Danilo Cambiaghi

Developments in dynamic testing of rubber compounds: assessment of non-linear effects

Abstract In the present work, a test method to characterize the dynamic behaviour of rubber compounds by electrodynamic shaker (ES) in the frequency range of 10–1000 Hz was developed. Data of dynamic moduli of two different rubber compounds were determined through the analysis of the transmissibility of a suitably designed test system. The results were compared with those of dynamic moduli master curves obtained through frequency–temperature reduction of data measured by a commercial dynamic mechanical thermal analyser (DMTA), by scanning temperature at various frequencies in the range 0.3–30 Hz. Very good agreement of the data obtained by the two different aproaches were found, in spite of the different range of frequency explored by the two instruments, ES and DMTA, respectively. For one of the material examined, non-linear effects at low strain amplitudes were investigated by the two experimental methods considered.

Cosmic ray detection based measurement systems: a preliminary study

Cosmic rays, mostly composed of high energy muons, continuously hit the Earths surface (at sea level the rate is about 10 000 m−2 min−1). Various technologies are adopted for their detection and are widespread in the field of particle and nuclear physics. In this paper, cosmic ray muon detection techniques are assessed for measurement applications in engineering, where these methods could be suitable for several applications, with specific reference to situations where environmental conditions are weakly controlled and/or where the parts to be measured are hardly accessible. Since cosmic ray showering phenomena show statistical nature, the Monte Carlo technique has been adopted to numerically simulate a particular application, where a set of muon detectors are employed for alignment measurements on an industrial press. An analysis has been performed to estimate the expected measurement uncertainty and system resolution, which result to be strongly dependent on the dimensions and geometry of the set-up, on the presence of materials interposed between detectors and, ultimately, on the elapsed time available for the data taking.

Tailored One-Way and Two-Way Shape Memory Capabilities of Poly(ε-Caprolactone)-Based Systems for Biomedical Applications

This paper investigates the shape memory capabilities of semicrystalline networks, focusing the attention on poly(ε-caprolactone) (PCL) systems, a class of materials that allows to satisfy important requirements for their applications as biomedical devices, such as the good biocompatibility, the fast recovery of large “temporary” shape configurations, and the easy tailoring of the transformation temperatures. The materials were prepared with various crosslink densities and crosslinking methodologies; in particular, beside a thermal crosslinking based on reactive methacrylic end groups, a novel type of covalently crosslinked semicrystalline systems was prepared by a sol-gel approach from alkoxysilane-terminated PCL precursors, so as to avoid potentially toxic additives typically used for free-radical thermal curing. The materials were subjected to biological tests, to study their ability in sustaining cell adhesion and proliferation, and to thermal characterizations, to evaluate the possibility to tailor their melting and crystallization temperatures. The one-way shape memory (i.e., the possibility to set the material in a given configuration and to recover its pristine shape) and the two-way shape memory response (i.e., the triggered change between two distinguished shapes on the application of an on-off stimulus) were studied by applying optimized thermo-mechanical cyclic histories. The ability to fix the applied shape and to recover the original one on the application of heating (i.e., the one-way effect) was evaluated on tensile bars; further, to investigate a potential application as self-expandable stents, isothermal shape memory experiments were carried out also on tubular specimens, previously folded in a temporary compact configuration. The two-way response was studied through the application of a constant load and of a heating/cooling cycle from above melting to below the crystallization temperature, leading to a reversible elongation/contraction effect, involving maximum strain changes up to about 80%, whose extent may be controlled through the crosslink density.

Semi-Active Strategies for Racing Car Suspension Control

Quite a lot has been written on active suspension, the topic being suitable for theoretical studies. Unfortunately only a few applications has seen the road and even less went into production; by now very few road cars equipped with a real active suspension system are available on the market, and the interest to this kind of application seems to be reduced, perhaps because of high costs and restrictive regulations applied to the race car world. For this reason this paper presents the results of a study conducted on the vertical dynamics of a two wheel car model with a semi active suspension system, a possible alternative way to a fully active system to considerably improve suspension performance. Here the damping force of each suspension is obtained by modulating its damping factor according to opportune functions of the system state variables. This allows to reach several of the objectives achievable with a fully active suspension, without the need of a big amount of energy.

Evaluation of the shape memory performances of poly(ε-caprolactone)-based tubular devices for potential biomedical applications

The shape memory behavior of tubular specimens based on crosslinked poly(e-caprolactone) was investigated in order to evaluate their ability i) to restore their shape after being folded in a more compact one, and ii) to exert stress under external confinement (recovery stress). The specimens were prepared following different crosslinking methodologies and with different network densities, in order to tailor the material response in terms of transformation temperatures and recovery stress capabilities. The devices are able to fully recover their shape once heated close to the melting temperature and to exert moderate stresses, that may be controlled through thickness and crosslink density, and whose values were employed to develop a new testing apparatus for the measurement of radial dilation capabilities.

Tailored one-way and two-way shape memory response of poly(ε-caprolactone)-based systems for biomedical applications

A series of crosslinked poly(ε-caprolactone) (PCL) materials were obtained starting from linear, three- and four-arm star PCL functionalized with methacrylate end-groups, allowing to tune the melting temperature (Tm) on a range between 36 and 55°C. After deforming the specimens at 50% above Tm, the materials are seen to fully restore their original shape by heating them on a narrow region close to Tm; further, when the shape memory effect is triggered under fixed strain conditions, the materials are able to exert stress on a range between 0.2 and 7 MPa. The materials also display two-way shape memory features, reversibly moving between two shapes when cooled and heated under a fixed load. Finally, to investigate the application of the PCL materials as self-expandable stents, one-way shape memory experiments are currently carried out on tubular specimens.

Rockfall Full Scale Field Tests

The phenomenon of rockfall along slopes is an environmental risk that frequently occurs in mountainous regions. In this phenomenon are directly involved infrastructures (railways, ordinary roads or highway) but also residential areas as well as individual structures are also interested in prevention and defense. Among different types of action taken into account to reduce the risk of rockfall, passive defenses are solutions widely adopted. In this field, the most frequently used are the elasto-plastic steel barriers, while greater resistance are offered by reinforced earth. University of Brescia has developed a special “test field” in Pezzaze (near Brescia) and in 2010 started a research activity with the aim of studying the phenomenon of rockfall both on elasto-plastic passive defenses and on reinforced earth.

High Frequency Dynamic Testing of Rubbers and Rubber to Metal Devices

This paper develops a methodology to test and evaluate the dynamic properties of elastomeric compounds and of rubber to metal devices by means of an electrodynamic shaker. The dynamic tensile and shear moduli of elastomeric materials and the dynamic stiffness of rubber components are evaluated under different conditions of excitation frequency, temperature, dynamic deformation, and static load.