials.

Graphene-based dipole antenna for a UHF RFID tag

This paper describes the design and measurements of a remote frequency identification (RFID) tag built of a graphene-based dipole antenna and a chip operating in the ultrahigh-frequency (UHF) band in accordance with the EPC Global Class 1 Gen. 2 standard. A custom-designed antenna has been designed first. Then, it was used to construct several tags that have been tested with a standard RFID reader to reveal that each one is fully operational, although the interrogation range for the graphene-based circuits has been limited in comparison to copper antennas. This can be attributed to increased sheet resistance of a graphene layer and-in the case of tags fabricated on paper-also to significant dielectric losses of the substrate material. However, it seems that for applications where the interrogation range is not crucial the novel antenna can be an alternative to much more expensive circuits printed with silver-based inks.

Screen printed, transparent, and flexible electrodes based on graphene nanoplatelet pastes

Transparent, flexible and conducting graphene films were produced by screen printing method using printing pastes based on graphene nanoplatelets in polymer matrix. The transparency of received layers and the mechanical resistivity in several bending cycles were measured. Subsequently percolation threshold was investigated. Graphene layers were printed on diverse substrates (glass, Al2O3, PET) and afterwards for samples printed on glass different firing atmospheres (N2, H2, air) were studied. Best firing results (resistance decrease) were obtained for treatment in 250 °C in atmosphere of air. Finally investigation results were used to produce a transparent and elastic electrode for an electroluminescent display, showing the application potential of our graphene nanocomposite pastes.

Investigations of Printed Flexible pH Sensing Materials Based on Graphene Platelets and Submicron RuO 2 Powders

The paper describes the investigations of pH-sensitive materials for screen printed flexible pH sensors. The sensors were fully printed and consisted of three layers, conductive made of low temperature-curable silver paste, insulating made of UV-curable dielectric paste, and pH-sensitive made of developed graphene/ruthenium oxide pastes. Graphene and ruthenium oxide composites were prepared with different proportions of graphene nanoplatelets paste and submicron ruthenium dioxide. To perform functional measurements, particular testing sensors were fabricated on flexible polyester foil. Afterwards electrochemical potential measurements of fabricated devices were carried out. Sensors were also exposed to cyclic bending and the change of pH sensitivity before and after bending was described. Eventually, percolation threshold concerning the amount of ruthenium oxide in the pH-sensitive layer was designated and UV influence on the sensitivity was observed that together allow for optimization of sensors’ fabrication costs.

Electric Properties of Graphene-Based Conductive Layers from DC Up To Terahertz Range

This paper describes results obtained using a hybrid measurement methodology employed to investigate electric properties of thin conductive layers based on graphene nanoplatelets in the frequency band spanning from dc up to terahertz range. As many as four different measurement methods were employed to cover the band of interest, including the terahertz time-domain spectroscopy and the Fourier-transform infrared spectroscopy besides resonator techniques applicable in the microwave band and the four-point dc technique. Raw measurement data obtained using these approaches were processed and based on the results a relationship between frequency and sheet resistance for various types of new graphene-based conductive layers was extracted. Eventually, several models that help to explain the observed behavior of each of the analyzed conductive inks were proposed.

Stabilization of glucose-oxidase in the graphene paste for screen-printed glucose biosensor

Various methods and materials for enzyme stabilization within screen-printed graphene sensor were analyzed. Main goal was to develop technology allowing immediate printing of the biosensors in single printing process. Factors being considered were: toxicity of the materials used, ability of the material to be screen-printed (squeezed through the printing mesh) and temperatures required in the fabrication process. Performance of the examined sensors was measured using chemical amperometry method, then appropriate analysis of the measurements was conducted. The analysis results were then compared with the medical requirements. Parameters calculated were: correlation coefficient between concentration of the analyte and the measured electrical current (0.986) and variation coefficient for the particular concentrations of the analyte used as the calibration points. Variation of the measured values was significant only in ranges close to 0, decreasing for the concentrations of clinical importance. These outcomes justify further development of the graphene-based biosensors fabricated through printing techniques.