Grzegorz Wroblewski

Electroluminescent structures printed on paper and textile elastic substrates

Purpose – New types of substrates were used for fabrication of printed electroluminescent structures. Polymer foils mainly used as substrates for such optoelectronic elements were replaced with paper and textiles. Printing on non-transparent substrate requires elaboration of printed transparent electrode, while usually polyester foils with sputtered ITO transparent electrodes are used. The paper aims to discuss these issues. Design/methodology/approach – Electroluminescent structures were fabricated with elaborated polymer compositions filled with nanomaterials, such as carbon nanotubes and graphene platelets, dielectric and luminophore nanopowders. Structures were printed as “reverse stack”, where transparent electrode is printed on top of the last luminophore layer. For that carbon nanotubes and graphene platelets filled composition was used, deposited with spray-coating technique. Findings – Main issue with new substrates is proper wetting with the use of screen-printing pastes, and much higher roughne...

Transparent electrodes with nanotubes and graphene for printed optoelectronic applications

We report here on printed electroluminescent structures containing transparent electrodes made of carbon nanotubes and graphene nanoplatelets. Screen-printing and spray-coating techniques were employed. Electrodes and structures were examined towards optical parameters using spectrophotometer and irradiation meter. Electromechanical properties of transparent electrodes are exterminated with cyclical bending test. Accelerated aging process was conducted according to EN 62137 standard for reliability tests of electronics. We observed significant negative influence of mechanical bending on sheet resistivity of ITO, while resistivity of nanotube and graphene based electrodes remained stable. Aging process has also negative influence on ITO based structures resulting in delamination of printed layers, while those based on carbon nanomaterials remained intact. We observe negligible changes in irradiation for structures with carbon nanotube electrodes after accelerated aging process. Such materials demonstrate a high application potential in general purpose electroluminescent devices.

Thick Film Polymer Composites with Graphene Nanoplatelets for Use in Printed Electronics

The paper presents the results of the investigation into layers based on graphene nanoplatelets in polymer resin. Several types of polymer composition with different amount of GNP’s were prepared by modified mixing process used in thick film material preparation. The composite structure was observed under a scanning electron microscope and atomic force microscope. Electoral and mechanical properties of screen printed layers on flexible PET foil were checked. Banding tests show good adhesion to polymer substrate and proved that GNP’s are good for reinforcing or as a conductive additive in composite materials.

Screen printed, transparent, and flexible electrodes based on graphene nanoplatelet pastes

Transparent, flexible and conducting graphene films were produced by screen printing method using printing pastes based on graphene nanoplatelets in polymer matrix. The transparency of received layers and the mechanical resistivity in several bending cycles were measured. Subsequently percolation threshold was investigated. Graphene layers were printed on diverse substrates (glass, Al2O3, PET) and afterwards for samples printed on glass different firing atmospheres (N2, H2, air) were studied. Best firing results (resistance decrease) were obtained for treatment in 250 °C in atmosphere of air. Finally investigation results were used to produce a transparent and elastic electrode for an electroluminescent display, showing the application potential of our graphene nanocomposite pastes.

Investigations of Printed Flexible pH Sensing Materials Based on Graphene Platelets and Submicron RuO 2 Powders

The paper describes the investigations of pH-sensitive materials for screen printed flexible pH sensors. The sensors were fully printed and consisted of three layers, conductive made of low temperature-curable silver paste, insulating made of UV-curable dielectric paste, and pH-sensitive made of developed graphene/ruthenium oxide pastes. Graphene and ruthenium oxide composites were prepared with different proportions of graphene nanoplatelets paste and submicron ruthenium dioxide. To perform functional measurements, particular testing sensors were fabricated on flexible polyester foil. Afterwards electrochemical potential measurements of fabricated devices were carried out. Sensors were also exposed to cyclic bending and the change of pH sensitivity before and after bending was described. Eventually, percolation threshold concerning the amount of ruthenium oxide in the pH-sensitive layer was designated and UV influence on the sensitivity was observed that together allow for optimization of sensors’ fabrication costs.

Graphene platelets as morphology tailoring additive in carbon nanotube transparent and flexible electrodes for heating applications

Flexible and transparent electrodes were fabricated with spray coating technique from paints based on multiwalled carbon nanotubes with the addition of graphene platelets. The work presents the influence of graphene platelets on the paints rheology and layers morphology, which has a strong connection to the electrooptical parameters of the electrodes. The paints rheology affects the atomization during spray coating and later the leveling of the coating on the substrate. Both technological aspects shape the morphology of the electrode and the distribution of nanoparticles in the coating. All these factors influence the sheet resistance and roughness, which is linked to the optical transmission and absorbance. In our research the electrode was applied as a transparent and elastic heating element with 68% optical transmission at 550 nm wavelength and 8.4 kΩ/• sheet resistance. The elastic heating element was tested with a thermal camera at the 3 diverse supply voltages -20, 30, and 60 VDC. The test successfully confirmed and supported our proposed uses of elaborated electrodes.

Structural and Optical Properties of Spray Coated Carbon Hybrid Materials Applied to Transparent and Flexible Electrodes

Transparent and flexible electrodes were fabricated with cost-effective spray coating technique on polyethylene terephthalate foil substrates. Particularly designed paint compositions contained mixtures of multiwalled carbon nanotubes and graphene platelets to achieve their desired rheology and electrooptical layers parameters. Electrodes were prepared in standard technological conditions without the need of clean rooms or high temperature processing. The sheet resistance and optical transmittance of fabricated layers were tuned with the number of coatings; then the most suitable relation of these parameters was designated through the figure of merit. Optical measurements were performed in the range of wavelengths from 250 to 2500 nm with a spectrophotometer with the integration sphere. Spectral dependence of total and diffusive optical transmission for thin films with graphene platelet covered by multiwalled carbon nanotubes was designated which allowed determining the relative absorbance. Layer parameters such as thickness, refractive index, energy gap, and effective reflectance coefficient show the correlation of electrooptical properties with the technological conditions. Moreover the structural properties of fabricated layers were examined by means of the X-ray diffraction.

The influence of graphene screen printing paste's composition on its viscosity

In the thick film technology it is very important that paste can be printed easily on the substrate and that printed pattern is correct and precise. Paste printing behavior is characterized by its rheology. The main aim of this work was to examine the influence of paste composition on the rheology of pastes containing graphene nanoplatelts. The secondary aim was to find the optimal composition of the pastes. The resulting measurements graphs of viscosity curves shows the influence of: binder type, functional phase content, dispersant type and content on the rheological properties of polymer pastes. The thicknesses of printed layers, obtained from pastes which characterized by various viscosity, were measured. At the end composition of the pastes with graphene nanoplatelets that exhibit the best rheological properties was described.

Carbon nanomaterials dedicated to heating systems

Purpose – The paper aims to present the research results related to transparent heating elements made from carbon nanomaterials. Heating elements were fabricated only with cost-effective techniques with the aim to be easily implemented in large area applications. Presented materials and methods are an interesting alternative to vacuum deposition of transparent resistive layers and etching of low-resistive patterns. Fabricated heating elements were designed to be used as de-icing structures in roof-top windows. Design/methodology/approach – The paper presents the research results related to transparent heating elements made from carbon nanomaterials. Heating elements were fabricated only with cost-effective techniques with the aim to be easily implemented in large area applications. Presented materials and methods are an interesting alternative to vacuum deposition of transparent resistive layers and etching of low-resistive patterns. Fabricated heating elements were designed to be used as de-icing structu...

Influence of electric field on separation and orientation of carbon nanotubes in spray coated layers

Purpose – The aims of this paper are to investigate the influence of direct current (DC) electric field on separation and orientation of carbon nanotubes (CNTs) in spray-coated layers and apply this method to the fabrication of elastic and transparent electrodes. The orientation of CNTs in the form of paths in the direction of electrical conduction should increase the electrode conductivity without decreasing its optical transmission. Design/methodology/approach – Materials are deposited using vacuum-free, ultra-fine nozzle spray coating technique, easily applicable for large-scale production. After the deposition of carbon nanomaterials, nanoparticles are oriented in the electric field and initially cured with infrared halogen lamp to evaporate solvents and preserve orientation of the nanoparticles in the deposited layer. Afterwards, layers are cured in a chamber dryer to obtain desired properties. Nanoparticles orientation and carbon nanomaterials separation via DC electric field are analysed, and the o...